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Brusca File No. 137-002 <br /> <br />Page 3 <br />June 25, 2019 <br />Murphy Parkway Property Soil Gas Monitoring <br /> <br /> <br /> <br />SOIL GAS LABORATORY TESTING <br /> <br />The soil gas samples collected from soil gas monitoring wells SGMW1 and SGMW2 were <br />transported to a State-certified laboratory for analysis. Both soil gas samples were analyzed for <br />met hane, oxygen, carbon dioxide, and nitrogen by ASTM Method D1946. The samples also <br />were analyzed for VOCs by EPA Test Method TO-15. The analytical laboratory results are <br />summarized on the attached Table I, along with data from past monitoring. The laboratory <br />reports, internal laboratory QA/QC data, and chain-of-custody documentation also are attached. <br /> <br /> <br />RESULTS AND DISCUSSION <br /> <br />As shown on Table I, the June 2019 soil gas sample s collected from SGMW1 and SGMW2 did <br />not contain methane at a concentration above the laboratory reporting limit s of 0.00021% <br />0.00026% for these samples, respectively. Methane concern at the site is not indicated by June <br />2019 data. <br /> <br />The soil gas samples collected from monitoring wells SGMW1 and SGMW2 in June 2019 <br />contained the VOCs acetone, chloroform and/or carbon disulfide at very low concentrations. To <br />evaluate the significance of the concentrations of acetone detected in the soil gas samples <br />(particularly with respect to the potential for vapor intrusion into indoor air spaces at <br />concentrations that could be considered a human health concern), we have co nsidered Regional <br />Screening Levels (RSLs) published by the US Environmental Protection Agency (USEPA) and <br />Environmental Screening Levels (ESL s) published by the San Francisco Bay Regional Water <br />Quality Control Board (SFBRWQCB). The applicable screening values for acetone, chloroform, <br />and carbon disulfide are shown on Table I along with the analytical data from the soil gas <br />monitoring wells . The published RSL values are for indoor air VOC concentrations. For use in <br />the screening evaluation for the subject site, the indoor air RSL values have been adjusted by an <br />attenuation factor of 0.03 to simulate the attenuation that could occur from soil gas to the indoor air <br />environment. <br /> <br />As shown on Table I, the concentrations of acetone, chloroform, and carbon disulfide detected in <br />the soil gas sample s in June 2019 are below the commercial/industrial agency screening values <br />considered, except for the chloroform concentration detected in the soil gas sample collected from <br />SGMW1. The soil gas sample collected from SGM W1 contained 3 4 ug/m3 chloroform which <br />slightly exceeds the screening level considered (18 ug/m3). The source of the chloroform detected <br />in the SGMW1 sample is unknown. Chloroform occurs naturally in certain settings, although <br />ant hro pogenic sources are responsible fo r much of the chloro fo rm in the environment. A <br />common anthropogenic source of chlorofo rm in the environment is the discharge of chlorinated <br />drinking water. It is possible that the detected chloroform in soil gas at the SGMW1 location is <br />related to the recent initiation of landscape irrigation in the area of SGMW1 utilizing municipal <br />water. Nonetheless, it is our opinion that the slightly elevated concentration of chloroform <br />detected at the SGMW1 location in June 2019 would not represent an unacceptable vapor <br />intrusion health risk at the onsite warehouse building, due to the distance to the building and the <br />nature of flo or slab system associated with the building. As mentioned above, the soil gas <br />screening levels considered were developed using an attenuation factor of 0.03, which most