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Mann-Kendall / Sen's Slope analysis identified significant decreasing statistical trends for the <br /> following inorganic constituents: calcium at AMW-12, chloride at AMW-12, hexavalent <br /> chromium at AMW-7, magnesium at AMW-12, nitrate at AMW-13, potassium at AMW-7, <br /> strontium at AMW-12, and field turbidity at AMW-2. Carbonate at AMW-12 exhibited an <br /> apparent decreasing trend according to the Mann-Kendall / Sen's Slope analysis, but this trend is <br /> due to a historical decrease in the laboratory RL. <br /> Mann-Kendall / Sen's Slope analysis did not identify any significant increasing statistical trends <br /> for VOCs. Mann-Kendall / Sen's Slope analysis identified significant decreasing statistical <br /> trends for trichlorofluoromethane at AMW-13 and 1,1-dichloroethane, cis-1,2-dichloroethene, <br /> dichlorodifluoromethane, tetrachloroethene,and trichloroethene at AMW-14. <br /> The first quarter 2012 barium concentration at AMW-13 (0.27 mg/L) is within the range of <br /> concentrations observed at that well since the beginning of monitoring in May 1995 (0.24 to 0.34 <br /> mg/L). As discussed above, barium at AMW-13 does not exhibit a significant increasing <br /> statistical trend. A Wilcoxon rank-sum test comparing the barium data at upgradient well AMW- <br /> 2 to the data at AMW-13 (a = 0.05) indicates that the barium data at AMW-13 are statistically <br /> distinct from those at the upgradient well. The Wilcoxon rank sum plot is presented in Appendix <br /> E. The presence of stable barium concentrations at AMW-13 that are statistically distinct from <br /> upgradient concentrations indicates that the concentration limit exceedance for barium at AMW- <br /> 13 in the first quarter 2012 is likely due to spatial variation in the natural groundwater <br /> geochemistry at the site. <br /> The first quarter 2012 barium concentration at AMW-14 (0.26 mg/L) is within the range of <br /> concentrations observed at that well since the beginning of monitoring in July 1995 (0.093 to 0.3 <br /> mg/L). As discussed above, barium at AMW-14 exhibits a significant increasing statistical trend. <br /> The increasing trend is not observed when the data are limited to the period of February 2009 to <br /> February 2012. A Wilcoxon rank-sum test comparing the July 1995 to November 2008 barium <br /> data at AMW-14 to the February 2009 to February 2012 data (a = 0.05) indicates that these <br /> periods are statistically distinct. The Wilcoxon rank sum plot is presented in Appendix E. This <br /> indicates that the significant increasing statistical trend in barium at AMW-14 may be due to a <br /> localized change in the site's natural geochemistry near AMW-14 in 2008-2009. This change <br /> was signified by a shift in barium at AMW-14 to higher but stable concentrations. <br /> The first quarter 2012 chloride concentration at AMW-14 (86 mg/L) is within the range of <br /> concentrations observed at that well since the beginning of monitoring in July 1995 (3 to 168 <br /> mg/L). As discussed above, chloride at AMW-14 exhibits a significant increasing statistical <br /> trend. The increasing trend is not observed when the data are limited to the period of March 2010 <br /> to February 2012. A Wilcoxon rank-sum test comparing the July 1995 to November 2009 <br /> chloride data at AMW-14 to the March 2010 to February 2012 data data (a= 0.05) indicates that <br /> these periods are statistically distinct. The Wilcoxon rank sum plot is presented in Appendix E. <br /> This indicates that the significant increasing statistical trend in chloride at AMW-14 may be due <br /> to a localized change in the site's natural geochemistry near AMW-14 in 2009-2010. This change <br /> was signified by a shift in chloride at AMW-14 to higher but stable concentrations. <br /> The first quarter 2012 hexavalent chromium at AMW-6 (0.0052 mg/L) is within the range of <br /> concentrations observed at that well since the beginning of monitoring in July 1995 (<0.002 to <br /> 0.0068 mg/L). As discussed above, hexavalent chromium at AMW-6 does not exhibit a <br /> significant increasing statistical trend. A Wilcoxon rank-sum test comparing the hexavalent <br /> chromium data at upgradient well AMW-2 to the data at AMW-6 (a = 0.05) indicates that the <br /> hexavalent chromium data at AMW-6 are statistically distinct from those at the upgradient well. <br /> 3 <br />