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R603 UPDATE-10 11/09/92 <br /> i <br /> prior to a filter in front of the vacuum pump. After the vapor <br /> stream leaves the vacuum pump, it is pushed into the thermal <br /> oxidizer (RXL 400 ) which oxidizes the gasoline range hydrocarbon <br /> vapors at no less than 1400°F and no greater than 15500F. <br /> Influent samples are obtained from the exit of the pump and <br /> effluent samples are obtained from the stack of the thermal <br /> oxidizer. The gasoline range hydrocarbons are oxidized into heat, <br /> CO2 and water vapor, see UPDATE STATUS REPORT #5 . <br /> A portable ambient air PID-GC (Photovac 10550 packed column) is <br /> used at the site to sample the influent and effluent of the REMOX <br /> oxidizer and the individual wells (MW1 , MW2-3 , MW10 and EX-411 ) , <br /> see Tables 2 , and 3. On October 22 , and 24, 1991, "Tedlar" bag <br /> samples were obtained of the influent and effluent of the REMOX <br /> incinerator. Also on January 20, May 21, June 22, July 15, August <br /> 26 , September 9 and September 11, 1992 influent samples were <br /> obtained. These samples were analyzed for TFH and BTEX along with <br /> screening for Tetrachloroethylene (PCE) , Trichloroethylene (TCE) <br /> and 1, 2, -Dichloroethane (DCE) using a Shimadzu GC-FID <br /> chromatograph mounted permanently in WEGE ' s portable laboratory. <br /> These compounds have the following retention times in the above <br /> • chromatograph, DCE = 2 . 079 minutes, TCE = 3 . 023 minutes and PCE = <br /> 3 . 75 minutes. Prior to sampling the wells or the system, a <br /> calibrant prepared from fresh gasoline is infected into the GC- <br /> PID. The resulting chromatogram has numerous responses. The <br /> microprocessor of the GC-PTD computes the area, per response, in <br /> volt seconds, and assigns a peak #, and retention time. The sum <br /> of all the responses are then used to obtain a mg/L per volt <br /> second calibrant factor, which is used to calculate mg/L as <br /> gasoline vapor from each analysis produced. Pounds per day can <br /> be computed using these mg/L values produced from the analysis of <br /> the different vapor recovery wells, the influent to the oxidizer, <br /> the pressure differential created at the orifice to determine flow <br /> rates for each well, and the influent to the oxidizer. The pounds <br /> per day values for each well and the influent are then averaged <br /> with the preceding site visit ' s pound per day value. This figure <br /> is then multiplied by the number of days the system operated <br /> between visits to estimate the total pounds each well and the <br /> system has removed for that time period. This poundage is then <br /> added to the accumulated poundage of the previous visit to update <br /> the total pounds removed to date. The effluent sample is computed <br /> in the same fashion, but also includes natural gas flow along with <br /> the .influent orifice flow rate. <br /> PAGE 6 <br />