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BP #172 (Thrifty) - 4 - 9 March 2017 <br /> 7647 Pacific Avenue <br /> Stockton, San Joaquin County <br /> A total purgeable petroleum hydrocarbons (TPPH) concentration of 1,000 mg/kg was <br /> reported in MW-14 at 30 ft bgs in 2011. <br /> Additionally, while soil gas samples collected in 2012 were below the LCTP VI <br /> commercial thresholds for Scenario 4 where no bio-attenuation zone exists, three of the <br /> five samples were collected from shallower than 5 ft bgs. According to the Department <br /> of Toxic Substances Control (DTSC) guidance document Active Soil Gas Investigations <br /> --Advisory dated July 2015, "soil gas samples collected at less than 5 ft bgs may be <br /> subject to barometric pressure effects and prone to breakthrough of ambient air through <br /> the soil column." Samples SV-1 and SV-3 are therefore void as they were collected from <br /> a depth of 2 ft bgs. As these sampling locations are closest to the Site building, and <br /> therefore data from these samples is most critical to evaluating the VI risk, additional soil <br /> gas sampling is needed in order to properly evaluate the VI risk. In order to confirm the <br /> VI risk at the Site, an additional round of soil gas sampling should be performed <br /> approximately 6 months after remediation has been completed. <br /> 5. The Site meets LTCP Direct Contact and Outdoor Air Exposure criteria. Hydrocarbon <br /> concentrations in the top 10 feet of soil are below the LTCP criteria, as detailed in Table <br /> 3 below. <br /> Table 3 — LTCP Direct Contact and Outdoor Air Exposure Criteria and Associated Site Data <br /> LTCP Thresholds <br /> Residential Commercial/Industrial Utility Site Maximums <br /> Chemical Worker <br /> Oto5ftbgs 5to10ft Oto5ftbgs 5to10ft OtolOftbgs OtaSft 5to10ft <br /> (mg/kg) m 9k (mg/kg) bgs(mg/kg) (mg/kg) bgs bgs <br /> Benzene 1.9 2.8 8.2 12 14 <0.02 0.006 <br /> Eth (benzene 21 32 89 134 314 0.020 <0.010 <br /> Naphthalene 9.7 1 9.7 45 1 45 1 219 1 Unknown Unknown <br /> PAH 0.063 NA 0.68 NA 4.5 Unknown Unknown <br /> 6. In order to properly assess the nature of the release, waste oil tank samples should be <br /> analyzed for total petroleum hydrocarbons as gasoline (TPHg), TPH as diesel (TPHd), <br /> total oil and grease (TOG), full-scan volatile organic compounds (VOCs) and semi-VOCs <br /> (SVOCs), polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), <br /> and Title 22 metals.- According to the November 1995 Tank Removal Report, the <br /> sample collected from the former waste oil tank basin was analyzed only for total <br /> purgeable petroleum hydrocarbons (TPPH), TPHd, TOG, and benzene, toluene, <br /> ethylbenzene, and xylenes (BTEX). <br /> In the Work Plan due 19 May 2017, please include a proposal for the collection of <br /> shallow soil in the vicinity of the former waste oil tank, with analysis to include: TPHg, <br /> VOCs, SVOCs, PAHs, PCBs, and Title 22 Metals. Please also include a proposal for <br /> the collection of a shallow soil sample outside of the hydrocarbon impacted area in order <br /> to establish naturally occurring background metals concentrations for comparison. <br /> 7. Recent Groundwater Monitoring Reports (GMRs) submitted have include figures <br /> depicting the distribution of dissolve-phase concentrations in groundwater via chemical <br />