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solid waste in an unlined landfill or waste pile could impair water quality. As moisture <br /> from infiltrating rainfall or from the waste itself percolates through the solid waste,soluble <br /> constituents are dissolved in the liquid phase. In this way leachate accumulates soluble <br /> waste constituents until it reaches the base of the landfill or waste pile. At that point, this <br /> "initial leachate" poses a water quality threat that is similar to that posed by the liquid <br /> waste considered in Section 3 3.2 above. The same environmental fate processes and <br /> attenuation factors that govern the potential impact of constituents of a liquid waste apply <br /> to constituents of the "initial leachate" from a solid waste. Therefore,the concentrations of <br /> constituents in the "initial leachate" which have the potential to degrade water quality are <br /> equal to the Total Designated Levels for constituents of a liquid waste. Therefore,from <br /> equation [I], <br /> Concentration of Constituent Water Environmental <br /> in "Initial Leachate" (mg/1) - Quality x Attenuation [2] <br /> s that could degrade water quality Goal (mg/1) Factor <br /> I <br /> 4 <br /> At this point, an assumption is made that the concentrations of soluble constituents in the <br /> waste itself (in mg/kg of waste)prior to leaching are numerically equivalent to their <br /> concentrations in the "initial leachate" (in mg/1 of leachate)formed from the waste. <br /> Therefore,from equation [2], <br /> 61A Soluble Concentration of Water Environmental <br /> Constituent in Waste (mg/kg of waste) Quality x Attenuation [3] <br /> that could degrade water quality Goal (mg/1) Factor <br /> As explained in the CAM SOR a concentrations in the "initial leachate" (in mg/l of <br /> leachate)could be lower,but could also exceed the soluble concentrations in the waste itself <br /> On mg/kg of=waste) — <br /> --- —Note:=Concentrations of constituentsin the-"initial leachate" should not be confused with <br /> .=concentrations of constituents to extract from the-Waste Extraction-Test.-They are not the - --- <br /> 4 T same. Concentrations of constituents in the "initial leachate" are the result of the <br /> a accumulation of constituents from the waste as moisture migrates through a IandfiIl or <br /> waste pile. Concentrations of constituents in the extract from the WET are the result of a <br /> ' specific laboratory procedure where waste constituents are extracted from a solid waste by an <br /> extract solution under a controlled set of circumstances. The extract from the WET i$, <br /> therefore, not a simulation of the "initial leachate",but a measure of the amount of waste <br /> _constituents-that-may be leached from the waste in-a IandfiIl. - - - - <br /> Soluble Designated Levels <br /> Extractable concentrations from the Waste Extraction Test are expressed in milligrams per <br /> [ 3 liter (mg/1) of extract, rather than milligrams per kilogram (mg/kg) of waste. Soluble <br /> Designated Levels for constituents of a solid waste should also be expressed in mg/1 of <br /> extract so that direct comparison with results from the WET may be made. However, .� <br /> conversion from the units of mg/kg of waste to mg/1 of extract must take into account the <br /> TO-fold dilution in the WET procedure as explained in Section 3.1.2, "Determining <br /> Designated Level Methodology Page 35 <br /> L <br />