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Musco Family Olive Company - 13 - 12 December 2006 <br /> between late 2002 and late 2004. However, the sampling points prior to and after this year <br /> indicate a small to moderate decreasing fluctuation of chloride concentrations in groundwater. <br /> It is important to note, that chloride and sodium concentrations, including TDS, have been <br /> detected well above the interim limits from the start of groundwater sampling. The TDS value <br /> in well MW-13 from April 2002 was 3,000 mg/L. The most recent sampling event (June 2005) <br /> detected TDS at a concentration of 2,300 mg/L. <br /> Bicarbonate concentrations are also elevated in MW-13. Bicarbonate has been detected in <br /> the process wastewater streams, the 1-million gallon pond, and the Reservoir. Bicarbonate <br /> appears to be naturally occurring in groundwater within this region as evidenced by the <br /> analytical results for the Regional Well. However, groundwater that is outside of the spray <br /> irrigation area or impact zone, concentrations of bicarbonate are relatively low. In well MW-13, <br /> bicarbonate is being supplied to groundwater from a source other than.spray irrigation. The <br /> source of bicarbonate for well MW-13 is likely the Reservoir and not upgradient groundwater <br /> j since well MW-1, up-gradient of well MW-13, has lower bicarbonate concentrations. Also the <br /> I Regional Well located outside the impact zone has lower bicarbonate concentrations. <br /> Well MW-14 <br /> Well MW-14 is near the western end of the Reservoir, north of Field 95. Based on Musco's <br /> groundwater contour maps, well MW-14 is situated down-gradient of. Field 95. Well MW-14 is <br /> located approximately 100 feet south from the upland spring. Chloride and sodium have <br /> increased and if compared to the interim limits, upland spring water, and the Regional well it is <br /> apparent the concentrations detected in well MW-14 compare more favorably with <br /> concentrations found in other impacted wells shown in Table 8 above. TDS has increased <br /> over time as indicated in the TDS Time Series plot. The initial TDS value collected in <br /> November 2002 was 2,300 mg/L. .The June 2006 TDS concentration was 3,000 mg/L. <br /> Bicarbonate is present in well MW-14 but remains relatively stable at a concentration relative <br /> to MW-1. Since well MW-1 and M-14 have increasing trends of chloride, sodium, and TDS <br /> over time, it is apparent that groundwater beneath Field 95 has been impacted by spray <br /> irrigation. <br /> Well MW-15 <br /> Well MW-15 is in the bypass channel north of the Reservoir. Chloride and sodium <br /> concentrations detected in this well are below the interim standards and appear to be relatively <br /> stable over time. However, when these concentrations are compared to the Regional Well <br /> outside of the impact zone, it is apparent that groundwater has been impacted by spray <br /> irrigation.. TDS concentrations also appear to be relatively stable with an initial concentration <br /> of 1,400 mg/L measured in November 2002. The most recent TDS concentration measured in <br /> June 2006 was 1,700 mg/L.- <br /> Although well MW-15 has relatively stable TDS, chloride, and sodium concentrations, <br /> bicarbonate is increasing over time. Initial measurements (November 2002) of bicarbonate <br /> were detected at a concentration of 670 mg/L and have increased to 950 mg/L in June 2006. <br /> Groundwater in the vicinity of well MW-15 flows north-northeast away from the Reservoir that <br /> contains high concentrations of bicarbonate. It is apparent from the time series plot, the <br /> Reservoir is leaking wastewater that is impacting groundwater in the vicinity of well MW-15 <br />