Laserfiche WebLink
were developed from the combined datasets. WIAC surveyed five codisposal sites and 70 MSW - <br />only sites. The WIAC toluene and benzene data were separately analyzed by disposal site type. <br />No significant differences were found between types of disposal sites for other compounds with <br />one exception. Carbon tetrachloride was detected at one codisposal site but at none of the MSW - <br />only disposal sites. The WIAC value for carbon tetrachloride includes the codisposal sites as <br />these had only a slight effect on the calculated value. The value is reported in Table 2 as a <br />`nondetect' with a footnote indicating that it was found at one codisposal site. <br />Data Summary <br />The WIAC results are compared with AP -42 default concentrations in Table 2. WIAC 1 and 2 <br />show the data prepared using past AP -42 and WIAC updated averaging methods, respectively <br />(see Data Averaging above). The WIAC 1 and 2 concentrations are similarly reduced from AP -42 <br />values by 76% and 80%, respectively. However simple alkane and alcohol compounds for which <br />relatively few analyses were available disproportionately skewed the results. Omitting these <br />compounds shows identical 56% overall reductions. Nearly identical reductions are also noted for <br />aromatic (58%) and chlorinated (79%) compounds. Even though the AP -42 and WIAC averaging <br />methods do not have any Iarge overall effect, the two methods did lead to very significant <br />differences for individual compounds (e.g., note those for 1,1,2,2 -Tetrachloroethane). <br />Discussion <br />AP -42 and WIAC Differences <br />The differences between the AP -42 default values and the WIAC survey results maybe, traced -.to <br />various factors. It was noted above that there are differences in the age of analyses between .the <br />AP -42 and WIAC data sets. Trends in LFG constituents have been well documented and'afe <br />addressed in the next section. Apart from differences in the age of analyses, it was found that <br />procedures used in U.S. EPA's preparation of the AP -42 defaults departed from the AP -42. <br />guidance6 in its use of nondetects and the minimum number of sources used for developing <br />default values. <br />The guidance specifies that nondetects should be used in the development of default values. <br />However all nondetects were discarded in at least one AP -42 update.' Nondetects may be <br />discarded under certain circumstances specified by the guidance where these are much greater in <br />magnitude than detects (doing otherwise would bias the default values high). However, the AP -42 <br />documentation does not identify which values are detects or nondetects making it impossible to <br />implement this procedure. Finally, the guidance states that default values developed entirely from <br />nondetects should be clearly identified as such. Since nondetects are not documented, this <br />procedure cannot be carried out. <br />6 "Procedures for Preparing Emission Factor Documents" Office of Air quality Planning and Standards, <br />Office of Air and Radiation, U.S. Environmental Protection Agency, Research Triangle Park, NC, <br />November 1997 (EPA -454/R-95-015 REVISED). <br />7 Phone communication (June 2000) with Stephen Roe, U.S. EPA contractor for past AP -42 revisions. <br />