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• SCIC:IATES INC <br /> ' GROUNDWATER MONITORING AND SAMPLING PROCEDURES <br /> (Includes No-Purge Sampling) <br /> Groundwater Monitoring and Decontamination Method <br /> Prior to beginning, a decontamination area is established Decontamination procedures consist of scrubbing <br /> down-well equipment in a Liquidnox* solution wash (or equivalent degreasing compound), and rinsing in <br /> potable water and a final rinse of de-ionized (or distilled) water before and after each well Any non- <br /> dedicated down-well equipment is decontaminated prior to use on site <br /> Prior to purging and sampling a well, the static water level is measured to the nearest 0 01 feet with an <br /> electronic interface probe and/or water level meter Depth to bottom is typically measured every quarterly <br /> event The water level meter and tape will be decontaminated between each well If floating phase- <br /> separated hydrocarbons (PSH) are suspected or previously confirmed, an electronic interface probe is used <br /> to measure the well fluids to the nearest 0 01 feet PSH may alternatively be measured using a clear, open- <br /> ended product bailer, and the thickness is measured to the nearest 0 01 feet in the bailer Any monitoring <br /> well containing a measurable thickness of PSH before or during purging is not additionally purged and no <br /> sample is collected from that well Wells containing hydrocarbon sheen are sampled unless otherwise <br /> specified by the project manager Field observations such as well mtegnty as well as water level <br /> ' measurements and PSH thickness are recorded in the field <br /> Well Puraine <br /> When well purging is required, each monitoring well to be sampled is purged using, a truck-mounted <br /> 1� vacuum pump, a polyvinyl chloride (PVC) bailer or a submersible pump Physical parameters (pH, <br /> temperature, and conductivity) of the purge groundwater are monitored during purging activities to assess if <br /> ' the water sample collected is representative of the aquifer If required,parameters such as dissolved oxygen, <br /> turbidity, salinity etc are also measured Samples are considered representative if parameter stability is <br /> achieved Stability is defined as a change of less than 0 25 pH units, less than 10%change m conductivity in <br /> mucro mhos, and less than 10 degree centigrade(1 8 degrees Fahrenheit)change in temperature Parameters <br /> ' are measured in a discreet sample decanted from the bailer separately from the rest of the purge <br /> groundwater Parameters are measured during purging, initially, and at volume intervals of one well or <br /> borehole'volume (dependent on local regulations) Purging continues until the required well or borehole <br /> volumes have been removed, until the well completely dewaters, or until measured parameters stabilize as <br /> indicated above When wells dewater or demonstrate a slow recharge, wells may be sampled although <br /> fewer than required volumes have been removed Well purging information is recorded on the Purge Data <br /> ' sheet All meters used to measure parameters are calibrated daily Purge water is sealed, labeled, and stored <br /> on site in DO T-approved 55-gallon drums After being chemically profiled,the water is transported to an <br /> appropriate disposal facility by a licensed waste hauler <br /> Groundwater Sample Collection <br /> After purging, groundwater samples are collected after at least 80% of its static water level is recovered in <br /> the well If recharge is extremely slow, the well is allowed to recharge until sufficient volume has <br /> ' accumulated for sample collection No-purge groundwater samples are collected when prior approval <br /> by the lead regulatory agency has been permitted When no-purge samples are collected the same <br /> procedures are followed excluding well purging. All groundwater samples are collected using <br /> polyethylene disposable bailers attached! with new, clean string or rope Groundwater samples being <br /> analyzed for compounds most,sensrtive to volatilmatiog are collected first Groundwater samples are placed <br /> in appropriate+ laboratory-supplied contaiiiers, labeled,, documented on a chain of custody, form ands <br /> preserved on ice in a,cooler,for transport'to a `state-certified analytical laboratory After collection, all <br /> samples are stored m a chilled cooler and'refngerated'to approximately four (4) degrees Celsius while a' <br /> laboratory representative transports the samples to their facility Analytical detection limits match or <br /> su11 <br /> rpass standards required by relevant local or regional guidelines <br /> l <br />