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1.0 Surface Water Monitoring <br /> During the first quarter 2011 monitoring event, surface water sampling was performed at the <br /> French Camp Landfill by Del-Tech Geotechnical Support Services, Inc. (Del-Tech). Surface <br /> water samples were collected from monitoring points SW-I, SW-2, and SW-3. Upstream surface <br /> water monitoring points SW-1 in Walker Slough and SW-2 in French Camp Slough are sampled <br /> to provide background monitoring data. Surface water monitoring point SW-3 is downstream at <br /> the confluence of the sloughs. <br /> The Waste Discharge Requirements(WDRs) stipulate semi-annual sampling of the surface water <br /> monitoring points for field parameters (pH, specific conductance, temperature, and turbidity) and <br /> monitoring parameters (bicarbonate alkalinity, calcium, carbonate alkalinity, chloride, <br /> magnesium,nitrate, potassium, sodium, sulfate,total dissolved solids [TDS], and volatile organic <br /> compounds [VOCs]). <br /> The field results provided by Del-Tech and the laboratory results provided by TestAmerica <br /> Laboratories, Inc. (TestAmerica) for the first quarter 2011 surface water monitoring event are <br /> summarized on Table 2.1. The historical surface water data are presented in Appendix A. Time <br /> series concentration plots of historical surface water data are presented in Appendix B. The <br /> concentration limits presented on Table 2.1 were calculated from upstream data collected through <br /> the third quarter 2010 monitoring event. The statistical analysis calculations for surface water <br /> monitoring points are presented in Appendix B. Information on the development of the <br /> concentration limits can be found in the Fourth Quarter/Annual 1999 Monitoring Report, French <br /> Camp Landfill prepared by CH2M HILL in January 2000. A copy of the statistical analysis <br /> methodology is presented in Appendix C. <br /> Potassium was the only constituent that exceeded its concentration limit at SW-3 during the first <br /> quarter 2011 monitoring event. There were no VOCs detected at surface water monitoring points <br /> during the first quarter 2011 monitoring event. <br /> Historical data from the surface water monitoring points were evaluated for temporal trend using <br /> Mann-Kendall / Sen's Slope trend analysis. Graphs and summary tables of the Mann-Kendall / <br /> Sen's Slope analyses are presented in Appendix B. Only carbonate alkalinity at SW-1 and SW-3 <br /> and field turbidity at SW-1, SW-2, and SW-3 exhibited significant increasing statistical trends <br /> according to the Mann-Kendall/ Sen's Slope evaluation. Given that carbonate alkalinity exhibits <br /> a significant increasing statistical trend at upstream monitoring point SW-1 and turbidity at <br /> upstream points SW-1 and SW-2, the increasing trends for carbonate alkalinity and turbidity at <br /> downstream point SW-3 are likely due to ongoing changes in the natural surface water <br /> geochemistry at the site. Bicarbonate alkalinity at SW-I, nitrate at SW-I, sulfate at SW-I, and <br /> TDS at SW-1 exhibited significant decreasing statistical trends according to the Mann-Kendall <br /> Sen's Slope evaluation. <br /> The first quarter 2011 concentration of potassium at SW-3 (6.4 mg/L) is consistent with the <br /> concentrations observed at upstream monitoring points SW-1 (6.1 mg/L) and SW-2 (6.3 mg/L). <br /> The first quarter 2011 monitoring event represents the highest potassium concentration observed <br /> at both upstream (SW-1 and SW-2) and downstream (SW-3) monitoring points since the <br /> beginning of backgound in May 2005. Prior to the first quarter 2011, upstream potassium <br /> concentrations ranged from 1.3 mg/L to 4.8 mg/L and downstream concentrations ranged from <br /> 1.9 mg/L to 4.9 mg/L. As discussed above, potassium does not exhibit a significant upward <br /> statistical trend at SW-I, SW-2, or SW-3. The presence of elevated potassium concentrations <br /> during the first quarter 2011 monitoring event at both upstream and downstream monitoring <br /> locations indicates that the concentration limit exceedance for potassium at SW-3 may be due to a <br /> recent change in the natural surface water geochemistry at the site. It is recommended that the <br />