Laserfiche WebLink
Dioxygenyl tetrafluoroborate is as very powferful oxidant. The addition of a small particle to small samples of <br />benzene, at ambient temperature, causes ignition. <br />Contact with sodium peroxide with benzene causes ignition. <br />Benzene ignites in contact with powdered chromic anhydride. <br />Virgorous or incandescent reaction with hydrogen + Raney nickel (above 210 C) and bromine trifluoride. <br />Special Remarks on Explosion Hazards: <br />Benzene vapors + chlorine and light causes explosion. <br />Reacts explosively with bromine pentafluoride, chlorine, chlorine trifluoride, diborane, nitric acid, nitryl perchlorate, <br />liquid oxygen, ozone, silver perchlorate. <br />Benzene + pentafluoride and methoxide (from arsenic pentafluoride and potassium methoxide) in <br />trichlorotrifluoroethane causes explosion. <br />Interaction of nitryl perchlorate with benzene gave a slight explosion and flash. <br />The solution of permanganic acid ( or its explosive anhydride, dimaganese heptoxide) produced by interaction of <br />permanganates and sulfuric acid will explode on contact with benzene. <br />Peroxodisulfuric acid is a very powferful oxidant. Uncontrolled contact with benzene may cause explosion. <br />Mixtures of peroxonnonsulfuric acid with benzene explodes. <br />Section 6: Accidental Release Measures <br />Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal. <br />Large Spill: <br />Flammable liquid. <br />Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, <br />sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or <br />confined areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. <br />Check TLV on the MSDS and with local authorities. <br />Section 7: Handling and Storage <br />Precautions: <br />Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing <br />material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. In case of insufficient ventilation, wear suitable <br />respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid <br />contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids. <br />Storage: <br />Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly <br />closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). <br />Section 8: Exposure Controls/Personal Protection <br />Engineering Controls: <br />Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their <br />respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the <br />work-station location. <br />Personal Protection: <br />Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. <br />Gloves. <br />Personal Protection in Case of a Large Spill: <br />Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be <br />used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist <br />BEFORE handling this product. <br />Exposure Limits: <br />P. 3