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§ 66261.30 BARCLO CALIFORNIA CODE OF REGULATIO* Title 22 <br />(5) it has an acute inhalation LC30 less than 10,000 parts per million <br />as a gas or vapor-, <br />(6) it has an acute aquatic 96 -hour LC50 less than 500 milligrams per <br />liter when measured in soft water (total hardness 40 to 48 milligrams per <br />liter of calcium carbonate) with fathead minnows (Pimephales prome- <br />las), rainbow trout (Salmo gairdnen) or golden shiners (Notemigonus <br />crysoleucas) according to procedures described in Part 800 of the "Stan- <br />dard Methods for the Examination of Water and Wastewater (16th Edi- <br />tion)," American Public Health Association, 1985 and "Static Acute <br />Bioassay Procedures for Hazardous Waste Samples," California Depart- <br />ment of Fish and Game, Water Pollution Control Laboratory, revised No- <br />vember 1988 (incorporated by reference, see section 66260.11), or by <br />other test methods or test fish approved by the Department, using test <br />samples prepared or meeting the conditions for testing as prescribed in <br />subdivisions (c) and (d) of Appendix II of this chapter, and solubilized, <br />suspended, dispersed or emulsified by the cited procedures or by other <br />methods approved by the Department; <br />it contains any of the following substances at a single or combined <br />concentration equal to or exceeding 0.001 percent by weight: <br />(A) 2 -Acetylaminofluorene (2 -AAF); <br />(B) Acrylonitrile; <br />(C) 4-Aminodiphenyl; <br />(D) Benzidine and its salts; <br />(E) his (Chloromethyl) ether (BCME); <br />(F) Methyl chloromethyl ether; <br />(G) 1,2-Dibromo-3-chloropropane (DBCP); <br />(H) 3,31-Dichlorobenzidine and its salts (DCB); <br />(I) 4 -Dimethylaminoazobenzene (DAB); <br />(J) Ethyleneimine (EL); <br />(K) alpha -Naphthylamine (1 -NA); <br />(L) beta -Naphthylamine (2 -NA); <br />(M) 4-Nitrobiphenyl (4 -NBP); <br />(N) N-Nitrosodimethylamine (DMN); <br />(0) beta -Propiolactone (BPL); <br />(P) Vinyl chloride (VCM); <br />(8) it has been shown through experience or testing to pose a hazard <br />to human health or environment because of its carcinogenicity, acute tox- <br />icity, chronic toxicity, bioaccumulative properties or persistence in the <br />environment. <br />(b) A waste containing one or more materials which exhibit the charac- <br />teristic of toxicity because the materials have the property specified in <br />subsection (a)(5) of this section may be classified as nonhazardous pur- <br />suant to section 66260.200 if the waste does not exhibit any other charac- <br />teristic of this article and is not listed in article 4 of this chapter and its <br />head space vapor contains no such toxic materials in concentrations ex- <br />ceeding their respective acute inhalation LC50 or their LCLO. The head <br />space vapor of a waste shall be prepared, and two milliliters of it shall be <br />sampled using a five milliliter gas-tight syringe, according to Method <br />5020 in "Test Methods for Evaluating Solid Waste, Physical/Chemical <br />Methods," SW -846, 2nd edition, U.S. Environmental Protection <br />Agency, 1982 (incorporated by reference, see section 66260.11). The <br />quantity in milligrams of each material, which exhibits the characteristic <br />of toxicity because it has the property specified in subsection (a)(5) of <br />this section, in the sampling syringe shall be determined by comparison <br />to liquid standard solutions according to the appropriate gas chromato- <br />graphic procedures in Method 8010, 8015, 8020, 8030 or 8240 in "Test <br />Methods for Evaluating Solid Waste, Physical/Chemical Methods," <br />SW -846, 3rd edition, U.S. Environmental Protection Agency, 1986 (in- <br />corporated by reference, see section 66260.11). The concentration of <br />each material in the head space vapor shall be calculated using the fol- <br />lowing equation: <br />QA 29.8ml I <br />CA = x x <br />MW mmole 2 x 10-6M3 <br />where C (in parts per million) is the concentration of material A in head <br />space vapor, Q (in milligrams) is the quantity of material A in sampling <br />syringe and MW (in milligrams per millimole) is the molecular weight <br />of material A. Where an acute inhalation LC50 is not available, an LC50 <br />measured for another time (t) may be converted to an eight-hour value <br />with the following equation: <br />Eight-hour LC50 = (t/8) x (t -hour LC50). <br />(c) A waste containing one or more materials which exhibit the charac- <br />teristic of toxicity because the materials have either of the properties spe- <br />cified in subsection (a)(3) or (a)(4) of this section may be classified as <br />nonhazardous pursuant to section 66260.200 if the waste does not exhibit <br />any other characteristic of this article and is not listed in article 4 of this <br />chapter and the calculated oral LD50 of the waste mixture is greater than <br />5,000 milligrams per kilogram and the calculated dermal LD50 is greater <br />than 4,300 milligrams per kilogram by the following equation: <br />Calculated oral or dermal LD50 = 100 <br />Ax n % <br />E <br />x = 1 TAx <br />where %Ax is the weight percent of each component in the waste mixture <br />and TAX is the acute oral or dermal LD50 or the acute oral LDLO of each <br />component. <br />NOTE: Authority cited: Sections 25141, 25159, 58004 and 58012, Health and <br />Safety Code. Reference: Sections 25117, 25120.2, 25141, 25159 and 25159.5, <br />Health and Safety Code and 40 CFR Section 261.24. <br />HISTORY <br />1. New section filed 5-24-91; effective 7-1-91 (Register 91, No. 22). <br />2. Amendment of table II filed 1-31-94; operative 1-31-94 (Register 94, No. 5). <br />3. Editorial correction of equation (Register 95, No. 36). <br />4. Amendment of subsection (a)(1) and NoTE filed 10-13-98; operative 11-12-98 <br />(Register 98, No. 42). <br />Article 4. Lists of RCRA Hazardous Wastes <br />§ 66261.30. General. <br />(a) A waste is a RCRA hazardous waste if it is listed in this article, un- <br />less it has been excluded from this list pursuant to 40 CFR sections <br />260.20 and 260.22 or is categorized as a non-RCRA hazardous waste <br />pursuant to section 66261.101. Wastes shall only be listed in this article <br />if they are listed in 40 CFR Part 261 Subpart D. <br />(b) The Department will indicate the USEPA Administrator's basis for <br />listing the classes or types of wastes listed in this article by employing one <br />or more of the following Hazard Codes: <br />Ignitable Waste (I) <br />Corrosive Waste (C) <br />Reactive Waste (R) <br />Acute Hazardous Waste (H) <br />Toxic Waste (T) <br />Appendix VII of this chapter identifies the constituent which caused <br />the USEPA Administrator to list the waste as a Toxic Waste (T) as in- <br />cluded in sections 66261.31 and 66261.32. <br />(c) Each RCRA hazardous waste listed in this article is assigned an <br />EPA Hazardous Waste Number which precedes the name of the waste. <br />This number shall be used in complying with the notification require- <br />ments of Health and Safety Code section 25153.6 and certain record- <br />keeping and reporting requirements under chapters 12 through 15, 18, <br />and 20 of this division. <br />Page 668 Register 98, No. 42;10-16-98 <br />