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PROPANE (Liquefied Petroleum Gas, LPG) G.A.S. 74-98-6 HIGHLY FLAMMABLE PHYSICAL DATA 0 State: Gas(compressed as liquid) Water Solubility:slight(o t to i%) Appearance: cololess BP: 44F(40C) Odor. Odorant(ethyl mercaptan)has foul, SG: 0.504 gadre or skunk-hke odor VD/GD; 150(Alt-1) Odor Threshold: 0.001 ppm PH: WA FiREM PLOWN MEASURES Emergency Overview: Flash Point: •157F(-1050) DANGER!Extremely Autoignition: 842F(4500) Ilamrnable liquefied gas Flammable Range: 2.1%-951/. under pressure; Unusual Huards: Severe fire d explosion hazard Gaslair mixtures are explosive.Vapor is heavier than eir.Vaporslgases may ignite at distant ignition sources and flash keep away from heal.sparks, back.Electrostatic discharges may be generated by!low or agilat-on resulting In flatrle l4 other Ignitkxt igni ienfenAoslon sources. Extinguishing Media: Carbon Dioxida,regular pry Chemical Special Instructions: Move container from fire area it It can be done w+thout risk Cool containers w/ Vapor reduces oxygen water spray until wet alter the lire is out Slay away from ends at tanks For available for breathing,8 may Lyes in cargo or storage area.cod containers vd water Imm unmanned hose cause suffocation In confined holder or monilor nozzles utl4 well atter lire Is out.h this Is impossible Keep spaces unnecessary people away.Isolate hazard area i4 deny entry.Let fire bum Withdraw immedalefy it rising sound from venting salety device or any dwgAomikm of tanks due to fire.For tank,rail car or tank muck-Stop teak a Use only with adequate possible without personal dsk,otherwise tel bum.For small tanks or cylinders, ventilation, Odor may not extinguish S isolate from other ilammables.Slop now of gas provide adequate warning of potentially hazardous REACTIVITY concentrations Incompatible: Oxidizing matenals,combustible materials Conditions to Avoid: Avoid heal,flames,sparks and other sources of Ignlllon Vapor is heavier than air and may collect at tow levels. EXPOSURE Lim rs/RaUTE(5)OF ENTRY TLV: 1000 ppm STEL: NIA Liquid may cause freeze bum PEL: 1000 ppm 1DLH• 20,01]0 ppm similar to frostbite.Do not gat liquid In eyes,on skin,or on rolhing. Eye Contact: Liquid may cause Ireeza bum similar to frostbite Ingestion: Same as eye contact Ingestion not expected to occur In normal use Inhalation: Nausea,vomiting irregular heanbeal-headache,symptoms of drunkenness, disodentation,suffocation,convulsions,coma Skin Contact: Busters.frostbite FIRST AID Eye Contact: Immediately flu"eyes with plenty of water lot at feast 15 minutes Get medxmt attention. Evacuation Procedure Ingestion: If swallowed get immediate medical attention Overview: Inhalation: Remove to uncontaminaled area.0 not breathing,give anirrdal respiration ff d1ficuity . breathing adrriaisler oxygen(qualified personnel) Got medical attention Evacuation radius(small)= Skin Contact: II frosthla!lreezing occurs,immediately Ilush with p%nly of lukewarm water(105-1 is F; 330 ft. 41.46 C),OOWT USE HOT WATER.It warm water Wet avaffabie gently wrap affected parts in blankets Get medical attention. Evacuation radius(large) ACCIDENTAL RELEASE MEASURE 3.000 n' Avoid heal Ifames,sparks E other sources of ignition Do not touch spi led matadal.Stop leak if possible without personal Ask Reduce vapors with waist spray Keep unnecessary people away isotate hazard area d deny entry.Remove sources of ignition Ventilate dosed spaces before entering. PERSONAL PRoTecnn EatiIPIAw(PPE) Equipment Type Color/Material/Description Gloves Ins-galed Clothing Insutaled Cold-resistant Goggles Chemical resistant Splash-proal Respirator Supplied Air Fun-face+separate escape air CHRONIC HEALTH EFFECTS No Information on significant adverse elleds