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NSA.. <br /> Working To Restore Nature <br /> Report on Vapor Extraction Test January 29, 1993 <br /> Coca-Cola Former Distribution Facility, Stockton, California 5400601 <br /> sample bags and labeled with the sample number, lob number, date, time, location, and <br /> sampler's name The samples were then placed on ice for transport to a State Certified <br /> laboratory A Chain of Custody Record accompanied all samples delivered to the <br /> laboratory <br /> LABORATORY METHODS <br /> Ten air samples were submitted with Chain of Custody Record to Sequoia Analytical, a <br /> State Certified laboratory in Redwood City, California Air samples were analyzed for <br /> TPHg and for the petroleum hydrocarbon constituents benzene, toluene, ethylbenzene, and <br /> total xylenes using EPA Methods 5030/8015/8020 Samples were analyzed on a 72 hour <br />' turnaround basis <br /> LABORATORY RESULTS <br /> Results of laboratory analyses of vapor samples are reported in Table 1 The Chain of <br /> Custody Record and laboratory analytical reports are included in Appendix C TPHg vapor <br /> concentrations ranged from a low of 33 milligrams per cubic meter (mg/m3) in the air <br /> sample from VEW-5 to a high of 19,000 mg/m3 in the sample from VEW-4 The average <br /> TPHg vapor concentration from all eight wells was 5,287 mg/m3 These are relatively low <br /> concentrations compared to other similar sites, and most likely this low concentration is due <br /> to the wide screen intervals (up to 60 feet) in the vapor wells and to moderate TPHg <br /> concentrations in the soil Benzene vapor concentrations ranged from 18 mg/m3 in VEW-5 <br /> ito 1,200 mg/m3 in VEW-3 After abatement by the IC engine, TPHg concentration was 320 <br /> mg/m3, and benzene was 46 mg/m3 This is an IC engine destruction efficiency of 97 5% <br /> for TPHg, and 84% for benzene <br /> The wells that contained the highest TPHg concentrations were VEW-3 which is located in <br />' the former tank pit, and VEW-4 which is about 20 feet north of the former tank pit In <br /> general, the wells with the lowest vapor concentrations are located farthest from the former <br /> tank pit After 120 minutes of operation, TPHg concentration decreased about 15% in <br />' VEW-3 However benzene increased, so that these fluctuations may be due in part to <br /> unsteady state conditions and laboratory methods standard deviation Comparing average <br /> vapor phase benzene concentration as a percent of TPHg average concentration for all <br /> wells, benzene generally comprised about 5% of the TPHg vapor This is a normal ratio <br /> of benzene to gasoline in soil vapors <br /> i <br /> r10 <br />