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Mr.M. Scott Mansholt—CEMC <br /> Fourth Quarter 2006 Groundwater Monitoring and Sampling Report and <br /> Annual Summary Report January 12,2007 <br /> Vernalis Pump Station Page 6 of 7 <br /> QUARTERLY OIL-ABSORBENT (OLEOPHILIC) SOCK REPLACEMENT <br /> An oleophilic sock was installed in well MW-1 due to SPO observed in the well. The sock has been <br /> monitored and replaced as necessary on a quarterly basis. During the fourth quarter of 2006,the sock was <br /> weighed but not replaced, and 2 ounces(approximately 0.017 gallon)of SPO had been absorbed. <br /> A summary of SPO thickness measurements is included in Table 1. <br /> QUALITY ASSURANCE/QUALITY CONTROL <br /> All field procedures were conducted in accordance with SAIC's Quality Assurance and Quality Control <br /> Sample Collection, Handling, and Analysis.10 Based on SAIC's evaluation, all analytical data are usable <br /> as qualified for the purpose of determining chemical concentrations in groundwater at the site. Qualified <br /> data with applicable reason codes are shown in Table B-1 of Attachment B. <br /> Unless noted otherwise,analytical data collected in support of this investigation are considered precise, <br /> accurate,representative, complete, and comparable, and they may be used for their intended purposes. <br /> ANNUAL SUMMARY 2006 <br /> Quarterly groundwater monitoring and sampling began at the site in the second quarter of 2005. Depth to <br /> groundwater recorded during 2006 ranged between approximately 33.46 (MW-6)to 38.92 (MW-4) feet <br /> btoc (Table 1). Groundwater flow during 2006 varied east to northeast at an average gradient of <br /> 0.001 ft/ft. A summary of groundwater flow directions and gradients is presented in Table 4, and the <br /> previous 2006 quarterly potentiometric surface maps are presented as Figure 5 through 7. <br /> The site wells are constructed with screen lengths of approximately 10 feet for wells MW-1 through <br /> MW-4 (28 to 38 feet bgs)and 20 feet for wells MW-5 through MW-7 (approximately 30 to 50 feet bgs). <br /> Depth to groundwater has ranged from approximately 31 to 38 feet bgs, indicating that wells MW-5 <br /> though MW-7 are appropriately screened to monitor the upper water-bearing zone beneath the site. Wells <br /> MW-1 though MW-4 are shallow and will need to be replaced if future groundwater levels become lower. <br /> A summary of well construction details is presented in Table 5. <br /> SPO has been observed in well MW-1. Oleophilic socks are currently used in MW-1 to extract the SPO. <br /> Approximately 0.012 gallon has been extracted by the sock. A summary of the SPO thickness <br /> measurements is presented in Table 1. <br /> No TPHg or BTEX were detected in the any groundwater samples during 2006(Table 2). TPHd were <br /> detected in the samples from wells MW-2 through MW-5 and MW-7 at concentrations up to 930µg/L. <br /> Low PAH concentrations were detected in wells MW-5,MW-6, and MW-7 (Table 3). The RWQCB <br /> Region 2 ESLs and the numerical State WQOs were slightly exceeded by benzo(b)fluoranthene. The <br /> WQO and ESL for benzo(b)fluoranthene are 0.04 and 0.014 pg/L,respectively. The highest <br /> benzo(b)fluoranthene concentration detected in the site wells was 0.044 pg/L in MW-6. A distribution <br /> map for 2006 of petroleum in groundwater is presented on Figure 4. <br /> CONCLUSIONS AND RECOMMENDATIONS <br /> The groundwater elevation and gradient remained relatively consistent during 2006. The groundwater <br /> elevation fluctuated between 68.83 and 72.04 feet above MSL with a gradient predominantly towards the <br /> east at 0.001 ft/ft. Dissolved-phase TPHg and BTEX do not appear to be present beneath the site. While <br /> dissolved-phase TPHd concentrations fluctuated between non-detect levels to 930 µg/L,the <br /> 10. SAIL,2006. Quality Assurance and Quality Control Sample Collection,Handling,and Analysis. January(Updated). <br />