Laserfiche WebLink
Selected Application Recommendations <br />Methanol and Other Gasoline -Alcohol Blends <br />Apart from ethanol, methanol is also widely considered <br />in gasoline applications, and in contrast to fermentation <br />of sugar or polysaccharides, methanol is ordinarily <br />made from carbon monoxide and hydrogen containing <br />gas associated with gasification or various synthesis <br />processes. Methanol has good octane properties, but <br />displays similar, if not more problematic concerns over <br />water, volatility, and phase separation. As in the case <br />of ethanol, resins, especially those with good crosslink <br />density, can display excellent resistance to methanol <br />based blends of gasoline. <br />Longer chain alcohols, such as butanol may find <br />increasing favor over ethanol due to butanol's lower <br />polarity, reduced fuel compatibility problems, and closer <br />resemblance to volatility and energy content of many <br />gasoline components. Historically, there have been <br />many cycles of interest in alcohol fuels and other fuel <br />additives, such as MTBE, and this is likely to continue <br />until energy policies become more definitive. Thus, it <br />is always good to select resins which are resistive to <br />all gasoline formulations which might be reasonable <br />to expect in the future. This is especially important in <br />regard to the octane properties offered by alcohols. <br />Octane requirements have significant implications <br />affecting refinery reforming capacity and in allowing <br />higher engine compression ratios necessary to meet <br />mileage standards mandated for newer automobiles. <br />Methanol has many other future implications for use as <br />a direct fuel for internal combustion engines and is in the <br />early stage of development for direct use in fuel cells. <br />Ore Extraction & Hydrometallurgy <br />Apart from conventional mining, smelting, and high <br />temperature ore reduction, extractive metallurgy <br />based on aqueous chemistry has evolved to permit <br />recovery of metal from ores, concentrates, or residual <br />materials. Metals produced in this manner include gold, <br />molybdenum, uranium, and many others. <br />The first step involves selective leaching of the metal <br />from the ore using a variety of acidic or basic solutions <br />depending on mineral forms or other factors. Acids are <br />commonly sulfuric or nitric acid, and common alkaline <br />materials include sodium carbonate or bicarbonate. <br />The leaching can be done on pulverized or specially <br />prepared ores, but some processes are amenable to <br />in-situ contact with the ore, which is sometimes called <br />solution mining. <br />Leached ores are then concentrated by a variety of <br />solvent or ion exchange type extraction processes. The <br />final step involves metal recovery and purification using <br />electrolysis (such as electrowinning) or various gaseous <br />reduction or precipitation processes. <br />Many of these unit operations can induce galvanic or <br />stress related corrosion to metals. Consequently, FRP <br />has a long history of successful use in hydrometallurgical <br />applications. <br />Potable Water <br />Piping, tanks and other components used to contain or <br />to process potable water must conform to increasingly <br />stringent requirements, such as those of the National <br />Sanitary Foundation (NSF), Standards 61 and 14. <br />Standard 61 entails a risk assessment to be performed <br />by NSF on extracted organics and other health related <br />features. It is always the responsibility of composite <br />products to ensure that such standards are met. <br />Composites based on the DION® IMPACT 9102 series <br />of vinyl esters have conformed to requirements of <br />NSF/ ANSI Standard 61 as applicable to drinking water <br />components. Resins, such as DION® 6631 also conform <br />to international standards associated with drinking <br />water, such as British Standard 6920. <br />When manufacturing composites for drinking water <br />applications it is good practice to obtain a good cure, <br />including post -curing and to wash exposed surfaces <br />thoroughly with a warm non-ionic detergent before <br />placing the equipment into service. It is also good to <br />use minimal amounts of plasticizers or solvent carriers <br />during fabrication. <br />