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17 November 2006 <br /> AGE-NC Project No. 01-0865 <br /> Page 3 of 5 <br /> was not reported in the samples collected from R-2 or directly below the point of discharge pipe <br /> (POD). <br /> No constituents of concern were reported in the samples collected on 16 November 2006.Laboratory <br /> reports for samples collected on 0 1, 14 and 16 November 2006 will be including in the fourth quarter <br /> monitoring report. <br /> The fuel oxygenate TBA was reported at the downstream port of each vessel for both the <br /> 01 November 2006 sampling and 14 November 2006 re-sampling. Wastewater with TBA was <br /> discharged to surface waters at a concentration of 1,200µg/l.The last effluent sampling for TBA was <br /> on 06 July 2006; at that time, TBA and all other constituents of concern were not reported above <br /> laboratory detection levels. Based upon the quantity of wastewater discharged from 06 July to <br /> 14 November 2006(49,829 gallons)and the concentrations of TBA reported on 06 July 2006 (<10 <br /> µg/1) and 01 November 2006 (1,200 µg/1), approximately 0.25 pounds of TBA was discharged to <br /> surface waters. Alternatively, based upon the quantity of wastewater discharged from 01 to 14 <br /> November 2006(4,480 gallons)and the concentration of TBA reported 01 November(1,200 µg/1) <br /> and 14 November 2006(1,100 µg/1) approximately 0.04 pounds of TBA was discharged to surface <br /> waters. Based upon these calculations,AGE estimates between 0.04 and 0.25 pounds of TBA was <br /> discharged to surface waters. <br /> In accordance with the General Order, effluent sampling for TBA was reduced from monthly to <br /> quarterly after the monthly sampling event in January 2006.TBA had been infrequently reported in <br /> the influent sample,in August 2005,May 2006 and June 2006 at concentrations of 4,100 µg/1,5,000 <br /> µg/1 and 310 µg/1, respectively. However, in the October 2006 influent sampling event, TBA was <br /> reported at 3,700 µg/1. <br /> MTBE concentrations reported in the influent sampling have ranged from <0.5 µg/1 to 240µg/l from <br /> January 2006 to November 2006. <br /> Carbon change-out had not been performed at the site. Initial discharge estimates of 4,320 gallons <br /> per day have not been achieved at the site.As of 14 November 2006, 509,100 gallons of wastewater <br /> have been discharged for a calculated rate of approximately 1,000 gallons per day (509 days of <br /> discontinuous operation).Additionally,influent MTBE concentrations have decreased dramatically <br /> in 2006 from an average of 2,461 µg/1 in 2005 to 87 µg/1. Discharge flow rate has been <br /> approximately 23% of initial estimates and 2006 influent MTBE concentrations have reduced to <br /> approximately 96%of 2005 influent MTBE concentrations indicating a significantly longer period <br /> before carbon change-out would be necessary. Excluding the obvious TBA breakthrough, GAC <br /> vessel number 1 was reported with the concentration of TPH-g and MTBE at 200 µg/1 and 24 µg/1, <br /> respectively, indicating the carbon in vessel number 1 required change-out. GAC vessel number 2 <br /> was reported with the concentration of TPH-g only at a concentration of 220 µg/1, indicated the <br /> Advanced GeoEnvironmental,Inc. <br />