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<br /> MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT VVM.GREENBOOK.NET 1
<br /> PRISM® —ASPIRATION HAZARD,DO NOT INDUCE VOMIT- brain and nervous system damage. Symptoms include
<br /> Herbicide ING fatigue,concentration difficulties, anxiety,depression,
<br /> ` This Material Safety Data Sheet (MSDS) serves dif- —MAY CAUSE ALLERGIC SKIN REACTIONS rapid mood swings and short-term memory loss. The
<br /> ferent purposes than and DOES NOT REPLACE OR —DO NOT GET IN EYES,ON SKIN OR ON CLOTH- reports are not clear with regard to the types of sol-
<br /> MODIFY THE EPA-APPROVED PRODUCT LABEL- ING vents that may cause these symptoms,and there is
<br /> ING(attached to and accompanying the product con- —KEEP OUT OF REACH OF CHILDREN controversy among scientists to whether the condition
<br /> tainer). This MSDS provides important health,safety, POTENTIAL HEALTH EFFECTS exists or is caused by this type of product. Since many
<br /> and environmental information for employers,employ- Acute Toxicity(Primary Routes of Exposure) other diseases cause some or all of these conditions,
<br /> ees,emergency responders and others handling large Signs and Symptoms of Systemic Effects: Signs of a doctor should be consulted if any appear.
<br /> quantities of the product in activities generally other toxicity in test animals exposed to lethal or near-lethal Trimethyl benzene may affect the liver and may cause
<br /> than product use,while the labeling provides that in- oral doses included salivation,diarrhea,and incoordi- changes in the blood cells and affect the blood's clot-
<br /> formation specifically for product use in the ordinary nation. This product contains a solvent mixture. Sol- ting ability. Trimethyl benzene can irritate the lungs.
<br /> ` course. vents,when inhaled,can cause nasal and respiratory Repeated exposures may cause bronchitis to develop
<br /> Use,storage and disposal of pesticide products is reg- irritation and central nervous system effects including with cough,phlegm,and/or shortness of breath.
<br /> ulated by the EPA under the authority of the Federal dizziness,weakness,fatigue, nausea,headache and This product contains naphthalene which has been
<br /> Insecticide, Fungicide, and Rodenticide Act (FIFRA) possibly unconsciousness and even death. Ingestion listed bythe International Agency for Research onCan-
<br /> through the product labeling. Al necessary and ap- of solvents can cause gastrointestinal irritation, nau- cer(IARC)as possibly carcinogenic to humans(Group
<br /> propriate precautionary,use,storage,and disposal in- sea,vomiting and diarrhea. Aspiration of low viscosity 2B).
<br /> formation is set forth on that labeling. It is a violation products can cause chemical pneumonitis which can Teratology(Birth Defects)Information: Clethodim
<br /> of federal law to use a pesticide product in any manner be fatal. Acute exposure to naphthalene by inhala- Technical produced developmental toxicity only at me-
<br /> not prescribed on the EPA-approved label. tion, ingestion, and dermal contact has been associ- ternally toxic dose levels. It is not expected to present
<br /> ated with hemolytic anemia, damage to the kidneys, a hazard under normal use conditions.There is limited
<br /> SECTION 1:CHEMICAL PRODUCT AND COMPANY cataracts,and,in infants,brain damage. evidence of fetal and maternal toxicity from exposure
<br /> IDENTIFICATION Eye:This product has been shown to cause prolonged to naphthalene.
<br /> PRODUCT NAME:PRISMO Herbicide or significant eye irritation.The degree of injury will de- Reproduction Information: No reproductive toxicity
<br /> VC NUMBER(S):VC-1041 pend on the amount and duration of contact and the was observed in animals exposed to Clethodim Tech-
<br /> EPA REGISTRATION NUMBER: 59639-78 speed and thoroughness of the first aid treatment. The nical.
<br /> SYNONYM(S):None expected adverse health effects resulting from an ex- Potentially Aggravated Condition: Individuals with
<br /> MANUFACTURER posure may include redness,swelling and pain which preexisting diseases of the liver, red blood cell and
<br /> VALENT USA CORPORATION could last for an extended period of time. central nervous system may have increased suscepti-
<br /> P.O.Box 8025 Skin: This product has been shown to cause pro- I bility to the toxicity of excessive exposures.
<br /> longed or significant skin irritation. The degree of in- For complete discussion of the toxicology data from
<br /> 1333 N.California Blvd.,Suite 600 which this evaluation was made, refer to Section 11.
<br /> Walnut Creek,CA 94596-8025
<br /> jury will depend on the amount and duration of contact
<br /> EMERGENCY TELEPHONE NUMBERS and the speed and thoroughness of the first aid treat- For Regulatory Information,refer to Section 15.
<br /> HEALTH EMERGENCY OR SPILL (24 hr): 1-800- merit. The expected adverse health effects resulting SECTION 4: FIRST AID MEASURES
<br /> 892-0099 from an exposure may include redness,swelling and
<br /> 24 hr.): CHEMTREC 1-800- pain which could last for an extended period of time. EMERGENCY NUMBER 1-800-892-0099
<br /> TRANSPORTATION
<br /> ( Based on an evaluation of the ingredients and/or simi- EYES: Flush eyes immediately with fresh water for at
<br /> 424-9300 or(202)483-7616 lar products,this product may cause allergic skin reac- least 15 minutes while holding eyelids open. Remove
<br /> PRODUCT INFORMATION tions. In sensitized individuals even small exposures contact lenses if worn. Get medical attention.
<br /> AGRICULTURAL PRODUCTS: 1-800-6VALENT can trigger allergic reactions. The expected adverse SKIN:Remove contaminated clothing.Wash skin thor-
<br /> PROFESSIONAL PRODUCTS:1-800-89VALENT health effects may include itching, redness, swelling oughly with soap and water. See a doctor d any signs
<br /> SECTION 2: COMPOSITION f INFORMATION ON and blistering of the skin. or symptoms described in this document occur. Dis-
<br /> INGREDIENTS This product has been shown to be minimally toxic card contaminated non-waterproof shoes and boots.
<br /> when absorbed through the skin. The degree of in- Wash contaminated clothing separately.
<br /> - ------- ---- jury will depend on the amount of material inhaled and INGESTION: If swallowed,DO NOT induce vomiting.
<br /> Ingmdient Name(CAS#) welght Exposure the speed and thoroughness of the first aid treatment. Call a physician or Poison Control Center. Promptly
<br /> (Chemical Name] Percent Limit Ret The expected adverse systemic health effects are de- I drink a large quantity of milk, egg whites or gelatin
<br /> CLETHODiM' 12-13 None — scribed above. solution. If these are not available, drink large quan-
<br /> (99129-21.2) Ingestion: tities of water. Avoid alcohol. Get medical attention
<br /> 2-pm en-4)03-a,iom- This product has been shown to be slightly toxic when immediately.
<br /> 2-pmpe.py1)-}
<br /> � Imino}propyl}-s{2-(ethyl- ingested. The degree of injury will depend on the INHALATION:If respiratory discomfort or irritation oc-
<br /> thio)pmpyi}-3-hymn■y-2- amount of material ingested and the speed and thor- curs, move the person to fresh air. See a doctor if
<br /> cyrJohexen-1-one] oughness of the first aid treatment. The expected ad- discomfort or irritation continues. If not breathing,give
<br /> NAPHTHALENE 5-9m
<br /> -910 ppm OSHA a verse systemic health effects are described above. artificial respiration, preferably mouth-to-mouth. Get
<br /> (91-20.3) 4A ACGIH Ingestion of this product may cause gastrointestinal medical attention.
<br /> s ppm NOTES TO PHYSICIAN: Ingestion of this product or
<br /> STEL irritation,nausea,vomiting and diarrhea. 9
<br /> TRIMETHVL BENZENE 1-2 25 ppm OSHA 8 Because of the low viscosity of this substance,it can subsequent vomiting can result in aspiration of light
<br /> (95-63.6) TWA ACGiH directly enter the lungs if it is swallowed(this is called hydrocarbon liquid, which can cause pneumonitis. If
<br /> TOTAL 70-80 10o ppm Mfgr. aspiration).This can occur during the act of swallowing ingested, probable mucosal damage may contraindi-
<br /> HyoRocARaolvs or when vomiting the substance. Once in the lungs, tate the use of gastric lavage.
<br /> (64742-94-5) the substance is very difficult to remove and can cause SECTION 5 FIRE FIGHTING MEASURES
<br /> Other** 1-15 1s None injury to the lungs and death.
<br /> Inhalation: Exposure to high concentrations may re- FLASH POINT:147'F(64'C)
<br /> Active Ingredient suit in respiratory irritation. Signs and symptoms may METHOD:Setaflash Closed Cup
<br /> Other ingredients,which are maintained as trade se- include, but not be limited to, nasal discharge, sore AUTOIGNITION:NDA
<br /> crets,are any substances other than an active ingre- throat,coughing and difficulty in breathing. EXTINGUISHING MEDIA: CO2, dry chemical, foam,
<br /> dient contained in this product. Some of these may Based on an evaluation of the ingredients and/or sim- water fog.
<br /> be hazardous,but their identity is withheld because ilar products,this product is expected to be minimally FLAMMABLE LIMITS(k by volume in air): Lower:
<br /> they are considered trade secrets.The hazards as- toxic when inhaled. The degree of injury will depend NDA Upper: NDA
<br /> sociated with the other ingredients are addressed in on the amount of material inhaled and the speed and NFPA RATINGS:Health 2;Flammability 2;Reactivity
<br /> this document. Specific information on other ingre- thoroughness of the first aid treatment. The expected 1;Special None
<br /> dients for the management of exposures,spills,or adverse systemic health effects are described above. (Least-0, Slight-1, Moderate-2, High-3, Extreme-4)-
<br /> safety assessments can be obtained by a treating Chronic Toxicity(Including Cancer): Increased liver These values are obtained using professional judge-
<br /> physician or nurse by calling 1-800-892-0099 at any weights and anemia have been observed in animals ment. Values were not available in the guidelines or
<br /> time. exposed to Clethodim Technical. Clethodim Technical published evaluations prepared by the National Fire
<br /> SECTION 3: HAZARDS IDENTIFICATION was not carcinogenic to animals. Protection Association,NFPA.
<br /> _..___. ..___ ._ ____._ Prolonged or repeated dermal exposures may cause FIRE FIGHTING INSTRUCTIONS: Liquid evaporates
<br /> w EMERGENCY OVERVIEW drying,scaling and even blistering of the skin. Chronic and forms vapor(fumes)which can catch fire and burn
<br /> WARNING: (long-term)exposure of workers and rodents to naph- with explosive violence. Invisible vapor spreads easily
<br /> —CAUSES SUBSTANTIAL BUT TEMPORARY EYE thalene has been reported to cause cataracts and dam- and can be set on fire by many sources such as pilot
<br /> IRRITATION age to the retina. Lesions in the kidneys and thymus, lights, welding equipment, and electrical motors and
<br /> —CAUSES SKIN IRRITATION signs of anemia, and reduced spleen weights have switches. Fire hazard is greater as liquid temperature
<br /> been observed in rats and mice chronically exposed rises above 85'F.
<br /> —HARMFUL IF SWALLOWED OR ABSORBED via gavage. Products of combustion from fires involving this mate-
<br /> THROUGH THE SKIN Reports have associated repeated and prolonged oc- rial may be toxic. Avoid breathing smoke and mists.
<br /> —AVOID BREATHING VAPORS OR SPRAY MIST : cupational overexposure to solvents with permanent I Avoid personnel and equipment contact with fallout
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