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GASOLINE (regular unleaded) C.A.S. 86290-81-5 FLAMMABLE LIQUID,TOXIC PHYSICAL DATA O ' State: Uquid Water Solubility_ Insoluble Appearance: Colorless to youow BP: 37.80(t00F)to 204 4C(4009 Odor: Petroleum SG: 0.7 grml•0.8 glml Odor Threshold: wA VDIGD: 3-4(Air-t) pH: NIA FIRF.IE)(PLDSION MEASURES Flash Point: <49F(a45C) Flammable Range: 1.4-7,13, Emergency Overview: Autaign)tion: >536F(>280C) Unusual Hazards: Extreme lire hazard.Liquid evaporates qu'ckly(even at low temperatures)d EXTREMELY FLAMMABLE forms vapor which can catch fire d bum w1 explosive violence.Invisible vapor LIQUID 8 VAPOR,Vapor spreads easily 3 can be sot an lira by many sources(pilot lights,welding equip., may cause flash fire electric malars 8 switches) Do not use lot cleaning,or portable healer or pressure appliance fuel.Toxic fumes may accumulate a cause death HARMFUL OR FATAL IF Extinguishing Media: Dry Chemical,CO2,AFFF Foam or alcohol resistant loam if>159:volume polar SWALLOWED—May cause solvents(oxygenates). lung damage if swallowed Special Instructions: Use water spray to cool fire exposed containers E to protect personnel. REACTIVITYVAPOR HARMFUL Incompatible: May react w:strong oxidizing agents,chlorates,nitrates,peroxides CAUSES SKIN 8 EYE Conditions to Avoid: Heat,Itame,sparks at other sources of Ignition. IRRITATION ExposunE LIMITS 1 ROUT (S)OF ENTRY KEEP OUT OF REACH OF TLV: apo ppm STEL: so0 ppm CHILDREN PEL: Soo ppm IDLH: X2000 ppm Long-term exposure to vapor Eye Contact: will cause Imiation,pe'n,and tearing,reddening swelling ft impaired vis'on has caused cancer In Ingestion: Due to low viscosity,this material can direct'y enter the lungs II sw20owed,at if subsequently laboratory wilmals vamiled Once in the lungs it Is very dinicu'I to remove d can cause severe Injury or death inhalation: The vaporlfumes may cause resp.ralory irritalion(cough.Ing,difficulty breathing) Toxic to aquatic organisms Concentrations above exposure limits may cause central nervous system ellects(headache, dizziness,nausea,vomifing,weakness,loss of coarfacalton,burred vision,drowsiness confusion,disorientation) At axtmme exposures.central nervous system effects include respiratory depression,tremors convuls ons,loss of consciousness coma or death Skin Contact:Contocl wl skin cruses Irrilat,on GDnta t mey cause drying or delatl.ng at the skin. Symptoms include pain,itching discafaralion,swell ng,bFslerfng Not expected to cause allergic skin response or be harmful to internal organs If absorbed through skin FiRST Ata Eye Contact: Flush eyes wl water Immediately whore hording eyelids open Remove contact lenses after Evacuation Procedure initial flushing b continue flush ng(at least 15 min.)Gat medical anent an it irritation persists Overview: Ingestion: If swallowed,DO NOT induce vom-t ng Get immedrale medical anentron Inhalation: Move exposed person to fresh air It not breathurg give ariiric al resplrakn.If breathing is Small spill or leak area, difficult,give oxygen.Get medics:attention it breathing 01'cullies continua isolate immediately for a Skin Contact:Wash skin w/water immediately d remove contaminated clothinglshoes.Gel medical 1 fi4 ft distance of 50 m attention it any symptoms develop To remove the materia'from skin use soap ti ) water.Discard contaminated clothing A shoes or thomugh:y c.ean berate reuse in all directions. ACCIDENTAL RELEASE MEASURE Large spills,isolate and Stop source of release it done without risk,contain to prevent contamination of soil sudacelgroundwater Clean consider downwind up split ASAP using non-combustible absorbent materials or pumping,observing all precauCons.All equipment used when handling product must be grounded Use vapor suppressing loam to reduce vapors use clean non. evacuation distance of sparking tools to collect absorbed malarial.Where feast e 8 appropriate remove contaminated soil.Place 300 m(984 It). Keep contaminated materials In disposable containers 8 dispose at in accordance w1 applicable regulations upwind and out of low PERSONAL PROTECTIVE EouipmENT(PPE) areas. Equipment Type Color/Material I Description Glave$ Chemical resistant N trile in the event of fire,isolate Goggles Chemical resistant Splash-proof for a distance of>1/2 mile. Air purifying respirator Full-face Cartridge.Black(Organic Vapor) CHRONIC HEALTH EFFECTS Prolonged/repeated exposure rmy cause cancer Gasoline:s classified as a Group 28 carcinogen(possibly carcinogenic to humans)by the Intemauonal Agency for Research on Cancer(IARC) Whole gasol ne exhaust Is atso classified as a Group 29 carcinogen by the IARC