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<br /> �� k�!ik���"�'11_. '+1-'� ?�'`4a '�r� w�F i•I .�._
<br /> F
<br /> i' 1255 2,5-Bis(1-azirldiny[)-3,6-bis(2-methdxyethoxy)-1,4-benzoquinone
<br /> 'h #
<br /> !' 1 USE n
<br /> "In vacuum pull
<br /> solid from ethanol. Hemihydrate, mp 288-289' (dec). -uv ride]; 1,1'-decamethylene-4,4'-(1,10-decamethylenediitni ; A l}.
<br /> max(H2O) 260,415 urn (e 72700, 16300). no)bis[quinaldinium chloride], Salvizol. C�H5BC12Ne; mol X1264: B2SmArk Br(
<br /> 1 ITHERAP CAT: Antineoplastic. wt 665.84. C 72.16%, H 8.78%,Cl 10.65%,N 8.41%. Prepn, e=i¢)6is(azo)]8is[6•meth
<br /> Rll
<br /> II i Stark, Brit.pat. 695,b90(1960). de• CJS Basic Brown
<br /> 1256. 2,5-Bis(1-azirldinyl)•3,6-bis(2-methoxyethoxy)- s toluene-2,4-d
<br /> .
<br /> I �!
<br /> 1,4-benzoquinone. 2,5•lIIS(I•a2iridinyt)-3,6-his(2-metlroxy-
<br /> ,, I Bssrnark Brown 53; Ve
<br /> ethoxy)-2,5-cyclohexudiene-l,4-dione; Bayer E 39 soluble. CHgCH2CH2CH2CHZCF12CH2CH2CHxCH2 ,t
<br /> C26,122N206;mol wt 338.35. C 56.79%,H 6.55%x, N 8.287., 1 I
<br /> repn: Gauss, � tion ol-toluene-2,4-dia
<br /> l O 28.37%. PGPetersen, Angew. em.Ch69,252 NH NH
<br /> I I x� Index vol 4_ 43rd ed., 1
<br /> 1 (1957); Brit. pat. 793,796 (1958 to Bayer). Antineopiastic
<br /> activity in vitro: M. Akhtar et at., Can. J- Chem. 53, 2891 I 2C1 1 xx
<br /> (1975); J. S. Driscoll et al., J. Pharm. Scf. 68, 185 (1979).
<br /> � CH2C112CH2C1l2CH2CH2CHzCH2CH2CH, 4AI yH211 N=N
<br /> ,l CN OCR 2CH2OCH 3 ; } - -
<br /> CH3OCH ZCH 2O NJ THERAP CAT: Antiseptic,disinfectant. - _--:.c
<br /> k"� a I260. Bis(p-dimethylamiitobenzylidene)benzidine. N iDark brown solid.
<br /> {l N'•Bis([4-(dintethylumirto)phenyl]methylene]jl,l'-biphen
<br /> ?.sol methanol,Ce
<br /> I: Gray needles from petr ether,mp 79-80.5': Gauss,Peter- yl]-4,4'-diamine; 4,4'-di(4-dim ethylarninobenzylideneam
<br /> sen, Med. Che (Bayer) 7, 649 (1963), C.A. 60, 2875i ino)biphenyl; bis(4.dimetltylaminobenzylidene)-p,p'-diami f lff
<br /> m. itc..- ,xisQl to benzene,
<br /> I..e p y iqk �vhtch'gn dilution tun
<br /> (1964), nodihenyl; N.N'-bis(p-dimethlaminobcnzal)benzidine
<br /> 11 C H N; mol wt 446.57. C 60.68%, H 6.77%, N 12.55% p Fk Btves violet solo which
<br /> 1257. Bisbentiamine. N,N'-[Uithiobi.a[2-[2-(benzoyl- ae 3o a 2kree base,,C2tH,4Ns,
<br /> Prepn from hydrazobenzene and p-dimethylaminobenzal t
<br /> ox y)ethyl]-I•meshyf-2,I-ethenediyl]]bisjN[(4-amino-2- 1 nlp 130135. Very sl
<br /> 11 dehyde: •Sachs, Whittaker, Der. 35, 1435 (1902).
<br /> tnethyl-5 pyrimidinyl)tnethyl]formantide]; N,h jdithiobis- acetone ,
<br /> [2-(2-hydroxyer)tyl)-l-metltyfvinylene]]bisjN-[(4-amino•2- cx Cx " A, �t]5E As textile dye,1
<br /> +liJ� methyl-5-pyrimidinyl)methyl]formamide] dibenzoate; Oben- 13 _ 3 r��51265;-.Bi nark $rot
<br /> I Ilk zoylthiamine disulfide; Beprocin; Beston. C3sHazNsO,S,; N \ ex=x / N=CH N 1
<br /> mol wt 770.95, C 59.20%, H 5.49%q N 14.54%,O 12.45%,5 — — �a � ` bts[I[3-bpnzenediamine]
<br /> 8.32%. Prepn: Brit.pat.922,444(1463 to Tanabe Seiyaku) cx3 3 ]a 4,4 m: hcn lenebis(a
<br /> �. { $ %drlsahioide{ C.I. 2100(
<br /> I curresp to U.S. pat. 3,109,040 (1963); Yarugi et al., Ann.hap z molnvt-aJ�,33, C 51.Sr
<br /> g Re Takeda Res. Lab. 27 25 (1968), C.A. 70, 96741m Yellow crystals from nitrobenzene; mp 318% Reacts with r
<br /> P' y g Pfepd,by.teaOdon of m
<br /> (1968);Imai, Miyaji, Ger,pat. 1,954,519 (1971 to Hitachi), solutions of the alkali tungstates to give a cinnabar-red pre
<br /> t acrd .J. Welcher, G
<br /> C.A. 75, 63821n(1971). cipitate.
<br /> l Nostrand Cc.,New Yo;
<br /> USE: Determination of tungsten: Hovorka. Coll. Czech
<br /> 1 (3rd ed 1'"971)p 4154.
<br /> lI x N Chem. Commun. 10, 518 (1938), CA- 33, 1624(1939).'
<br /> CH3 CH3 4CH
<br /> 3 1261. Bis(1,2-dimethylpropyl)borane. DisiamA orane 1 , 4.
<br /> I ;t�1 xk I I IIx
<br /> di
<br /> -sec-isaamyfbotine; bis(3-methyl-2-butyl)borane. xx2
<br /> Cto
<br /> I'1
<br /> —2-- 7c—c—ss—C=C—N—[[2C \ H23 B;mol wt 154.10. C 77.94%.H 15.04%,B 7A1%. Prepn Y ]
<br /> Brown, Zweifel, J.Am. Chem. Soc. 83, 1241 (1961). Use in azx N=x
<br /> ,ell i,l x11Clio CHxx
<br /> CHCHOya! \.
<br /> I
<br /> 2 Z 2 2 selective reductions: G. W. Kabalka, C. F. Lane, Chem
<br /> I
<br /> CH2 CH2 _ Tech. 6, 324(1976). r r¢
<br /> l /
<br /> CPO OOC3
<br /> � - CH CN—CH—BH—CH—CNCH3
<br /> CH 3 CH 3 CH 3 CH "-�,.Plackish-brown powd
<br /> � ) v ;&a ni,-Cellosoive-prac
<br /> 4 i I,] Prisms from alc, mp 146-147°. bon,tetrachloride. In ,
<br /> ,I Crystals, mp 35-40 Unstable to air. carted tra acid
<br /> I' THERAP CAT: Vitamin Bt source. gives e
<br /> 1, usE: Selective reagent for steric control.of hydroboration ,user As a'ti xtile dye,
<br /> 1256. Bis(p-chlorophenoxy)methane. I,7'-[Methylene- of aEefins
<br /> r�I`1j i bis(oxy)]bis[4-chloro]benzene; di-(p-chlorophenoxy)meihane; _ .'k 1266 :$ts(!I•met$ylan
<br /> 1262. is(2-eth the Phthalate. l,2-Benzenedicarb bu[at 101c::add 1,4-bis
<br /> DCPM; K 1875; Neotran. C13EI,oCl202; mol wt 269.12. C !
<br /> 1,,,, axylic acid rs( -et ylhexyi)ester, t -ethylhexyl)phthalate dlhexyl sodium sulfosua
<br /> ,', 58.02%,H 3.75%,Cl 26.35%,O 11:89%. Prepd from p-chlo- ,�
<br /> dioctyl phthalate; Octoil. C24H38Dy; mol wt 390.54..- G 11 71a0 S;
<br /> rophenol and dichloromethane: Moyl, U.S. pat. 2,503,207 tb xt 7 mo] wt
<br /> 73.80%, H 9.8k%. 0 16.39%. Prepn: Garner,Watson,US 592 o b(1950 to Dow); from sodium phenolate and drehlorometh� 28;83%, S 8.25
<br /> � s
<br /> n, Lowry, J. Arm Chem. Soc. 73, 1872 (1951), pat. 2,508,911 (]95D to Shell); IIrit. pat. 747,260 (1956 to� sttlFdsuccinic acid mono
<br /> Chemische Werke Huls). Y e ^tytth the diliexyl ester. P
<br /> 616on. maleic :
<br /> 1 —� 0—Ci1.2 0 Cl COOcx2cH(C2Hc)(CH2)3cH3 - t� aBod�um ESIsulCtte; .laege
<br /> COOCH C11 Cc x HCH } CR j at446,568; 1'r,
<br /> from petr ether. mp 69.7-70.2. bp6 189-194'.
<br /> Ir at 25• in gl100 ml: acetone 189; benzene 40: ` H2
<br /> I "roon tetrachloride 28; methanol 0.5; ether 87. Practically t
<br /> insol in water,petr oils. LDSe orally in rats: 5.8 glkg;lethal Note: This substance may reasonably be anticipated to b4 '.V' N:o3s
<br /> k` Concn for rats in air: 16,000 ppm. a carcinogen: Fourth Annual Report on Carcinogens WT. �
<br /> I usEt Miticide. Toxicity: No record of human poisoning. 85-002, 1985) p 83.
<br /> 2� Animal expts show low toxicity,but large doses have caused. USE: In vacuum pumps. F
<br /> liver injury, Effects may be similar to,but less severe than, �ivarlable as wh21e,-sliI
<br /> . s -eyexyeacae. ecaneoc acd brt, I✓1a51 be"'s
<br /> DDT,q.v.,Spencer et af.,Arck Ind.Hyg. Occup.Med. 1,341 1263Bi (2thlhl) SbtDdiiioaked to dissolm h❑
<br /> (1950) (2-ethylhexyl) ester di(2•ethylhexyE) Sebacate; Octoil 8,} 'Water'. $olubiEi£y i
<br /> Plexol 201. C76H5e04;mol wt 426.456. C 73.19%, H 11.81 447 gV, Tvfazimum concl
<br /> 1259. Bisdequaiinium Chloride. 6,7,8,9,10,77,12,13,14,- O 15.007.. CH3(CHz),CH(CZHS)CH,OOC(C13t)sCOOCHt� :the welting agent is sol:
<br /> I5,I6,17,24,25,26,27,28,29,3U,3I,32,33-Aacosahydro-35,37- CHCCZHS)(CH2)3CH3. Prepn: Bruno, U.S. at. 2,628,SQ�9� j nbr 8%1VaNO3(slight
<br /> 9 dimethyl-5,34:78,23-diethenodibenzo[b,r](I,S,I6,20]tetraaza- (1953 to Pittsburgh Coke & Chemical);'Brit. pat. 747,1 a oil oleic acid, aceto
<br /> i f •,[ : cvc1otriacontine-23,34-diium dichloride; N2,Nt'-decamethyl- (1956 to Chemische Werke Hills), $ethanol" benzene, hot
<br /> ene-N4,N4'-decamethylenebis[4-aminoquinaldinium chlo- Liquid, d2s 0.911.9, no 1.4496, k i
<br /> Page 194 Consult the cross index before using this section. c
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