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M. Scott Mansholt -2- 2 August 2005 <br /> ChevronTexaco <br /> Crude Oil Management &Remediation <br /> (pumped through the OVP and TAOC pipelines) such as San Joaquin Valley crude or Kern River crude <br /> have API gravity values of 13 to 15 placing them in the asphaltic-base range of crude oil classification. <br /> Heavy crude oil and the primarily fine-grained geological materials (relatively low hydraulic <br /> conductivity)present in the subsurface results in crude oil mobility being very limited. According to the <br /> report, San Joaquin and Kern River crude oils, at ambient groundwater temperatures, are significantly <br /> more viscous than other petroleum products such as gasoline, diesel, and light crude oil. Thus, the high <br /> viscosity of the crude oil severely minimizes the mobility thus limiting its flow into a well. Significant <br /> reductions in viscosity are not achieved until heavy the unsaturated eated to greater than zo e and water table t0echnicalyF) <br /> Consequently,the conditions make removal from <br /> infeasible and/or not economically viable. <br /> In addition to providing a description of the dynamic processes for movement of the weathered crude oil <br /> in the subsurface,the relationship between the various components is expressed mathematically. By <br /> using numerical values for the different components of crude oil in soil and groundwater, i.e., size and <br /> permeability/porosity of the geologic materials (generally fine sand, silt and clay) the report discusses <br /> combined with the crude oil's specific gravity and viscosity, it was concluded that free product removal <br /> is limited. <br /> In general, the evaluation described a variety of alternatives to address remediation of the weathered <br /> crude oil in soil and groundwater under the conditions described. The methods described included: mass <br /> removal of petroleum-impacted soil, extraction of product floating on groundwater,pump and treat <br /> impacted groundwater, or leaving free product and/or elevated TPH concentrations in soil in place. In <br /> the event it is subsequently determined that the latter may be the only viable option, a plan for <br /> implementing in-place management/natural attenuation(i.e.,monitored natural attenuation) combined <br /> with regulatory controls could be included as part of the consideration for possible NFA site closure. <br /> We have the following comments: <br /> • A discussion of one or more viable remedial options may be applicable for the HPP sites and <br /> each will be considered on a site-to-site basis even though the source is the same (crude oil). <br /> Depth to groundwater, the extent and concentration of petroleum hydrocarbons present, and the <br /> variable subsurface conditions will be evaluated in conjunction with the petroleum-impacted soil. <br /> • When considering a site for a no further action(NFA) closure request, the justification for the <br /> remedial option(s) selected, if any, should be described. The request may include a narrative for <br /> the different processes being considered for the conditions observed; each site will be addressed <br /> accordingly. <br /> Prior to evaluating an NFA request for closure, regardless of the remedial option, soil and <br /> groundwater characterization must be complete and approved by Regional Board staff, and a <br /> Human Health Risk Assessment (LIRA)must be reviewed and approved. <br />