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_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 724060 - Unbranded Gasoline Reformulated with Ethanol Page 2/10 Issue Date: 20-Jun-2016 Status: FINAL SECTION 4: First aid measures Eye Contact: For direct contact, remove contact lenses if present and easy to do. Immediately hold eyelids apart and flush the affected eye(s) with clean water for at least 15 minutes. Seek immediate medical attention. Skin Contact: Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops, seek medical attention. Wash contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician. (see Note to Physician) Inhalation: If respiratory symptoms develop, move victim away from source of exposure and into fresh air in a position comfortable for breathing. If breathing is difficult, oxygen or artificial respiration should be administered by qualified personnel. If symptoms persist, seek medical attention. Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious and vomiting, place on the left side with the head down. If possible, do not leave victim unattended and observe closely for adequacy of breathing. Seek medical attention. Most important symptoms and effects, both acute and delayed: Effects of overexposure can include slight irritation of the respiratory tract, nausea, vomiting, and signs of nervous system depression (e.g., headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue). Continued exposure to high concentrations can result in vomiting, cardiac irregularities and sudden loss of consciousness. Prolonged or repeated contact may dry skin and cause irritation. Notes to Physician: Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to high concentrations of hydrocarbon solvents (e.g., in enclosed spaces or with deliberate abuse). The use of other drugs with less arrhythmogenic potential should be considered. If sympathomimetic drugs are administered, observe for the development of cardiac arrhythmias. When using high-pressure equipment, injection of product under the skin can occur. In this case, the casualty should be sent immediately to the hospital. Do not wait for symptoms to develop. High-pressure hydrocarbon injection injuries may produce substantial necrosis of underlying tissue despite an innocuous appearing external wound. These injuries often require extensive emergency surgical debridement and all injuries should be evaluated by a specialist in order to assess the extent of injury. Early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. Federal regulations (29 CFR 1910.1028) specify medical surveillance programs for certain exposures to benzene above the action level or PEL (specified in Section (i)(1)(i) of the Standard). In addition, employees exposed in an emergency situation shall, as described in Section (i)(4)(i), provide a urine sample at the end of the shift for measurement of urine phenol. SECTION 5: Firefighting measures NFPA 704 Hazard Class SECTION 3: Composition/information on ingredients Chemical Name CASRN Concentration¹ Gasoline 86290-81-5 >90 Ethyl alcohol 64-17-5 < 10 Hazardous Constituent(s) Contained Within Above Complex Substance(s) Chemical Name CASRN Concentration¹ Toluene 108-88-3 0-35 Xylenes (o-, m-, p- isomers)1330-20-7 0-15 Benzene 71-43-2 0-5 n-Hexane 110-54-3 0-5 Ethylbenzene 100-41-4 0-5 ¹ All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Health: 1 Flammability: 3 Instability: 0 0 (Minimal)