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Product Ne.: 580080 Cabrlo TMEG Fungicide BASF Corporation Product No.: 580080 Cabrlo TMEG Fungicide BASF Corporation SARA 311!312 REPORTING —"--- PESTICIDE Boor IC ATO RS&WORKERS must refer to the Product Label and Directions For Use FIRE:No PRESSURE:No REACTIVITY:No ACUTE:Yes CHRONIC:No TPQ(Ibs):10,000 attached to the product for Aarlcultural Use Reeulremenls In accordance with the EPA Worker SPILL AND LEAK PROCEDURES: Protection Standard 40 CFR part 170. � Incase of large scale spillage of this product,avoid contact,isolate area and keep out animals and unprotected RECOMMENDATIONS FOR MANUFACTURING COMMERCIAL BLENDING AND PACKAGING persons.Call CHEMTREC(800 424-9300)or BASF Corporation(800 832-HELP). For a small spill,wear personal: WORKERS: protective equipment as specked on the label. FOR A LIQUID SPILL: Dike and contain the spill with inert material(sand,earth,etc.)and transfer the liquid and Protective Clothing I solid diking materials to separate containers for disposal. Protective suit and chemical resistant gloves. FOR A SOLID SPILL: Sweep solid into a drum for re-use or disposal, Remove personal protective equipment Eye Protection: and decontaminate it priorto re-use. Chemical goggles. '1HAZARDOUS SUBSTANCE SUPERFUND: No RQ(Ibs):None Respiratory Protection: WASTE DISPOSAL METHOD: —" If dusts are generated,wear a NIOSH/MSHA approved respirator. Pesticide wastes are acutely hazardous. Wastes resulting from this product may be disposed of on site or at an Ventilation: approved waste disposal facility. Improper disposal of excess pesticide,spray mix or rinsate is a violation of federa Whenever possible,engineering controls should be used to minimize the need for personal protective law. If these wastes cannot be disposed of according to label instructions,contact the state agency responsible for pesticide regulation or the Hazardous Waste representative at the nearest EPA Regional Office for guidance equipment _ _ :a: HAZARDOUS WAST C E 40 F 6 ��Q�: :{x1i�i:•J�:?`:S'�?:::: ::: ::i�:t�ii:�ii:�::: R2 1. No :::::::::•::::::::.::. .. ..........................:..................... HAZARDOUS WASTE NUMBER:None ENVIRONMENTAL TOXICITY DATA CONTAINER DISPOSAL: Pyraclostrobin is toxic to fish and invertebrates. Triple rinse all containers and dispose of in an approved sanitation site. It is generally of low acute and chronic toxicity to birds bees,terrestrial plants and aquaticplants. ............""-: -- '"'" """'�'^"------�-""" ----^^^^�• ----- ..,.:,, �.f1ce::.': Lrfrx:�f./�s �c,fj ........... ::::;;::; ::X;r.;::o:;D�.....:..i. 1 _.::,+,i711^i':�1�1...?,'sJnL3�.^.:+.a' Bobwhite Quail,(single dose)Oral LD50 2000 mg/kg bw D.O.T.PROPER SHIPPING NAME(49CFR172.101-102): HAZARDOUS SUBSTANCE Bobwhite Quail,(5 day dietary feeding)Oral LC50>5000 mg/kg None (49CFR CERCLA LIST): Mallard Duck,(5 day dietary feeding)Oral LC50>5000 mg/kg None Daphnia magna,(48 hr)EC50 =0.0157 mg/L Daphnia magna,(21 day reproduction)NOEC =0.004 mg/L _ RQ(Ibs):None Rainbow Trout,(96 hour)LC50 =0.0062 mg/L 'D.O.T.HAZARD CLASSIFICATION(CFR 172.101.102): Algae,(96 hour)EC50<1 mg/L PRIMARY SECONDARY BluegNone Mysid,ll Sunfish,EC hour).004C50 =mg/L mg/L D.O.T.LABELS REQUIRED 49CFR172.101-102 D.O.T.PLACARDS POISON CONSTITUENT M ysid,(96 hour)EC50 =0.0042 mg/L I i ( )� Sheepshead minnow,(96 hour)LC50=0.077 mg/L REQUIRED(C FR 172.504): (49C FR 172.203(K)): Oyster(96 hour)EC50 =0.0125 mg/L None None BILL OF LADING DESCRIPTION Fungicide,agricultural,N.O.I.B.N. By watership as Environmentally Hazardous Substance,Solid,N.O.S.(Pyraclostrobin)9,UN3077,PG 1�1.Marine Pollutant CC NO.: UN/NA CODE: N/A Page 3 of 5 Page 4 of 5