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EXfiOXNET PIP - CHLORPYRIFOS Page 3 of 4 4 „ active ingredient per acre may cause fish and aquatic invertebrate deaths [43]. Chlorpyrifos toxicity to fish may be related to water temperature. The 96-hour LC50 for chlorpyrifos is 0.009 mg/L in mature rainbow trout, 0.098 mg/L in lake trout, 0.806 mg/L in goldfish, 0.01 mg/L in bluegill, and 0.331 mg/L in fathead minnow [50]. When fathead minnows were exposed to Dursban for a 200-day period during which they reproduced, the first generation of offspring had decreased survival and growth, as well as a significant number of deformities. This occurred at approximately 0.002 mg/L exposure fora 30-day period [8]. Chlorpyrifos accumulates in the tissues of aquatic organisms. Studies involving continuous exposure of fish during the embryonic through fry stages have shown bioconcentration values of 58 to 5100 [51]. Due to its high acute toxicity and its persistence in sediments, chlorpyrifos may represent a hazard to sea bottom dwellers [52]. Smaller organisms appear to be more sensitive than larger ones [50]. . Effects on other organisms: Aquatic and general agricultural uses of chlorpyrifos pose a serious hazard to ' wildlife and honeybees [13,48]. N t Environmental Fate: . Breakdown in soil and groundwater: Chlorpyrifos is moderately persistent in soils. The half-life of chlorpyrifos in soil is usually between 60 and 120 days, but can range from 2 weeks to over 1 year, depending on the soil type, climate, and other conditions [12,19]. The soil half-life of chlorpyrifos was from 11 to 141 days in seven soils ranging in texture from loamy sand to clay and with soil pHs from 5.4 to 7.4. Chlorpyrifos was less persistent in the soils with a higher pH [51]. Soil half-life was not affected by soil texture or organic matter content. In anaerobic soils, the half-life was 15 days in loam and 58 days in clay soil [43]. Adsorbed chlorpyrifos is subject to degradation by UV light, chemical hydrolysis and by soil microbes. When applied to moist soils, the volatility half-life of chlorpyrifos was 45 to 163 hours, with 62 to 89% of the applied chlorpyrifos remaining on the soil after 36 hours [51]. In another study, 2.6 and 9.3% of the chlorpyrifos applied to sand or silt loam soil remained after 30 days [51]. Chlorpyrifos adsorbs strongly to soil particles and it is not readily soluble in water [19,51]. It is therefore immobile in soils and unlikely to leach or to contaminate groundwater [51]. TCP,the principal metabolite of chlorpyrifos, adsorbs weakly to soil particles and appears to be moderately mobile and persistent in soils [43]. . Breakdown in water:,The concentration and persistence of chlorpyrifos in water will vary depending on the type of formulation. For example, a large increase in chlorpyrifos concentrations occurs when emulsifiable concentrations and wettable powders are released into water. As the pesticide adheres to sediments and suspended organic matter, concentrations rapidly decline. The increase in the concentration of insecticide is not as rapid for granules and controlled release formulations in the water, but the resulting concentration r persists longer [50]. Volatilization is probably the primary route of loss of chlorpyrifos from water. Volatility half-lives of 3.5 and 20 days have been estimated for pond water [51]. The photolysis half-life of chlorpyrifos is 3 to 4 weeks during midsummer in the U.S. Its change into other natural forms is slow [52]. Research suggests that this insecticide is unstable in water, and the rate at which it is hydrolyzed increases with temperature, decreasing by 2.5-to 3-fold with'each 10 C drop in temperature. The rate of hydrolysis is constant in acidic to neutral waters, but increases in alkaline waters. In water at pH 7.0 and 25 C, it had a half- life of 35 to 78 days [12]. Breakdown in vegetation: Chlorpyrifos may be toxic to some plants, such as lettuce [36]. Residues remain on plant surfaces for approximately 10 to 14 days. Data indicate that this insecticide and its soil metabolites can accumulate in certain crops [8]. Physical Properties: . Appearance: Technical chlorpyrifos is an amber to white crystalline solid with a mild sulfur odor [13]. _ to . Chemical Name. 0,0-diethyl 0-3,5,6 tnchloro-2-pyndyl phospharothioa [13 ] I . CAS Number: 2921-88-2 . Molecular Weight: 350.62 . Water Solubility: 2 mg/L @ 25 C [13] . Solubility in Other Solvents: benzene s.; acetone s.; chloroform s.; carbon disulfide s.; diethyl ether s.; xylene s.; methylene chloride s.; methanol s. [13] Melting Point: 41.5-44 C [13] . Vapor Pressure: 2.5 mPa @ 25 C [13] . Partition Coefficient: 4.6990 [13] . Adsorption Coefficient: 6070 [19] Exposure Guidelines: