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Composite samples for waste characterization will be collected from waste soil and water generated <br /> by well installation and development. These materials will be analyzed for volatile organic chemicals <br /> using U.S. Environmental Protection Agency (EPA) Method 8260 and metals using EPA Method <br /> 6010. Based on results from previous site investigations, it is anticipated that the waste materials <br /> generated by this phase of the investigation will prove to be non-hazardous. Accumulated waste will <br /> be disposed of off-site at disposal facilities authorized to accept them, based on the results of the <br /> characterization. <br /> 5.2 Injection Well Placement Evaluation <br /> Previous revisions of this work plan called for three injection wells to be installed hydraulically <br /> upgradient of the MW-5 well cluster(Figure 5). Monitoring data from the new MW-10 well cluster <br /> shows the plume beneath the site extents further northwest than earlier investigative studies <br /> concluded. Monitoring data from the MW-5 and MW-10 well clusters, as wells as data from the new <br /> well MW-11, will be used to refine placement of the injection well cluster. Previous experience at other <br /> sites has shown that sometimes the initial monitoring results from wells installed in relatively fine <br /> textured soils may not be representative of longer-term results. As such, UniFirst proposes to evaluate <br /> the results of at least three semiannual monitoring events for well MW-11 prior to proposing the final <br /> location of the new well cluster. The proposed well cluster location will be provided in the monitoring <br /> report submitted following three MW-11 monitoring events.. <br /> 5.3 Pre-Injection Monitoring <br /> Pre-injection monitoring will be used to establish groundwater quality conditions prior to injection of <br /> amendments and to measure populations of dechlorinating microorganisms. Dechlorinating <br /> microorganisms were detected in a soil sample collected from deeper soil in 2007. However, <br /> analytical methods available at that time were far less sensitive than current methods and <br /> distinguished just one type of microbe (dehalococcoides ethanogenes). Current methods can detect a <br /> variety of dehalogenating organisms. Depending on the results, these data can be used to identify <br /> which organisms are most prevalent and; therefore, which chlorinated compounds may be most <br /> readily degraded dechlorination or the absence of organisms likely to degrade select compounds, <br /> which could result in incomplete dechlorination. <br /> It is anticipated that adjustments to the amounts of each amendment described below may be made <br /> to the injection program described below depending on the evaluation of the pre-injection monitoring <br /> data. The selected method for the analysis is the QuantArray method from Microbial Insights, Inc. <br /> (Microbial Insights), in Knoxville Tennessee. A sample analytical report for dechlorinating <br /> microorganisms is provided in Appendix C. The results include the estimated number of each type of <br /> organism and charts showing the relative proportion of organisms capable of dechlorinating various <br /> CVOCs. <br /> An initial sampling event will be conducted on the MW-5 and MW-10 well clusters prior to well <br /> installation and will include field parameters and laboratory analyses. Before sampling, each <br /> monitoring well will be purged using a portable Grundfos stainless-steel electric submersible pump. <br /> Purging with the Grundfos pump will consist of removing at least four casing volumes or until the field <br /> parameters of the purge water(temperature, pH, and electrical conductance) have stabilized and the <br /> water is relatively clear and free of sediment. Other measured field parameters of the purge water will <br /> include oxidation reduction potential (ORP), dissolved oxygen, and a qualitative assessment of <br /> turbidity. This monitoring may be conducted as part of a semiannual monitoring event. <br /> Following purging and completion of the field measurements, groundwater samples will be collected in <br /> laboratory-prepared containers, labeled, and placed in an ice-cooled chest for delivery to the <br /> laboratory using chain-of-custody procedures. The Grundfos pump and associated tubing will be <br /> decontaminated before collecting samples from each monitoring well by washing with a Liquinox <br /> solution, rinsing with clean water, and rinsing again with deionized water. Water generated from <br /> groundwater sampling activities will be placed in 55-gallon drums for characterization and subsequent <br /> disposal. <br /> 2019 Groundwater Interim Remedial Action Work Plan—Revision 3 Page 5 <br /> UniFirst Facility,Stockton,California <br /> Project No.0132902023 <br /> I:\13000s\13290\Arch ive\13290-177.docx <br />