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III. Environmental Setting, Impacts, and Mitigations <br /> G. Air Quality <br /> Ozone(Q31. The federal 03 standard is violated occasionally in some parts of the San Joaquin <br /> Valley and,therefore,the Air Basin is non-attainment for 03. Violations of the state standard are <br /> more frequent. Ozone is a secondary pollutant produced through photochemical (sunlight) <br /> reactions of emitted hydrocarbons and nitrogen oxides. Motor vehicles are a major source of <br /> hydrocarbons and nitrogen oxides. As shown in Table HI.G.1, O3 levels in San Joaquin County <br /> have exceeded the state standard regularly over the past five years. <br /> Particulate Matter jMM 1 Q). Particulate matter(PM10)refers to particulates with an aerometric <br /> diameter less than ten microns. Sources of PMIO include stationary point sources such as fuel <br /> combustion and industrial processes,fugitive sources such as dust from agricultural sources, <br /> traffic on paved and unpaved roads,wind erosion from open land, and transportation sources <br /> such as automobile exhausts. Very small particles of certain substances(e.g.,sulfates and <br /> nitrates)can cause lung damage directly,or can contain adsorbed gases(e.g.,chorides or <br /> ammonium)that may be injurious to health. Particulates also can damage materials and reduce <br /> visibility. Table III.G.1 shows that excesses of the State PM10 standard have been recorded <br /> regularly in San Joaquin County since 1988. <br /> Landfill Gas Emissions <br /> Municipal solid waste(MSW)landfills are potential sources of gas mixtures generated from the <br /> natural decomposition of organic wastes and vapors from volatile compounds present in the <br /> waste. Volatile organics are produced by biological processes or chemical reactions in the <br /> landfill. The major factors affecting the air emission production mechanisms are composition of <br /> waste, moisture content,temperature,age of landfill,pH, and oxygen and nutrient availability for <br /> bacteria. The major factors affecting transport are soil porosity,concentration gradient, <br /> compatibility of waste, amount of compaction,overburden weight, and rate of precipitation and <br /> evaporation(EPA, 1991 a). <br /> Landfill gas consists of approximately 50 percent by volume CO2,50 percent methane,and trace <br /> amounts of non-methane organic compounds(NMOL). Other constituents of landfill gas can <br /> include ammonia,hydrogen sulfide, nitrogen,hydrogen chloride,carbon monoxide, and a variety <br /> of volatile organic compounds(AWMA, 1992). Organic air emissions from landfills may <br /> include some toxic compounds and hazardous compounds with carcinogenic and non- <br /> carcinogenic health effects. The five major effects of.landfill gas emissions are human health and <br /> tvegetation effects from ozone produced by NMOC emissions,carcinogenicity and other possible <br /> HI.G.7 <br />