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Quarterly Monitoring Report – Third Quarter 2025 <br />www.arcadis.com <br />Forward Landfill 3Q25 Quarterly Mon Report 3 <br />monitoring points and constituents for the past year (third quarter 2024 through third quarter 2025) are included in <br />Appendix D. <br />The isoconcentration contours for tetrachloroethene (PCE), trichloroethene (TCE), cis-1,2-dichloroethene (cis-1,2- <br />DCE), carbon tetrachloride, and chloroform in shallow wells are shown on Figures 9, 10a, 10b, 11, 12, and 13, <br />respectively. The isoconcentration contours for PCE, TCE, cis-1,2-DCE, carbon tetrachloride, and chloroform in <br />intermediate wells are shown on Figures 14, 15, 16, 17, and 18 respectively. The isoconcentration contours for <br />PCE and TCE in deep wells are shown on Figures 19 and 20, respectively. <br />The following is a summary of the third quarter 2025 monitoring results: <br />x Non-statistical data analysis: The California non-statistical data analysis method (CNSDAM) was used for <br />VOCs detected in background samples less than 10 percent (%) of the time. Under the CNSDAM, a <br />monitoring well is to be resampled during the following quarter when concentrations of two or more VOCs <br />exceed their respective MDLs, or the concentrations of one or more VOCs equals or exceeds their respective <br />PQLs. Table 4 presents detection and upgradient program wells (MRP Section B.1(a) Table 1 [RWQCB <br />2024]) with VOC concentrations exceeding the applicable MDLs during third quarter 2025. There were no <br />MDL exceedances in the detection and upgradient program wells during the third quarter 2025 monitoring <br />period. <br />x Concentration limit (CL) thresholds. CLs were recalculated in fourth quarter 2024. In accordance with the <br />MRP (RWQCB 2024), the routine inorganic constituent monitoring data for the third quarter 2025 monitoring <br />period were compared to CLs established for the wells. Table 4 presents the CLs established for detection <br />and upgradient program wells (MRP Section B.1(a) Table 1 [RWQCB 2024]) and inorganic constituent <br />concentrations. There was one exceedance of the CLs for inorganic constituents during third quarter 2025, at <br />monitoring well MW-14A for nitrate as nitrogen (9.4 mg/L). <br />x PCE and TCE. The monitoring results suggest that the PCE and TCE plumes in the shallow zone (Figures 9 <br />and 10a) and intermediate zone (Figures 14 and 15) continue to remain separated between the Site and the <br />California Department of Corrections and Rehabilitation (CDCR) property. Additionally, the monitoring wells <br />installed at the CDCR property in August 2023 (AMW-58S, AMW-58M, AMW-59S, and AMW-59M) and in <br />second and third quarters 2024 (AMW-60S, AMW-60M, AMW-61S, and AMW-61M) continue to define and <br />monitor the distribution of carbon tetrachloride (Figure 12) and chloroform (Figure 13) near monitoring well <br />AMW-22S. Based on the third quarter 2025 monitoring results, the elevated carbon tetrachloride and <br />chloroform concentrations historically observed in monitoring well AMW-22S appear to be limited in extent. <br />However, the concentrations extend locally within the shallow zone and have migrated vertically and laterally <br />into the intermediate zone from monitoring well AMW-22S (Figures 17 and 18), following the northeast <br />groundwater flow direction. <br />The specified detection and upgradient program wells (MRP Section B.1(a) Table 1 [RWQCB 2024]) with VOC <br />detections and/or CL exceedances (Table 4) were identified for resampling in fourth quarter 2025 as required by <br />MRP Section B.4.h (RWQCB 2024). The RWQCB was notified of this exceedance in a letter dated October 29, <br />2025 (Forward 2025).