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Nis. Wendy Cohen <br /> 5/4/95 <br /> Page 2 <br /> 2. Analysis of the soil and groundwater for glycol compounds and groundwater for <br /> semi-volatile organic compounds. <br /> As discussed with Mr. John Moody of your office, we will analyze soil and groundwater <br /> samples collected during this site investigation for ethylene glycol because under some <br /> circumstances ethylene glycol may form as an intermediate compound from the <br /> biodegradation of triethylene glycol. If ethylene glycol is not identified in any of the soil <br /> and groundwater samples collected during this study, it will not be included in the list of <br /> monitoring parameters during future routine groundwater sampling efforts. Conversations <br /> with chemists at analytical laboratories have revealed that the preferred method for <br /> analyzing soil and groundwater samples for ethylene glycol is by GC, rather than HPLC, <br /> due to its high water solubility. Therefore, we propose to test the soil and groundwater <br /> samples for ethylene glycol using GC methods. We do not propose to analyze the soil or <br /> groundwater samples for the other glycol compounds because, with the exception of <br /> ethylene glycol, glycol compounds are not regulated per Chapter 11, Title 22 of the <br /> California Code of Regulatons, nor are they contained in the water quality goals listed in <br /> Marshack (October 1986; revised September 1991). <br /> We do not beleive that the request for analyzing groundwater samples for semi-volatile <br /> compounds is warranted. Gas condensate liquids at this gas dehydrator station resemble a <br /> petroleum fuel, similar to kerosene, and as such, we propose to analyze all groundwater <br /> samples for TPH as gasoline, kerosene, diesel and motor oil, and BTEX compounds. This <br /> list of petroleum hydrocarbon analytes is consistent with the suggested list of chemical <br /> analytes for underground fuel tank cases presented in Regional Board Staff <br /> Recommendations for Initial Evaluation and Investigation of Underground Tanks. <br /> 3. Use of gradient information, in addition to soil boring results, in the selection of well <br /> locations. <br /> The Lathrop Gas Dehydrator Station is located in the San Joaquin Delta at a location <br /> relatively near the Middle River. As a result, it is possible that groundwater flow beneath <br /> the site may be influenced by tidal fluctuations. Therefore, taking a"snap shot" look at <br /> the groundwater gradient to direct well placement decisions may result in significant field <br /> judgment errors. The well locations provided in the workplan were designed to surround <br /> the groundwater plume as defined from the 1993 investigation results. As a result, <br /> regardless of the predominant groundwater flow direction,the proposed well locations <br /> should give adequate coverage for monitoring the lateral extent of the plume. As part of <br /> the workplan, we have proposed measuring groundwater levels at the site over a 24-hr <br /> period to determine if tidal fluctuations are observed in the groundwater levels at the site. <br /> If tidal fluctuations are observed in the groundwater levels at the site, the groundwater <br /> levels will be measured in several wells for a 72-hr period to determine the mean <br /> groundwater gradient direction. <br />