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Workplan for Additional Assessment and Subslab Gas Sampling <br /> Tracy Office Plaza <br /> 324 E. i 1 th Street, Tracy,CA <br /> November 22,2013 <br /> Select groundwater and select soil samples will be analyzed for total petroleum hydrocarbons as motor oil <br /> (TPHmo), total petroleum hydrocarbons as diesel (TPHd), and total petroleum hydrocarbons as gasoline <br /> (TPHg)by EPA Method 8015Cm;and benzene,toluene,ethylbenzene,xylenes(BTEX),and methyl-tertiary <br /> butyl ether (MTBE) by EPA Method 8021B. To satisfy LTCP requirements, select samples will also be <br /> analyzed for oxgenates, lead scavengers(1,2-DCA and EDB),and naphthalene by EPA Method 8260 <br /> Task 3—Subslab Gas Sampling <br /> Pangea proposes to install two(2)subslab probes to facilitate collection of subslab gas samples.As the highest <br /> hydrocarbon concentrations detected in soil were Vencountered at a depth of approximately 1 ft bgs,Pangea <br /> proposes subslab gas sampling to determine if hydrocarbon vapors could migrate through underground <br /> conduits to below the onsite slab. Semi-permanent probes will be used to allow subsequent collection if <br /> merited.Pangea anticipates collecting initial soil gas samples during the cold season. If requested by SCEHD, <br /> additional soil gas samples will be collected during the warm season. <br /> The proposed sampling locations were selected to minimize disruption to existing businesses. As shown on <br /> Figure 2, the two subslab probe locations (SS-1 and SS-2)are proposed a the onsite building. Subslab gas <br /> samples will be collected within Summa canisters and submitted to a state-certified laboratory for analysis. <br /> Subslab gas samples will be analyzed for total petroleum hydrocarbons as gasoline(TPHg),benzene,toluene, <br /> ethylbenzene, xylene(s) (BTEX), methyl-tertiary butyl ether (MTBE), and naphthalene by modified Total <br /> Organics Method 15(TO-15);and for percent oxygen and helium(leak check compound)by Method ASTM <br /> D-1946.The oxygen analyses will help evaluate the potential for future degradation and attenuation of detected <br /> hydrocarbons,and will help assess soil column characteristics(>=4%oxygen in soil gas is referenced in the <br /> S WRCB's Underground Storage Tank Low-Threat Site Closure Policy).Additionally,for naphthalene analysis <br /> by TO-15, the analytical laboratory will utilize procedures for recovery, carryover,canister cleanliness,age, <br /> and matrix spikes and matrix spike duplicates as outlined in the April 2012 Cal/EPA Advisory Appendix E. <br /> The subslab gas probe installation procedure involves using a rotohammer to drill a 1 '/z-inch diameter,4-inch <br /> deep hole in the approximately 6-inch thick concrete slab of the building, drilling a '/z-inch diameter hole <br /> through the remaining concrete,installing a rubber stopper with stainless steel tubing(capped on one end with <br /> a Swagelok fitting)and placing a bentonite seal from the top of the stopper to within an inch of the surface.A <br /> second rubber stopper will be placed over the subslab probe to protect it and the probes will be allowed to <br /> equilibrate for at least 48 hours,prior to sampling. <br /> An analytical laboratory will provide sampling assemblies and certified Summa canisters for sampling. The <br /> Summa canisters will come under a complete vacuum of approximately 30 inches of mercury.Prior to sample <br /> collection a shut in test will be conducted on the sampling assembly with a vacuum pump to confirm no leak <br /> 4 <br />