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` Material Safety Data Sheet 'a"`pu
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<br /> I. R.Simplot Company.
<br /> AgriBusiness
<br /> Trade Name: sulfur Trioxide
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<br /> . Registration Na: , None
<br /> PRODUCTCHEMICAL • COMPANY-INFORMATION
<br /> Manufacturer or Formulator, J.R.Simplot Company Product name: Sulfur Trioxide
<br /> PA.Box 70013 Common Name: Sulfuric Anhydride
<br /> Boise,ID 83707 Chemical Type: Acid Gas
<br /> Emergency Phone-Chemtrec: 1-800-424-9300
<br /> SECTION 2 COMPOSITIONIINFORMATION ON INGREDIENTS
<br /> Chemical Name and Synonyms C.A.S.No, Chemical Formula - WTI/6 TLV PEL
<br /> Hazardous
<br /> sulfur Trioxide 7446-11-9 SOS 0-11%(vol) 1 mglm' 1 mgtm'8 Hr TWA
<br /> Ingestion: Not normal route of entry
<br /> Inhalation:. Extremely irritating. Reacts with moisture from mucus or lungs to form sulfuric add. Thermal or chemical bums are possible.
<br /> Eye Contact: Irritation,bums,comeal necrosis(loss of sight).Reacts with moisture from mucus or lungs to form sulfuric_acid. Thermal or
<br /> chemical burns are possible.
<br /> Skin Absorption: -Not normal route of entry
<br /> Skin Contact: May cause Irritation on skin. If skin is wet S03 will react to form sulfuric add. Thermal or chemical bums are possible.
<br /> Effects of Overdose: LOCAL: Conjunctivitis,corneal necrosis,dermatltis,skin bums,ulceration. RESPIRATORY: Irritation of the nose and throat,
<br /> laryngeal edema,bronchitis,pneumonia,pulmonary edema.
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<br /> Emergency and First Ald Procedures, Treatment is symptomatic.
<br /> Ingestion: Rlr)se mouth with large amounts of water. DO NOT INDUCE VOMITING. If patient is conscious give milk mixed with egg
<br /> whites or as much water as possible.
<br /> Inhalation: Remove person from exposure area to fresh air and support breathing.
<br /> Eyes: IMMEDIATELY flush eyes with fresh running water for 15-20 minutes.
<br /> Skin: Give continuous flow of water to wash material off body, Remove contaminated clothing(under a shower if possibld)and
<br /> subject patient to deluge-type shower,if possible. Treat for shock. Prompt medical consultation is essential.
<br /> • 5 FIRE FIGHTING MEASURES
<br /> Extingutshing Media: Fires involving small amounts of combustibles may be smothered with suitable dry chemicals. Use water on '
<br /> combustibles In vicinity of this material but use care,as water applied directly to their acid results In evolution
<br /> of heat and causes splattering.
<br /> Special Fire Fighting Procedureg: Avoid any contact with acid, Wear full protective rubber clothing,gloves,boots,wear self-contained
<br /> breathing apparatus or suitable respirator.
<br /> Unusual Fire and Explosion Hazards: Not flammable but highly reactive and can cause ignition by contact with combustible materials.This is a
<br /> very powerful acidic oxidizer which can ignite on contact with many materials;i.e.,acetic add,acetone
<br /> cyanhydrin,(acetone+HNO3),(acetone+K2Cr207),acetonitrile,acrolein,acrylonitrile,(acrylonitrile+H20),
<br /> (alcohols+1-1200,allyt alcohol,allyl chloride.NH.OH,2-amino ethanol,NH4 triperchromete,aniline,
<br /> (bromates+metals,BrFs,n-butyraldehyde,carbides,CDHC2,chiorates,(metals+chlorates),CiF;,
<br /> chlorosulfonic add,Cu,N,diisobutylene,(dimethyl benzyicarbinol+HA),epichlorohydrin,ethylene
<br /> cyanhydrin,ethylene diamine,ethylene glycol,ethylene imine,fulminates,HCI,1-12,IFr(Indene+HNO,'+
<br /> glycerides,p-nitroluene,perchlorates,HC104,(Col-le+permanganates),pentasilver trlhydroxydlamino .
<br /> phosphate,(I-phenyl-2-methyl propyl alcohol+H202),P.P(OCN)2,picrates,potassium-tert-butoxide,KCIO3,
<br /> KMnO4,(KMnO.+KCq,KMnOe+H2O)beta-propiolactone,RbHCa,propylene oxide,pyridine,NA,Na2CO3,
<br /> NaOH,steel,styrene monomer,water,vinyt acetate,(HNOa+toluene).
<br /> SECTION
<br /> Environmental Precautions: This is an intermediate In the manufacture of sulfuric acid. Sulfuric Acid has a reportable quantity of 100D tbs.and should
<br /> be kept out of all watercourses and bodies of water. Do not contaminate any watercourse or body of water by direct
<br /> application,cleaning of equipment or disposal.
<br /> Steps to be taken In case material Is released or spilled:
<br /> Treat with extreme caution, Zone off contaminated area. Sulfuric acid-may farm as a result of gaseous release and
<br /> should be neutralized with soda ash or 0me.Organic or combustible materials such as sawdust or rags should never be
<br /> used to soak up spills. Wear full protective clotting(add protective slicker suit,respirator or self contained breathing
<br /> apparatus,acid faceshield).
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