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Stantec <br /> L & M OPERABLE UNIT- FOURTH QUARTER AND ANNUAL 2012 SITE STATUS, <br /> REMEDIAL SUMMARY, AND GROUNDWATER MONITORING REPORT <br /> Groundwater Monitoring and Sampling <br /> February 1, 2013 <br /> Number of Number ofMinimum Detected Maximum Detected <br /> C-Zone <br /> Constituents Detections Wells Concentration in mg/L Concentration in mg/L <br /> above the MRL Analyzed (Well ID) (Well ID) <br /> TPHg 4 7 0.35 (MW-65) 3.1 (MW-66) <br /> TPHd 5 7 0.14 (MW-63) 2.5 (MW-54) <br /> TPHo 5 7 0.095 (MW-66) 1.1 (MW-67) <br /> Benzene 3 7 0.00086 (MW-64) 0.013 (MW-66) <br /> Toluene 2 7 0.00065 (MW-54) 0.0043 (MW-66) <br /> Ethylbenzene 1 7 --- 0.0011 (MW-66) <br /> Total Xylenes 3 7 0.0012 (MW-64) 0.012 (MW-66) <br /> MtBE 2 7 0.003 (MW-54) 0.0088 (MW-64) <br /> TBA 2 7 0.028 (MW-64) 0.056 (MW-54) <br /> Definitions: <br /> ID = Identification <br /> mg/L = Milligrams per liter <br /> MRL = Method reporting limit <br /> MtBE= Methyl tertiary butyl ether <br /> TBA = Tertiary butyl alcohol <br /> TPHd = Total petroleum hydrocarbons as diesel <br /> TPHg = Total petroleum hydrocarbons as gasoline <br /> TPHo = Total petroleum hydrocarbons as motor oil <br /> --- = Not applicable <br /> 2.5.2.3 Quality Assurance/Quality Control Samples <br /> Duplicate sample QCDUP-3 was collected from L&M OU C-Zone well MW-62 during 4Q12 <br /> sampling event. A comparison of the samples is shown below. <br /> Analyte Sample # Sample # % Difference <br /> MW-62 QCDUP-3 <br /> TPHg (mg/L) <0.05 <0.05 0% <br /> TPHd (mg/L) 0.27 0.29 +/-7.1% <br /> TPHo (mg/L) 0.55 0.44 +/-22.2% <br /> Benzene (mg/L) <0.0005 <0.0005 0% <br /> MtBE (mg/L <0.0005 <0.0005 0% <br /> TBA (mg/L) <0.005 <0.005 0% <br /> A RPD for TPHo is estimated at 22.2 percent, during 4Q12. The RPD value for TPHo is greater <br /> than the recommended range of RPD (20 percent) for QC purposes. This may indicate a <br /> possible bias for reproducibility and precision. The TPHo analytical results are within historical <br /> values; therefore, the reported values are not anticipated to be affected. <br /> I:\Tidewater\TW Stockton(P2A)\QMRs\2012\4Q12-Ann ual\4Q12 and Annual QSSR QRSR QMR Stockton_FINAL.doc 2.9 <br />