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BASF Product No.: 580080 CabrloTMEG Fungicide BASF Corporation BASFCorporation ..::.............................................. .. .. .......... .,. MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE NUMBERS: NIA-Not available' N/D-N mined; N Not determined; -Not rated; N/E-Not established Agricultural Products Group BASF 1 Corporation: 800 832-HELP ;•r::a:cc:::a;::cc;:a::+i::o»:::cc"""'" :::;""'"": :::i%%i;;:;; :^^^^^^^??'�'��•+': +••: ^•^•-•^::.:r•:.:e;.;;;;;;.;.;: .-^-:-.-.m:::-.•- P.O.Box 13528, P ( ) z;:iiiSEf�•tYl13W� ��:': '':• ':;:;�::�::::2:::c::::'::?:::�:+.:;:>:'+.`::#:::;i`:�::;:ii:;i i:�i: :;;:<;:�i i:�ii:�::�i:�iii:iiiii:�iiif i:�i:�i:i:�i;:i;�i":� ......�{...:...��:E,:��.:•:::::::::::.:.......................::::::.�:::::::: Research Triangle Park NC 27709 CHEMTREC: 1(800)424-9300 TOXICOLOGICAL TEST DATA: u ..... (919)547-2000 For the formulated product. Product No.: 580080 CabrloTMEG Fungicide Rat,Oral LD50-2000 mg/kg Date Prepared:9/2011999 Date Revised:811712004 Rat,Dermal LD50>2000 mg/kg .....�..�:::::::::::. ,..,:_:srs.^<;,^^-::r.::::::::::.:............:..:.:::::.:•"";'.;;.%-:;--^:;:•:;•r:•:;:; ;v::•::;;•::•:::•:>:•::•>:+:::•:T;: Rat,Inhalation LC50(4 hr)=4.7 mg/L < Rat Inhalation C L 50 1 hr calculated-1 : iii:;ii:i::i i ::Gi: : Trade Name: CabrloTMEG Fungicide Rabbit Skin Irritation-Slightly irritating Rabbit Eye Irritation-Slightly irritating Chemical Name: Carbamic acid,[2-[([t-(4-chi o top he nyl)-lH-pyrazo 1-3-yl]oxy]m ethyl]phe nyl]m ethoxy- Guinea pig,Dermal Sensitizer-Nota sensitizer methyl ester For Pyraclostrobin: Synonyms: pyraclostrobin,BAS 500 F,F500 Formula: C18 H76 CI N3 Od Ina 2 generation rat reproduction study,no adverse effects were noted on reproduction. Parental toxicity and pup effects were observed at the highest dose tested only. Chemical Family: strobllurin Mol Wt: 387.83 In rat and rabbit teratology studies,no teratogenic effects were noted. ... mr•-•m- m--.:--.o............-- -. .--�.;-�-�.- .f;: ;; Minor developmental effects were noted in the rabbit study at doses that induced toxic' in the mother. �Fji�i�ltyra�}T ?f: toxicity---- , ........... y g of In itro and In vivo tests. COMPONENT CAS NO. '/, PELITLV-SOURCE Pyraclostrobin was not carcinogenic in long-term studies with rats and mice. Pyraclostrobin 175013-18-0 20.0 Not established Inerts including. 80.0 Not established kaolin 1332-58-7 10 mg/m(3)PEL-OSHA,5 mg/m(3) respirable dust, 2 mg/m(3)TLV-ACGIH respirable fraction EFFECTS OF OVEREXPOSURE: - -- SARA Title III Section 313: Yes _ _ - ---�:- -- - :: - -'�-yt <:: i:i•::; See Product Label and Directions For Use for additional precautionary statements. ::: 4N. ... Y:►11 #1:: . •• ••••••••••••••••+••••••+•• ••••••••+••••• CAUTION.Harmful if swallowed or abs ��•'�•�� abed through skin. Causes moderate eye irnlation.Avoid contact with skin eyes BOILINGIMELTING POINT@760mm Hg: NID pH: 6.5-7.5[1%solution] clothing. y or VAPOR PRESSURE mmHg P.20°C: NID Existing medical conditions aggravated by this formulation: None known for this product. SPECIFIC GRAVITY OR BULK DENSITY: .5-.7 kg/L FIRST AID PROCEDURES SOLUBILITY IN WATER' Dispersible H swallowed: Call a poison control center or doctor immediately for treatment advice.Have person sip a glass ofwalar ifable to swallow.Do not induce vomiting unless told to by a poison control canter or doctor.Do not give anything to APPEARANCE: Brown solid ODOR:Aromatic INTENSITY: Faint an unccnsnaun person. ....................................:.........:..:....;..::::......- •......;:.................... y}� ��yt Hon skin or clothing: Take off contaminated cl°Inin.Rinses- 9 k n immediately with plenty of water for 1S2G minutes,Call a Dison ;;QQ.. / �ry/r;�r /[x, •+��k::`:fi::<:� :�ti?��I!:F:t�l!f:K'�YY:;'•':� :R1k�� R 471 ::c:::•:;::>::>:;�.>:::.::�.;::::. con o canter a oc or or t .................:........ .................. ...... .. .................... ..:....:•..:..:.:....... tr I d t ( trealmen aMice. FLASH POINT(TEST METHOD): 203°F(PMCC) AUTOIGNITION TEMP:About 904°F ff In eyes: Hold eye open and rinse sloely and gently with water for 15-20 minutes.Remove contact lenses,apresent, FLAMMABILITY LIMITS IN AIR(%BY VOL): LOWER:1.8 UPPER:11.8 at 77°F after first 5 minutes,then continue rinsing eye.Call a poison control center or doctor for treatment advice. If Inhaled: Move person to hash air.If person is not breathing,call 911 or an ambulance,than give artificW respiration, NFPA 704 HAZARD CODES preferably mouth-to-mouth if possible.Call a poison control center or doctorfor furthor treatment advice. HEALTH: 2 FLAMMABLE:3a INSTABILITY: 1' OTHER: Noteloptystdan: Treat according to symptoms(decontamination,vital functions),no known specific antidote. NFPA 30 STORAGE CLASSIFICATION: Non-flammable solid »::»::.::c;::::::c'�:;�:::.::::::::::<:•:c•�c::<•:`V.*THV.'.�.s.'41'I.1�1i.�..... '•:..:..::. .:;.:.: •:'.'ilii:::iiiiiiiiiii::%::a;::;;::•:cc::i;:;i::ii::S::: (EXTINGUISHING Use water fog,foam,or dry chemical extinguishing media. STABILITY: Stable .MEDIUM CONDITIONS TO AVOID: Store in original container in cool,dry,well ventilated place away from ignition sources, 1SPECIAL Firefighters should be equipped with self-contained breathing apparatus and turnout gear. heat or flame. FIREFIGHTING CHEMICAL INCOMPATIBILITY: Strom oxidizers,bases,chlorate nitrates PROCEDURES _ 9 UNUSUAL FIRE rMay form explosive dust/air mixtures,Class St 1. HAZARDOUS DECOMPOSITION PRODUCTS: Including oxides of carbon and nitrogen,ammonia,HCI;HCN EXPLOSION DSC exotherm @ 168°C,Kst=41 bar/sec,Pmax(bara)-5.9,MIE>10,000 mJ. HAZARDOUS POLYMERIZATION: No HAZARDS CONDITIONS TO AVOID: Store away from sunlight,Ignition sources. CORROSIVE TO METAL: No i OXIDIZER: No Page 1 of 6 Page 2 of 5