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MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2
<br /> and runoff. Minimize the amount of water used for VISCOSITY: 14 cps @ 25'C and, in infants, brain damage. There is limited evi-
<br /> fire fighting. Do not enter any enclosed area with- CORROSION CHARACTERISTICS:Not corrosive to dente of fetal and maternal toxicity from exposure to
<br /> out full protective equipment, including self-contained high density polyethylene. I naphthalene.
<br /> breathing equipment. Contain and isolate runoff and iChronic exposure of workers and rodents to debris for proper disposal. Decontaminate personal SECTION 10: STABILITY AND REACTIVITYI naphtha-
<br /> lene has been reported to cause cataracts and dam-
<br /> protective equipment and fire fighting equipment be- CHEMICAL STABILITY: Unstable at extreme pH's, age to the retina. Lesions in the kidneys and thymus,
<br /> fore reuse. Read the entire document. temperature and upon exposure to UV light. signs of anemia, and reduced spleen weights have
<br /> HAZARDOUS COMBUSTION PRODUCTS: Normal INCOMPATIBILITY: May react with strong oxidizing been observed in rats and mice chronically exposed
<br /> combustion forms carbon dioxide, water vapor and agents,such as chlorates,nitrates,peroxides,etc. via gavage. Naphthalene has been listed by the In-
<br /> may produce oxides of nitrogen, sulfur. Combustion IMPACT EXPLODABILITY: No sensitivity to mechani- ternational Agency for Research on Cancer(IARC)as
<br /> may produce toxic compounds of chlorine. Incomplete cal impact, possibly carcinogenic to humans(Group 2B).
<br /> combustion can produce carbon monoxide. OXIDATION/REDUCTION PROPERTIES:Not an ox- Trimethyi benzene may affect the liver and may cause
<br /> SECTION 6: ACCIDENTAL RELEASE MEASURES idizing or reducing agent. changes in the blood cells and affect the blood's clot-
<br /> SECTION 11: TOXICOLOGICAL INFORMATION ting ability. Trimethyl benzene can irritate the lungs.
<br /> VALENT EMERGENCY PHONE NUMBER: 1-800- Repeated exposures may cause bronchitis to develop
<br /> 892-0099 ACUTE(Product Speck Information): with cough,phlegm,and/or shortness of breath.
<br /> CHEMTREC EMERGENCY PHONE NUMBER: 1- Eye Irritation: This product produced mild iritis and i For a summary of the potential for adverse health ef-
<br /> 800-424-9300 severe irritation in rabbits which cleared within 21 days. fects from exposure to this product,refer to Section 3.
<br /> r OBSERVE PRECAUTIONS IN SECTION 8: PER- ! (Toxicity Category II) For information regarding regulations pertaining to this
<br /> SONAL PROTECTION Skin Irritation: This product produced severe skin product,refer to Section 15.
<br /> Stop the source of the spill if safe to do so. Contain irritation in rabbits. (Toxicity Category II)
<br /> the spill to prevent further contamination of the soil, ! Dermal Toxicity:The dermal LD50 in rabbits is greater SECTION 12: ECOLOGICAL INFORMATION
<br /> surface water,or ground water. than 5 g/kg. (Toxicity Category IV) AVIAN TOXICITY: The acute toxicity of Clethodim
<br /> FOR SPILLS ON LAND: Oral Toxicity: The oral LD50 in rats is 4.8 g/kg for Technical to birds is very low.
<br /> CONTAINMENT:Avoid runoff into storm sewers and females and greater than 5.0 g/kg for males. (Toxicity Bobwhite quail oral LD5o greater than 2 g/kg
<br /> ditches which lead to waterways. Contain spilled liq- Category III)Signs of toxicity at lethal or near lethal Bobwhite quail dietary LC50 greater than 6000 ppm
<br /> uids with dry sorbents. doses included salivation,diarrhea and incoordination. Mallard duck dietary LC5o greater than 6000 ppm
<br /> CLEANUP: Clean up spill immediately. Absorb spill Inhalation Toxicity: No product specific toxicology No reproductive effects were observed in mallard
<br /> with inert material (such as dry sand or earth), then data available. The 4-hour LC50 in rats for a similar ducks exposed to 1000 ppm of Clethodim Technical.
<br /> place in a chemical waste container. Wash area with formulation Select 2 EC Herbicide was greater than In Bobwhite quail,a slight decrease in viability of em-
<br /> soap and water. Pick up wash liquid with additional 5.4 mg/l. (Toxicity Category IV)This product is also bryos of eggs from females exposed to 1000 ppm was
<br /> absorbent and place in a chemical waste container. expected to be a respiratory irritant. observed. A NOEL was established at 300 ppm for
<br /> FOR SPILLS IN WATER: Skin Sensitization: No product specific data avail- this study.
<br /> CONTAINMENT:This material forms an emulsion in able. Based on a review of the ingredients and/or AQUATIC ORGANISM TOXICITY:Clethodim Techni-
<br /> water. Stop or reduce contamination of any water. similar products,this product may be a skin sensitizer. cal is only slightly toxic to freshwaterfish and practically
<br /> Isolate contaminated water. TOXICITY OF CLETHODIM TECHNICAL nontoxic to daphnia.
<br /> CLEANUP:Remove contaminated water for treatment SUBCHRONIC: Compound-related effects, noted at Rainbow Trout 96-hour LCso=67 mg/I
<br /> or disposal. high doses of Clethodim Technical in subchronic toxic- Bluegill Sunfish 96-hour LCso=120 mg/I
<br /> fly studies conducted in mice,rats,and dogs,were de-
<br /> SECTION 7: HANDLING AND STORAGE creased body weights,increased liver size(increased j Daphnia magna 48-hour LC5o greater than
<br /> END USER MUST READ AND OBSERVE ALL PRE- liver weights and hypertrophy)and anemia(decreased OTHER NON-TARGET ORGANISM TOXICITY:ICITTY:
<br /> CAUTIONS ON PRODUCT LABEL. hemoglobin, hematocrit,or erythrocyte counts). Clethodim Technical was found to be nontoxic t0
<br /> DO NOT USE OR STORE near flame, sparks or hot CHRONIC/CARCINOGENICITY: In chronic studies adult worker bees at the highest dose tested, 100
<br /> surfaces. Use only in well ventilated area. Keep con- with Clethodim Technical in the mouse,rat,and dog, micrograms/bee.
<br /> tainer closed. similar effects as seen in subchronic have been noted. SECTION 13: DISPOSAL CONSIDERATIONS
<br /> ft. DO NOT weld,heat or drill container. Replace cap or j No treatment related increases in neoplasms were ob- END USERS MUST DISPOSE OF ANY UNUSED
<br /> bung. Emptied container still contains hazardous or served in any study. PRODUCTS PER THE LABEL ANY UNUSED
<br /> explosive vapor or liquid. TERATOLOGY/DEVELOPMENTAL TOXICITY: De- TIONS.
<br /> NDA-
<br /> Keep pesticide in original container. Do not store or velopmental toxicity in rats and rabbits was observed DISPOSAL METHODS: Check governmental regula-
<br /> transport near food or feed. Do not contaminate food only at maternally toxic dose levels of Clethodim Tech-
<br /> or feed. Do not put concentrate into food or drink nical. tions and local authorities for approved disposal of this
<br /> containers. Do not dilute concentrate in food or drink REPRODUCTION: No reproductive toxicity was ob- material. Dispose in accordance with applicable laws
<br /> containers. Store in a cool, dry place, out of direct served in a study with rats exposed to Clethodim Tech- and regulations.
<br /> sunlight. nlcal for two generations. SECTION 14: TRANSPORT INFORMATION
<br /> MUTAGENICITY: Clethodim Technical was negative --- — -- -- -----
<br /> SECTION 8: EXPOSURE CONTROLS/PERSONAL
<br /> in the following genotoxicity assays:microbial reverse D.O.T.SHIPPING NAME: Compounds, weed killing.
<br /> PROTECTION liquid,non-regulated.
<br /> .. mutation(Ames Assay),in vitro chromosome aTECHNICAL SHIPPING NAME: Clethodim 12% So-
<br /> END USER MUST READ AND OBSERVE ALL PRE- ! tion assay in Chinese Hamster Ovary Cells, inn vivo vivo
<br /> CAUTIONS ON PRODUCT LABEL. chromosome aberration assay in Rat Bone Marrow lution
<br /> EYE PROTECTION:Appropriate eye protection must Cells and in vivo Unscheduled DNA Synthesis Assay. RQ:159 gal
<br /> be worn when working with this material or serious Clethodim Technical does not present a genetic hazard D.O.T.HAZARD CLASS:NA
<br /> harm can result. Wear protective eyewear to intact animal systems. U.NJN.A.NUMBER:NA
<br /> RESPIRATIONIVENTILATION:This material may be TOXICITY OF OTHER INGREDIENTS: REMARKS: Regulated when shipped in bulk(> 119
<br /> a respiratory irritant and,unless ventilation is adequate, This product contains a solvent mixture. Solvents, gal)•
<br /> the use of approved respiratory protection is recom- when inhaled, can cause nasal and respiratory irrita- EXCEPTION REQUIREMENT:49 CFR 173.150
<br /> mended. Use this material only in well ventilated ar- tion and central nervous system effects including dizzi- SECTION 15• REGULATORY INFORMATION
<br /> eas. ness,weakness,fatigue,nausea,headache and pos-
<br /> SKIN PROTECTION:Do not get on skin or clothing, sibly unconsciousness and even death. Ingestion of REGULATIONS UNDER FIFRA: All pesticides are
<br /> Skin contact should be avoided by wearing protec- solvents can cause gastrointestinal irritation, nausea, governed under FIFRA (Federal Insecticide, Fungi-
<br /> tive clothing including chemical resistant gloves,long vomiting and diarrhea. Prolonged or repeated dermal tide,and Rodenticide Act). Therefore,the regulations
<br /> sleeved shirt, long pants, shoes and socks. Discard exposures may cause drying, scaling and even blis- presented below are pertinent only when handled out-
<br /> clothing and other absorbent materials that may have tering of the skin. Aspiration of low viscosity products side of the normal use and applications of pesticides.
<br /> been drenched or heavily contaminated with this prod- can cause chemical pneumonitis which can be fatal. This includes waste streams resulting from manufac-
<br /> r uct's concentrate. Do not reuse them. Reports have associated repeated and prolonged oc- turing/formulation facilities, spills or misuse of prod-
<br /> SECTION 9: PHYSICAL AND CHEMICAL PROPER- cupational overexposure to solvents with permanent ucts,and storage of large quantities of products con-
<br /> TIES brain and nervous system damage. Symptoms include taining hazardous or extremely hazardous substances.
<br /> fatigue, concentration difficulties, anxiety,depression, OTHER U.S.FEDERAL REGULATIONS:
<br /> APPEARANCE: Light yellow liquid. rapid mood swings and short-term memory loss. The I OSHA:See Section 2
<br /> ODOR:mild aromatic odor. reports are not clear with regard to the types of sol- CERCLA RQ': Product RQ=37 gal(based on glycol
<br /> MELTING POINT:NA vents that may cause these symptoms,and there is ethers); glycol ethers RO = 1 Ib, naphthalene RQ=
<br /> BOILING POINT:NDA controversy among scientists to whether the condition 100 Ib
<br /> DENSITY:0.93 g/ml @ 20'C(7.76 Ib/gal) exists or is caused by this type of product.Since many RCRA": Naphthalene waste code=U165
<br /> SOLUBILITY:Emulsifies in water other diseases cause some or all of these conditions, SARA TITLE III:
<br /> VAPOR PRESSURE:NA a doctor should be consulted if any appear. Sara(313)Chemicals: 1,2,4 trimethylbenzene,naph-
<br /> DISSOCIATION CONSTANT:NA Acute exposure to naphthalene by inhalation, inges- thalene,glycol ethers
<br /> OCTANOL/WATER PARTITION COEFFICIENT:NA tion, and dermal contact has been associated with Sara(311,312):
<br /> pH:4-5 as 1%emulsion in distilled water hemolytic anemia,damage to the kidneys,cataracts, Immediate Heafth Effects: YES
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