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Mr. Gregory Torlai, Jr - 2 - • 11 January 2008 <br /> H & H Marina <br /> Groundwater at the Site is characterized as occurring in two zones. The shallow zone occurs <br /> from the surface to 14 feet below ground surface (bgs), and a deep zone occurs from 50 to 60 <br /> feet bgs. <br /> Groundwater monitoring and reporting requirements for the site are set forth in Monitoring and <br /> Reporting Program (MRP) No. R5-2004-0828. Groundwater monitoring is conducted on a <br /> quarterly basis. A before and after comparison of petroleum hydrocarbon detections in <br /> groundwater as reported in the 16 August 2007 Quarterly Report-Second Quarter 2007 <br /> (Second QMR) and the 17 December 2007 Quarterly Report-Third Quarter 2007 (Third QMR) <br /> is tabulated below. Monitoring for the Second and Third QMRs was conducted on 7 June and <br /> 7 September, respectively. <br /> Well Number MW-2 MW-3 MW-4 MW-2 MW-3 MW-4 <br /> Constituent June 2007 September 2007 <br /> u /L <br /> TPH 110 <50 3,200 190,000 140 13,400 <br /> TPHd <50 <50 <50 <50 <50 <50 <br /> Benzene <0.5 <0.5 <0.5 3,500 <0.5 <0.5 <br /> Toluene <0.5 <0.5 <0.5 19,000 16 14 <br /> Ethyl benzene <0.5 <0.5 7.6 5,600 9.2 960 <br /> Xylene <0.5 <0.5 240 27,400 31.1 130 <br /> MTBE 13 <0.5 25 18 <0.5 38 <br /> TBA 5,300 500 <5 410 <0.5 <5 <br /> Legend <br /> ug/L micrograms per liter <br /> < less than <br /> TPHg total petroleum hydrocarbons as gasoline <br /> TPHd total petroleum hydrocarbons as diesel <br /> MTBE Methyl tertiary butyl ether <br /> TBA Teritary butyl alcohol <br /> Groundwater samples collected from monitoring wells MW-2 and MW-4 historically have <br /> contained the highest concentrations of constituents of concern. However, during June 2007, <br /> TPHg was detected at 1,400 ug/L in upgradient shallow well MW-12 for the first time since <br /> monitoring began in this well in 2003. Deep zone well MW-7 also contained TPHg at 1,400 ug/L <br /> as well as benzene, toluene, ethyl benzene, and xylene (BTEX). These constituents were <br /> previously detected in MW-7 in 2002 and 2005 but were non-detect (ND) in both MW-7 and <br /> MW-12 in September 2007. The highest concentrations of TBA have been observed historically <br /> in MW-2 and MW-3. Concentrations in MW-2 ranged from <br /> 72 ug/L in September 1997 to 5,300 ug/L in June 2007. <br /> Operation of the interim groundwater treatment system commenced in June 2005 under <br /> general National Pollutant Discharge Elimination System (NPDES) Permit No. CAG915001, <br /> Order No. 5-00-11938. Groundwater is extracted from one 6-inch diameter extraction well <br /> (EW-1) screened in the shallow zone from about 4 to 14 feet bgs' and located about 40 feet <br /> and 100 feet downgradient from MW-2 and MW-4, respectively. MW-3 is about 40 feet cross <br /> Groundwater Extraction Feasibility Test Report, 24 July 2003, Advanced GeoEnvironmental Inc. <br />