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Propane Section 6. Accidental release measures For emergency responders If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Large spill Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment(see Section 8). Contains gas under pressure. Do not get in eyes or on skin or clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved area. including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatibilities incompatible materials (see Section 10). Eliminate all ignition sources. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits Propane NIOSH REL (United States, 10/2016). TWA: 1800 mg/m3 10 hours. TWA: 1000 ppm 10 hours. OSHA PEL (United States, 5/2018). TWA: 1800 mg/m3 8 hours. TWA: 1000 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 1800 mg/m3 8 hours. TWA: 1000 ppm 8 hours. ACGIH TLV(United States, 3/2019). Oxygen Depletion [Asphyxiant]. Explosive potential. Date of issue/Date of revision :1111512020 Date of previous issue :101512020 Version :1.02 4112