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Brusca File No. 137-002 <br /> <br />Page 3 <br />April 1, 2020 <br />Murphy Parkway Property Soil Gas Monitoring <br /> <br /> <br />SOIL GAS LABORATORY TESTING <br /> <br />The soil gas samples collected from soil gas monitoring wells SGMW1 and SGMW2 were <br />transported to a State-certified laboratory for analysis. Both soil gas samples were analyzed for <br />methane, oxygen, carbon dioxide, and nitrogen by ASTM Method D1946. The samples also <br />were analyzed for VOCs by EPA Test Method TO-15. The analytical laboratory results are <br />summarized on the attached Table I, along with data from past monitoring. The laboratory <br />reports, internal laboratory QA/QC data, and chain-of-custody documentation also are attached. <br /> <br /> <br />RESULTS AND DISCUSSION <br /> <br />As shown on Table I, the March 2020 soil gas samples collected from SGMW1 and SGMW2 did <br />not contain methane at a concentration above the laboratory reporting limits of 0.00023% and <br />0.00024% for these samples, respectively. Methane concern at the site is not indicated by the <br />March 2020 data. <br /> <br />The soil gas samples collected from monitoring wells SGMW1 and SGMW2 in March 2020 did <br />not contain any of the tested VOCs at concentrations above the laboratory reporting limits, <br />except for chloroform. As shown on Table I, the concentrations of chloroform detected in soil <br />gas wells SGMW1 and SGMW2 were 24 micrograms per cubic meter (ug/m3) and 34 ug/m3, <br />respectively. <br /> <br />To evaluate the significance of the concentrations of chloroform detected in the soil gas samples <br />(particularly with respect to the potential for vapor intrusion into indoor air spaces at <br />concentrations that could be considered a human health concern), we have considered Regional <br />Screening Level s (RSLs) published by the US Environmental Protection Agency (USEPA) and <br />Environmental Screening Levels (ESLs) published by the San Francisco Bay Regional Water <br />Quality Control Board (SFBRWQCB). The applicable screening values for chloroform are shown <br />on Table I along with the analytical data from the soil gas monitoring wel ls. The published RSL <br />values are for indoor air VOC concentrations. For use in the screening evaluation for the subject <br />site, the indoor air RS L values have been adjusted by an attenuation factor of 0.03 to simulate the <br />attenuation that could occur from soil gas to the indoor air environment. As shown on Table I, the <br />concentrations of chloroform detected in the March 2020 soil gas monitoring well samples slightly <br />exceed the screening level considered (18 ug/m3). The source of the chloroform detected in the <br />soil gas monitoring wells is unknown. Chloroform occurs naturally in certain settings, although <br />anthropogenic sources are responsible for much of the chloroform in the environment. A <br />common anthropogenic source of chloroform in the environment is the discharge of chlorinated <br />drinking water. It is possible that the detected chloroform in the soil gas monitoring wells is <br />attributable to landscape irrigation in the areas of the wells utilizing municipal water. <br />Nonetheless, it is our opinion that the slightly elevated concentrations of chloroform detected at <br />the soil gas monitoring well locations would not represent an unacceptable vapor intrusion health <br />risk at the onsite warehouse building, due to the distance to the building and the nature of floor <br />slab system associated with the building. As mentioned above, the soil gas screening levels <br />considered were developed using an attenuation factor of 0.03, which most certainly is <br />excessively conservative considering that the floor slab for the onsite warehouse building is <br />seven inches thick and is underlain by a 12-inch section of cement treated subgrade. Given the