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WASTE DISCHARGE REQUIREMENTS ORDER NO. R5-2003-0049 -21- FORWARD INC. AND ALLIED WASTE INDUSTRIES FOR OPERATION OF FORWARD CLASS II LANDFILL SAN JOAQUIN COUNTY concentration estimates in the trace range (if available) for statistical analysis, in order to increase the statistical power by decreasing the number of"ties". 17. The Discharger may propose an alternate statistical method [to the methods listed under 27 CCR §20415(e)(8)(A-D)] in accordance with §20415(e)(8)(E)of Title 27, for review and approval by the Executive Officer. Upon receiving written approval from the Executive Officer, alternate statistical procedures may be used for determining the significance of analytical results for common laboratory contaminants(i.e.,methylene chloride, acetone, diethylhexyl phthalate, and di-n-octyl phthalate). Nevertheless, analytical results involving detection of these analytes in any background or downgradient sample shall be reported and flagged for easy reference by Board staff. 18. The Discharger shall use the following nonstatistical method for the VOC,ater and VOC,pg (Soil Pore Gas)Monitoring Parameters and for all Constituents of Concern which are not amenable to the statistical tests above(i.e., less than 10%of the data from background samples that equal or exceed their respective MDL). Each qualifying constituent at a monitoring point shall be determined based on either: a. The data from a single sample for that constituent,taken during that reporting period from that monitoring point; or b. The data from the sample which contains the largest number of qualifying constituents,where several independent samples have been analyzed for that constituent at a given monitoring point. c. Background for water samples or soil-pore gas samples shall be represented by the data from all samples taken from applicable background monitoring points during that reporting period(at least one sample from each background monitoring point). The Discharger may propose an alternate statistical method [to the methods listed under 27 CCR§20415(e)(8)(A-D)] in accordance with §20415(e)(8)(E)of Title 27, for review and approval by the Executive Officer. 19. The method shall be implemented as follows: a. For the Volatile Organic Compounds Monitoring Parameter For Water Samples [VOCwateYJ: For any given monitoring point,the VOCWater Monitoring Parameter is a composite parameter addressing all"qualifying VOCs" (in this case, VOCs that are detected in less than 10%of background samples). The Discharger shall conduct verification testing(see Detection Monitoring Specifications E.21. and E.23 below, as appropriate) to determine whether a release Of VOCWater Monitoring Parameter has occurred if the data for any monitoring point meets either of the following triggering conditions: