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I I <br /> Mr. M. ScottMansholt—CEMC <br /> Fourth Quarter Groundwater Monitoring and Sampling Report and <br /> 2005 Annual Summary December 22,2005 <br /> Vernalis Pump Station, Vernalis,California Page 5 of <br /> GROUNDWATER MONITORING AND SAMPLING <br /> MONITORING <br /> On October 18,2005, depth to water(DTW) was measured in wells MW-1, MW-2, MW-3, <br /> MW-4, MW-5, MW-6, and MW-7 using a hydrocarbon/water interface probe. DTW in these <br /> wells ranged from 33.71 feet below top of casing (bloc) in MW-6 to 37.42 feet btoc in MW-5. <br /> The approximate groundwater flow direction beneath the site is to the east-southeast at a <br /> calculated gradient of approximately 0.001 feet/foot (ft/ft). Cumulative DTW measurements, <br /> groundwater elevations, and SPO thickness measurements are presented in Table 1. A map <br /> showing the potentiometric surface is presented on Figure 3. Field data sheets are included in <br /> Attachment A. <br /> SAMPLING <br /> Following DTW measurements, groundwater samples were collected from wells MW-2 through <br /> MW-7 on October 18, 2005. Wells MW-2, MW-3, and MW-4 were not purged due to the low <br /> volume of water in the well casing. Wells MW-5, MW-6, and MW-7 were purged of <br /> approximately four casing volumes using a 2-inch disposable polyethylene bailer or a low-flow <br /> submersible pump. In these wells, pH, specific conductance, dissolved oxygen, turbidity, and <br /> temperature water-quality parameters were recorded. After water-quality parameters stabilized <br /> (i.e., a minimum of three consecutive readings with values within 10 percent for each parameter), <br /> groundwater samples were collected. No sample was collected from MW-1 due to the presence <br /> of SPO in this well. Field data sheets are included as Attachment A. <br /> GROUNDWATER ANALYTICAL RESULTS <br /> Groundwater samples were collected on October 18, 2005 from wells MW-2, MW-3, MW-4, <br /> MW-5, MW-6, and MW-7. All samples were collected using a bailer, and laboratory-provided <br /> bottles were filled directly from the bailer or by a low-flow submersible pump using new <br /> polyethylene tubing through which groundwater was extracted. The bottles were labeled, sealed, <br /> and placed immediately into an ice-cooled chest for delivery to Lancaster Laboratories, Inc. <br /> (Lancaster), under SAIC chain-of-custody protocol. Lancaster is a California State-certified <br /> laboratory(ELAP#2116). <br /> The samples were analyzed for the following: <br /> • TPHd: CIO—C25 using U.S. Environmental Protection Agency(EPA) Method 8015M and <br /> TPHd with silica-gel preparation for samples with detectable concentrations of TPHd <br /> using EPA Method 8015M; <br /> • TPHg: C6—Ci0, using EPA Method 8015M; <br /> • BTEX using EPA Method 826013; and <br /> • PAHs using EPA Method 8270C SIM. <br /> SPO was present in MW-1, and, therefore, no sample was collected from this well. No TPHg or <br /> BTEX were detected in any of the groundwater monitoring wells sampled. TPHd was only <br /> detected in well MW-7 (620 pg/L; 270 pg/L with silica-gel cleanup). No PAHs were detected in <br /> the groundwater sample collected from MW-4 and MW-5. Low concentrations of some PAHs <br /> were detected in samples from MW-2, MW-3, MW-6, and MW-7. Groundwater analytical <br /> results are presented as Tables 2 and 3. A petroleum-hydrocarbon distribution map is presented <br /> as Figure 4. A copy of the laboratory analytical report is presented as Attachment B. <br />