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MATERIAL SAFETY DATA SHEET.Database and format copyright©1999 by C&P Press. All rights reserved. 1 MICROTHIOL® FIRE AND EXPLOSION DATA HEALTH HAZARD INFORMATION DISPERS STM FLASH POINT(TEST METHOD) EFFECTS OF EXPOSURE TO CONCENTRATE MICRONIZED WETTABLE SULFUR 207-C(INRS) PERMISSIBLE EXPOSURE LIMIT (TLV/TWA OR 0 EMERGENCY TELEPHONE NUMBERS: FLAMMABLE LIMITS CEILING[C]) (215)419-5094(7:30 a.m.-4 p.m. EST)(PRIMARY) NE (800)424-9300(CHEMTREC) AUTOIGNITION TEMPERATURE/FIRE POINT ACGIH TLVITWA NE (303)623-5716 Rocky Mountain Poison Control 232'C OSHA TWA NE ADDRESS: EXTINGUISHING MEDIA IRRITATION ELF ATOCHEM NORTH AMERICA, INC. 0 WATER SPRAY NOT AN IRRITANT AGRICHEMICALS GROUPx❑WATER FOG CORROSIVITY 2000 MARKET ST.,21st FLOOR IXJ WATER STREAM NOT CORROSIVE PHILADELPHIA, PA 19103-3222 ❑CO2 SENSITIZATION FORM 4627 U DRY CHEMICAL NOT A SKIN SENSITIZER REV. 10/99 ❑ALCOHOL FOAM INHALATION EFFECTS PRODUCT IDENTIFICATION ❑FOAM NE C7 EARTH OR SAND LUNG EFFECTS 0 PRODUCT NAME SPECIAL FIRE FIGHTING PROCEDURES LUNG INJURY UPON PROLONGED INHALATION MICROTHIOL®DISPERSST" ❑DO NOT ENTER BUILDING EMERGENCY FIRST AID EPA REG.NO. ❑ALLOW FIRE TO BURN INGESTION 45 1:1 WATER MAY CAUSE FROTHING ❑GET MEDICAL ATTENTION ELFF ATOCHEM NORTH AMERICA, INC. CODE El DO NOT USE WATER INDUCE VOMITING NUMBER OTHER: ❑ DO NOT INDUCE VOMITING 619 USE SELF-CONTAINED BREATHING APPARA- GIVE PLENTY OF WATER CHEMICAL NAME AND FORMULA TUS. ❑OTHER: SULFUR UNUSUAL FIRE AND EXPLOSION HAZARDS DERMAL SYNONYMS DUST EXPLOSION HAZARD ❑GET MEDICAL ATTENTION SULFUR FX1 FLUSH WITH SOAP AND WATER CAS NUMBER ❑SENSITIVE TO SHOCK I CONTAMINATED CLOTHING—REMOVE AND 7704-34-9 ❑CONTAMINATION LAUNDER CHEMICAL FAMILY ❑x TEMPERATURE n CONTAMINATED CLOTHING—DESTROY NA EYE CONTACT REACTIVITY DATA ❑G HAZARDOUS INGREDIENTS ET MEDICAL ATTENTION STABILITY D FLUSH WITH PLENTY OF WATER FOR AT ❑x STABLE LEAST 15 MINUTES MATERIALS OR COMPONENTS y WW ❑UNSTABLE INHALATION SULFUR 80 CONDITIONS CONTRIBUTING TO INSTABILITY ❑GET MEDICAL ATTENTION Contains no substances listed as toxic by SARA 313. NA U REMOVE TO FRESH AIR Contains no substances known to be carcinogens. INCOMPATIBILITY—AVOID CONTACT WITH ElIF NOT BREATHING, GIVE ARTIFICIAL RESPI- RATION SARA TITLE III ❑STRONG ACIDS U GIVE OXYGEN El STRONG ALKALIS Hazards Classification(40 CFR 370): x❑STRONG OXIDIZERS SPECIAL PROTECTION INFORMATION Immediate Health: YES HAZARDOUS DECOMPOSITION PRODUCTS, VENTILATION REQUIREMENTS— Fire: YES NONE Delayed Health: NO THERMAL AND OTHER: ALWAYS MAINTAIN EXPOSURE BELOW PERMIS- Sudden Pressure: NOSIBLE EXPOSURE LIMITS Reactivity: NO CONDITIONS TO AVOID ❑ CONSULT AN INDUSTRIAL HYGIENIST OR EN- Section 313(40 CFR 372): This product contains the ❑HEAT VIRONMENTAL HEALTH SPECIALIST ❑OPEN FLAMES following chemicals subject to SARA Section 313 re- ❑LOCAL EXHAUST ❑x SPARKS USE WITH ADEQUATE VENTILATION porting requirements: Sulphur. ❑x IGNITION SOURCES (] CHECK FOR AIR CONTAMINANT AND OXYGEN NFPA RATINGS DEFICIENCY SPILL OR LEAK EYE Flammability: 1 n SAFETY GLASSES Reactivity: 1 STEPS TO BE TAKEN IF MATERIAL IS RELEASED El FACE SHIELD Health: 2 OR SPILLED F-1 GOGGLES [I FLUSH WITH WATER SHIPPING INFORMATION ❑ABSORB WITH SAND OR INERT MATERIAL HAND(GLOVE TYPE) PROPER SHIPPING DESCRIPTION ❑NEUTRALIZE [i]POLYVINYL CHLORIDE AGRICULTURAL FUNGICIDE, N.O.S. NOT REGU- SWEEP OR SCOOP UP AND REMOVE ❑NEOPRENE LATED BY DOT,IMO,ICAO. ❑ KEEP UPWIND. EVACUATE ENCLOSED ❑ BUTYL RUBBER PLACARD SPACES LJ NATURAL RUBBER NOT REQUIRED ❑PREVENT SPREAD OR SPILL ❑POLYVINYL ALCOHOL ❑DISPOSE OF IMMEDIATELY ❑POLYETHYLENE PHYSICAL PROPERTIES ❑ANY WASTE DISPOSAL METHOD: PHYSICAL STATE If wastes cannot be disposed of by use according to 0 RESPIRATOR TYPE— BOILING POINT/RANGEUse NIOSH approved respiratory equipment appro- label instructions,contact your State Pesticide or En- priate to the material and/or its components where NA vironmental Control Agency,or the hazardous waste airborne exposure is likely. If exposures cannot be 214.5E guidance. MELTING POINT representative at the nearest EPA Regional Office for kept n FREEZING POINT at a minimum with engineering controls, con- suit respirator manufacturer to determine appropriate FREE NATOXICITY type of equipment for a given application. Observe MOLECULAR WEIGHT(CALCULATED) respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions SPECT(ATOMIC) ORAL(ACUTE) where there may be potential for significant expo- SPECIFIC GRAVITY(H2O=1) LDsO>2,000 mg/kg sure,use an approved full face positive-pressure,self- NA DERMAL(ACUTE) contained breathing apparatus or positive-pressure air- VAPOR PRESSURE(mm Hg) LD50 >2,000 mg/kg line with auxiliary self-contained breathing apparatus 0.0086 mbar INHALATION(ACUTE) self-contained air supply. Respiratory protection pro- SOLUBILITY IN H2O LC50 > 1.35 mg/L(4 HR) grams must comply with 29CFR 190.134. INSOLUBLE CHRONIC,SUBCHRONIC,ETC. OTHER PROTECTIVE EQUIPMENT APPEARANCE AND ODOR THERE ARE NO KNOWN RISKS OF ONCOGENIC, WEAR PROTECTIVE CLOTHING WHICH PRE- SOLID AMBER CRYSTALS, CHARACTERISTIC TERATOGENIC OR REPRODUCTIVE HAZARDS AS- VENTS SKIN CONTACT, INCLUDING LONG- ODOR SOCIATED WITH SULFUR. SLEEVED SHIRT AND LONG-LEGGED PANTS.