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Mr.M. Scott Mansholt—CEMC <br /> Fourth Quarter 2005 Groundwater Monitoring and Sampling Report and <br /> 2005 Annual Summary January 5,2006 <br /> US Can-Welty Road,Vernalis,California Page 5 of 7 <br /> SAMPLING <br /> Following DTW measurements, groundwater samples were collected from wells MW-3 through <br /> MW-5 and WFSMW-1 on October 19,2005. Wells MW-3 through MW-4 were not purged due <br /> to the low volume of water in the well casing. Wells MW-5 and WFSMW-1 were purged of <br /> approximately four casing volumes using either a 2-inch disposable polyethylene bailer or a low- <br /> flow submersible pump. In these wells,pH, specific conductance, dissolved oxygen,turbidity, <br /> and temperature water-quality parameters were recorded. After water-quality parameters <br /> stabilized(i.e., a minimum of three consecutive readings with values within 10 percent for each <br /> parameter), groundwater samples were collected. No samples were collected from MW-1 and <br /> MW-2 due to the presence of SPO in these wells. Field data sheets are included as Attachment A. <br /> GROUNDWATER ANALYTICAL RESULTS <br /> Groundwater samples were collected on October 19,2005. All samples were collected using a <br /> bailer or by a low-flow submersible pump using new polyethylene tubing through which <br /> groundwater was extracted. Laboratory-provided bottleware was used to preserve the samples. <br /> The bottles were labeled, sealed, and placed immediately into an ice-cooled chest for delivery to <br /> Lancaster Laboratories, Inc. (Lancaster),under SAIC chain-of-custody protocol. Lancaster is a <br /> California State-certified laboratory(ELAP#2116). <br /> The samples were analyzed for the following: <br /> • TPHd: C10—C25 using Environmental Protection Agency(EPA)Method 8015M and TPHd <br /> with silica-gel preparation for samples with detectable concentrations of TPHd using <br /> EPA Method 8015M; <br /> • TPHg: C6—Clo,using EPA Method 8015M; <br /> • BTEX using EPA Method 8260B; and <br /> • PAHs using EPA Method 8270C SIM. <br /> SPO was present in MW-1,and a petroleum odor was detected in MW-2;therefore,no samples <br /> were collected from these wells. No TPHd, TPHg,BTEX were detected in the groundwater <br /> samples, except 2,500 and 240 gg/L TPHd in wells MW-3 and WFSMW-1,respectively. No <br /> PAHs were detected in the groundwater samples from MW-4 and MW-5. Four PAHs were <br /> detected in groundwater sample from well MW-3 at concentrations just above detection limits. <br /> Fluorene was detected in WFSMW-1 at the detection limit. The groundwater analytical results <br /> are presented in Tables 2 and 3. A petroleum hydrocarbon distribution map is presented as <br /> Figure 4. A copy of the laboratory analytical report is presented as Attachment B. <br /> ABSORBENT(OLEOPHILIC) SOCK REPLACEMENT <br /> An oleophilic sock has been installed in well MW-1 due to the presence of SPO in the well and <br /> an oleophilic sock was placed in MW-2 due to the petroleum odor detected from the well. The <br /> oleophilic sock in MW-1 has been monitored and replaced as necessary on a quarterly basis. <br /> During the fourth quarter 2005,the oleophilic sock from MW-1 was weighed but not replaced, <br /> and approximately 10 ounces(0.07 gallon) of SPO had been absorbed. A summary of SPO <br /> thickness measurements is included in Table 1. <br /> QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) <br /> All field procedures were conducted in accordance with SAIC's Quality Assurance and Quality <br /> Control Sample Collection, Handling, and Analysis procedures. No sample was received by the <br />