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Report: Groundwater-quality Monitoring—January 20,2003: 7500 West Eleventh Street, Tracy, CA. Page 12 <br /> Monitoring Well MW-12 is located, as shown on Figure 2, in the area that is interpreted <br /> to be the source of the secondary plume of affected groundwater found beneath the 7500 <br /> West Eleventh Street property. Analysis of the sample of groundwater recovered from. <br /> 1' Monitoring Well 12 on January 20, 2003 contained, for the first time since water quality <br /> in that well was fist tested in April 2002, no detectable concentrations or any other <br /> analytes of concern except diesel at a concentration of 98 gg/L, that concentration having <br /> fallen to the lowest value since groundwater sampling from the well was initiated. <br /> j 2.4.2 Groundwater Quality in the Degper Confined Aquifers <br /> No detectable concentrations of any analytes of concern that are "components of fuel <br /> =s hydrocarbons were detected in samples of groundwater recovered on January 20, 2003 <br /> from any of the monitoring wells screened in the aquifers that lie beneath the first clay <br /> aquitard that is present beneath the 7500 West Eleventh Street property at a depth of <br /> approximately 20 ft. (See Figures 3 through 5 for hydrostratigraphy.) This was also the <br /> case, with the exception of 0.60 µg/L of MTBE apparently present in the sample <br /> recovered from Well 3A on April 11, 2002 , which result proved to be spurious, when <br /> those wells were sampled on April 11, July 29 and October 25, 2002. <br /> However, as had been the case on October 25, 2002 when groundwater in Monitoring <br /> i Well MW-3A was similarly affected, the samples recovered from Monitoring Wells <br /> MW-3B and MW-12A on January 20, 2003, contained a compound that was NOT a fuel <br /> hydrocarbon, at concentrations of 87 µg/L and 100µg/L respectively. Although it was not <br /> a fuel hydrocarbon, it included components with molecules having carbon-chain lengths <br /> within part of the same range that includes compounds that are components of diesel. <br /> As was discussed in the Groundwater-Quality Monitoring Report for October 25, 2002, at <br /> that time, SJC and STL carefully evaluated possible sources of the unknown analyte <br /> found in samples recovered from Monitoring Wells MW-3A, MW-3B and MW-12A, but <br /> could find no plausible explanation that related to the discharge of fuel hydrocarbons that <br /> occurred on the 7500 West Eleventh Street site or that might have been introduced by a <br /> field or laboratory error (The San Joaquin Company Inc. 2002a). <br /> As noted in Section 2.3, in anticipation of the need to further evaluate the unluiown <br /> analyte previously found in samples of groundwater from the deeper aquifers beneath the <br /> G' site, when the groundwater sample was recovered from Monitoring Well MW-12A on <br /> January 20, 2003, a second sample of water from that well was recovered and designated <br /> Sample No. MW-12AS. When the results of the primary analyses of the samples <br /> recovered on January 20, 2003 were available and the same unknown analyte that <br /> included carbon-chains in the diesel range was again found in the samples from <br /> Monitoring Wells MW-3B and MW-12A, the laboratory was directed to analyze Sample <br /> r _,I No. MW-12AS for diesel, but, in that instance, to prepare the sample with silica gel <br /> before the analysis was made. As is recorded in the Certificate of Analysis for Sample <br /> No. MW-12AS, which is included in Appendix B that analysis found no detectable <br /> concentrations of petroleum hydrocarbons in the diesel range in the sample. <br /> is <br /> i sic <br />