Laserfiche WebLink
localized change in the site's natural geochemistry near AMW-14 in 2009. This change was <br />signified by a shift in barium at AMW-14 to higher but stable concentrations. <br />The fourth quarter 2012 chloride concentration at AMW-12 (87 mg/L) is within the range of <br />concentrations observed at that well since the beginning of monitoring in August 1991 (24 to 90 <br />mg/L). As discussed above, chloride at AMW-12 does not exhibit a significant increasing <br />statistical trend when the entirety of the August 1991 through November 2012 data set is <br />considered. A Wilcoxon rank -sum test comparing the chloride data at upgradient well AMW-2 to <br />the data at AMW-12 (a = 0.05) indicates that the chloride data at AMW-12 are not statistically <br />distinct from those at the upgradient well. The Wilcoxon rank sum plot is presented in Appendix <br />E. The presence of stable chloride concentrations at AMW-12 that are not statistically distinct <br />from upgradient concentrations indicates that the concentration limit exceedance for chloride at <br />AMW-12 in the fourth quarter 2012 is likely due to variation time in the natural groundwater <br />geochemistry near AMW-12. Examination of the time series plot for chloride at AMW-12 <br />indicates that chloride concentrations generally decreased to a low of 24 mg/L in May 2003, then <br />began to increase, and have since stabilized in the past two years. An increasing trend is <br />observed when the data are limited to the period of May 2003 through November 2012, but no <br />trend is observed when the data are limited to the period of June 2010 through November 2012. <br />The fourth quarter 2012 chloride concentration at AMW-14 (81 mg/L) is within the range of <br />concentrations observed at that well since the beginning of monitoring in July 1995 (3 to 168 <br />mg/L). As discussed above, chloride at AMW-14 exhibits a significant increasing statistical <br />trend. The increasing trend is not observed when the data are limited to the period of March 2010 <br />to November 2012. A Wilcoxon rank -sum test comparing the July 1995 to November 2009 <br />chloride data at -14 to the March 2010 to November 2012 data data (a = 0.05) indicates <br />that these periods are statistically distinct. The Wilcoxon rank sum plot is presented in Appendix <br />E. This indicates that the significant increasing statistical trend in chloride at AMW-14 may be <br />due to a localized change in the site's natural geochemistry near AMW-14 in 2009-2010. This <br />change was signified by a shift in chloride at AMW-14 to higher but stable concentrations. <br />The fourth quarter 2012 hexavalent chromium concentration at AMW-6 (0.0051 mg/L) is within <br />the range of concentrations observed at that well since the beginning of monitoring in July 1995 <br />(<0.002 to 0.0068 mg/L). As discussed above, hexavalent chromium at AMW-6 does not exhibit <br />a significant increasing statistical trend. A Wilcoxon rank -sum test comparing the hexavalent <br />chromium data at upgradient well AMW-2 to the data at AMW-6 (a = 0.05) indicates that the <br />hexavalent chromium data at AMW-6 are statistically distinct from those at the upgradient well. <br />The Wilcoxon rank sum plot is presented in Appendix E. The presence of stable hexavalent <br />chromium concentrations at AMW-6 that are statistically distinct from upgradient concentrations <br />indicates that the concentration limit exceedance for hexavalent chromium at AMW-6 in the <br />fourth quarter 2012 is likely due to spatial variation in the natural groundwater geochemistry at <br />the site. <br />The fourth quarter 2012 hexavalent chromium concentration at AMW-7 (0.0058 mg/L) is within <br />the range of concentrations observed at that well since the beginning of monitoring in July 1995 <br />(<0.002 to 0.01 mg/L). As discussed above, hexavalent chromium at AMW-7 does not exhibit a <br />significant increasing statistical trend. A Wilcoxon rank -sum test comparing the hexavalent <br />chromium data at upgradient well AMW-2 to the data at AMW-7 (a = 0.05) indicates that the <br />hexavalent chromium data at AMW-7 are statistically distinct from those at the upgradient well. <br />The Wilcoxon rank sum plot is presented in Appendix E. The presence of stable hexavalent <br />chromium concentrations at AMW-7 that are statistically distinct from upgradient concentrations <br />indicates that the concentration limit exceedance for hexavalent chromium at AMW-7 in the <br />