Laserfiche WebLink
is again a good compromise between the bag and the cartridge. Air <br />shipment of bogs is not advised. Reanalysis from the some bag or canister <br />is convenient. This degree of flexibility can be important when samples <br />containing unexpectedly high or low levels of trace organics are <br />encountered or when several different types of analysis are required. <br />Gas phase reactions taking place as the bag or steel container is <br />collected will continue during shipment and storage. Since many of these <br />reactions are accelerated by light, CCAS recommends that bags be wrapped <br />in foil or immediately overbagged with a dark plastic bag upon collection. <br />Overbagging also provides a buffer of air similar to the collected air so <br />that diffusional exchange with dissimilar air is reduced. <br />Cartridge samples, once collected, are inherently more stable than <br />bag or canister samples. We have seen virtually identical gas <br />chromatographic patterns when comparing archived cartridge samples with <br />companion samples analyzed a year earlier. Furthermore, thermally <br />desorbable cartridges destined for analysis with legal implications should <br />be preanalyzed to avoid questions arising from the use of contaminated <br />cartridges. Even fresh cartridges supplied by commercial sources require <br />rigorous precleaning. <br />It is planned that canisters will be used exclusively in connection <br />with the proposed study. <br />DETECTION LIMITS <br />Quantitation from full -scan mass spectrometric data is based upon <br />area counts for one or more extracted ions. Since noise levels for <br />extracted ions are typically 100 area counts, a signal of 1000 would <br />provide a signal-to-noise ratio of 10 to 1. Detection limits can then be <br />calculated from calibration data on the basis of this signal to noise <br />ratio. Some examples are provided in Table 1. Frequent experimental <br />verification, of course, is required. Please note that all detection <br />levelt are less than or match your program requirements. <br />Since the data are collected by full scan GC/MS, absolute <br />confirmation of identity is practiced. This extra measure of quality <br />assurance is not even possible with the selective detector methods. <br />Furthermore the inspection of the data for additional compounds is <br />possible so that reanalysis would not be necessary even if the list Of <br />target compounds is extended after measurements have already been <br />completed at a given site. Since only one run is required for both <br />aromatic and halogenated components, this better technology does not <br />require the incurrence of higher costs. Therefore, it would seem unlikely <br />that the use of equivalent, but slightly less satisfactory techniques <br />would be required. <br />