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risen about 10 feet since 2005. Depth to groundwater and groundwater elevations are summarized in <br /> Table 1. <br /> The horizontal and vertical gradients of groundwater flow at the site have been fairly consistent over <br /> time. The horizontal direction of the groundwater gradient in October 2022 was typical for the site and <br /> was generally to the northeast though somewhat more easterly in the on-site wells than off-site <br /> (Figure 3). The vertical groundwater gradients at the site have been measured at the site at the MW-5 <br /> well cluster between wells MW-5A and MW-513 and between wells MW-513 and MW-5C. The vertical <br /> gradients between these wells have been consistently downwards. <br /> 3.4 Background Groundwater Quality <br /> The quality of groundwater beneath the western portion of the City of Stockton, where the site <br /> is located, is being impacted by seawater intrusion from the Sacramento and San Joaquin River Delta <br /> (USGS, 2006). Seawater intrusion results in elevated concentrations of total dissolved solids (TDS). <br /> The site is located within the eastern edge of the seawater intrusion front(defined by the 300 <br /> milligrams per liter TDS contour) (CDM, 2001). It has been estimated that the seawater intrusion front <br /> is migrating to the east at approximately 150 to 250 feet per year(CDM, 2001). <br /> 3.5 Beneficial Uses of Groundwater <br /> Shallow groundwater in the western downtown Stockton area, in which the site is located, is not used <br /> for domestic or municipal water supply. The groundwater beneath this area has elevated TDS and <br /> chloride concentrations as a result of seawater intrusion from the Sacramento and San Joaquin River <br /> Delta (to the west of the site). The poor groundwater quality of western Stockton has resulted in <br /> importation of drinking water from eastern Stockton through the municipal water distribution system <br /> (CDM, 2001). <br /> 4 Constituents of Concern in Groundwater <br /> The results of on-site and off-site groundwater investigations and groundwater monitoring indicate the <br /> presence of COCs in groundwater beneath the site and the off-site area (AMEC Geomatrix, 2010a). <br /> The COCs include CVOCs and trace amounts of petroleum hydrocarbons constituents. The nature <br /> and extent of the primary COCs, the CVOCs PCE and TCE, in groundwater beneath the on-site and <br /> off-site areas were described in the RAP and are summarized in the paragraphs below. <br /> CVOCs consisting of the historically common industrial solvent PCE and its transformation byproducts <br /> are the primary COCs in groundwater at this site. CVOC concentrations detected in samples collected <br /> during the October 2022 monitoring event are shown on Figure 4 and in Table 2. <br /> PCE is the most prevalent CVOC measured in groundwater samples collected from on-site and off- <br /> site monitoring wells (Figure 4). PCE degrades in the environment to TCE, then to either 1,1- <br /> dichloroethene or 1,2-dichloroethene, then to vinyl chloride, and finally to ethane. PCE has been <br /> detected in groundwater beneath the site and the off-site area northeast of the site. The groundwater <br /> samples containing the highest PCE concentrations in the site vicinity were collected from borings on <br /> North Hunter Street south of the intersection with East Poplar Street and from the MW-5 and MW-10 <br /> well clusters (Figure 4). <br /> TCE is the second-most prevalent CVOC measured in groundwater samples collected from on-site <br /> and off-site monitoring wells (Figure 4). TCE at the site is likely present in groundwater as a <br /> degradation product of PCE. TCE is in groundwater beneath the site and the off-site area northeast of <br /> the site. Groundwater samples containing the highest TCE concentrations in the site vicinity were <br /> collected from borings on North Hunter Street south of the intersection with East Poplar Street and <br /> from the MW-5 and MW-10 well clusters (Figure 4). <br /> Additional COCs, including cis-1,2-dichloroethene, trans-1,2-dichloroethene, 1,2-dichloroethene <br /> (1,2-DCA), chloroform, and vinyl chloride, and the petroleum hydrocarbon constituents benzene, <br /> toluene, ethylbenzene, and xylenes have been detected in groundwater beneath the on-site and the <br /> off-site area northeast of the site, typically at concentrations significantly less than PCE and TCE. <br /> In general, the additional CVOCs are found at the same locations as TCE and PCE, except for <br /> 2019 Groundwater Interim Remedial Action Work Plan—Revision 3 Page 3 <br /> UniFirst Facility,Stockton,California <br /> Project No.0132902023 <br /> IM 3000s\13290\Archive\13290-177.docx <br />