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Mr <br />Selected Application Recommendations <br />Radioactive Materials <br />Polymer -matrix composites in general have a very low <br />neutron cross-section capture efficiency. Therefore, they <br />are very well-suited to the containment of radioactive <br />materials, even at relatively high levels of radioactivity. <br />Testing of uncured DION® 382 by Atlas Chemical <br />Laboratories demonstrated that this resin is highly <br />resistant to molecular weight changes at dosages up <br />to 15 million rads. Extrapolations based on this study <br />estimate that DION® 382 may be able to withstand 50 <br />to 100 million rads. For reference, the lethal radiation <br />dose is about 400 rads. Given the hazardous nature of <br />radioactive materials, testing is recommended before <br />actual use in high radiation environments. <br />Sodium Hydroxide and Alkaline Solutions <br />Alkaline solutions can attack the resin, usually by <br />hydrolysis of any ester groups. Glass fibers and other <br />silica based materials can also be attacked or digested. <br />This leads to a very characteristic type of wicking and <br />blistering, as well as fiber blooming. Dilute sodium <br />hydroxide is often more aggressive than the more <br />concentrated solutions. This relates to the fact that <br />NaOH is a very strong base, but at higher concentration <br />there is equilibrium between dissolved and solid phase <br />NaOH, which reduces the caustic effects. Epoxy based <br />vinyl esters and bisphenol-A based polyesters display <br />exceptional resistance to caustic. <br />Even though novolac based vinyl esters are well- <br />regarded for excellent corrosion and thermal resistance <br />in many applications, it is often observed that novolac <br />based resins can show somewhat inferior caustic <br />resistance. Laminates based on novolac vinyl esters <br />exposed to caustic have a tendency to develop a pinkish <br />color incipient to failure. It is speculated this is due to <br />formation of phenolates from the novolac structure. <br />There is widespread belief that it is advisable to use <br />synthetic surfacing veils versus C -glass in caustic <br />applications. However, controlled laboratory tests <br />usually reveal no clear-cut or distinct advantages to a <br />synthetic veil, and there is a long history of use of C -veil <br />in alkaline environments. <br />The synthetic veil allows an increased resin content at <br />the surface to ostensibly afford more protection. On the <br />other hand, the resin rich areas can make the surface <br />more prone to cracking and can, at times, present more <br />fabrication difficulties. <br />