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Musco Family Olive Company - 12 - 12'December 2006 <br /> To further illustrate the point, the data set has been plotted as "Time Series Plots" for the <br /> constituents listed below: <br /> • TDS <br /> • Calcium <br /> • Sodium <br /> • Magnesium <br /> • Sulfate <br /> • Chloride <br /> • Bicarbonate <br /> The "Time Series Plots" for TDS and general minerals are presented in Appendices C and D, <br /> respectively, for the Regional Well, and shallow wells MW-1, MW-3, MW-5, MW-13 through <br /> MW-17. As shown in the plot for the Regional Well, groundwater in this well is sulfate <br /> dominant. Chloride and sodium are stable at concentrations below the interim background <br /> groundwater concentration limits of 601 and 591 mg/L. Bicarbonate is also stable and shows <br /> no increasing trend. Calcium and Magnesium are detectable at low concentrations and stable. <br /> Staff believes the Regional Well groundwater data is more appropriate for the development of <br /> interim background groundwater concentrations for the deep zone due to its location outside <br /> the impact zone and its well construction. Furthermore, the use of the Production Well data as <br /> interim background groundwater concentrations is inappropriate due to the well depth, <br /> unknown pump depth, and unknown screen intervals. Consequently, it is unknown what zone <br /> the Production Well is capturing groundwater from_ When the Regional Well is compared to <br /> wells located in the upland, mid-slope, and lowland spray irrigation fields and adjacent to the <br /> Reservoir or 1 million gallon pond, apparent geochemical differences standout. <br /> Well MW-1 <br /> Well MW-1 is near the southern most boundary of Field 95, could be considered an <br /> up-gradient well possibly representative of background groundwater conditions. However, <br /> when the CDCs are plotted on the trend analysis it is evident that chloride and sodium <br /> concentrations have increased since 2002. The Time Series Plot of TDS indicates a sharp <br /> increase between early 2002 and late 2003 when concentrations equilibrate and stabilize over <br /> time. TDS has increased from 690 mg/L (April 2002) to 1,400 mg/L (June 2006). The same <br /> pattern for chloride and sodium are also seen in their respective plots. The increase of TDS, <br /> chloride, and sodium still remain below the interim water quality standard. This is likely due to <br /> continued mixing with groundwater outside the impact zone. Musco has been spray irrigating <br /> Field 95 since 1991. <br /> Well MW-13 <br /> Well MW-13 is down-gradient of well MW-1 in Field 95. It is located in a topographic low next <br /> to a drain inlet that conveys wastewater under the railroad tracks to the Reservoir. Well <br /> MW-13 has been dry since mid 2005, yet the earlier data indicates groundwater in the vicinity <br /> of well MW-13 is impacted by elevated concentrations of chloride, sodium, and bicarbonate. <br /> The chloride trend plot for well MW-13 varies significantly between sampling events conducted <br />