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k" KLEINFELDER <br /> 4.6 SYSTEM SHUTDOWN AND DISSASSEMBLY <br /> Aller the pilot testing is complete, the system will be shutdown, the main electrical breaker <br /> switched off and the sparge and ventilation well valves secured. Where necessary, the supplier(s) <br /> of the equipment will complete the piping and electrical disconnection and the system will be <br /> removed within two weeks of shutdown. Kleinfelder will manage removal of fencing, piping, <br /> wiring, and related items which were installed. To the extent possible, the site will be restored to <br /> conditions present prior to the pilot test although abandonment of the pilot test well will occur <br /> later. <br /> 1 <br /> 4.'7 OZONE BENCH SCALE TEST <br /> Though Kleinfelder will be field testing ozone sparging in the source area of the site, there is <br /> potential that this testing will not provide sufficient information to evaluate effectiveness or to <br /> design a full scale remediation system utilizing ozone to treat the DCA at the site. The ozone <br /> generator has a relatively low production(1 pound per day)relative to demand of TPH for ozone <br /> f in oxidation(3 pounds of ozone per one pound of TPH). Consequently, there is potential that <br /> f ozone from the sparge well will be rapidly consumed in the TPH-rich source area before reaching <br /> the monitoring wells. Considering the intended use of the ozone sparging is to remediate the <br /> leading edge of the relatively low concentration DCA plume, we will simulate this condition with <br /> a bench-scale test using groundwater from MW-DISC-11. This testing will provide more <br /> specific information on the effectiveness of ozone exclusively on DCA in groundwater <br /> containing a concentration of 1,2-DCA and the dissolved minerals indicative of the proposed <br /> target area of the technology. <br /> The test will involve first purging MW-DISC-11 and drawing a sample and sending it to the <br /> laboratory for analysis for DCA. Extracted groundwater will then be placed into two 5-gallon <br /> plastic vessels, one completely filled (Vessel#1) and one half-filled, sealed and placed at room <br /> temperature (Vessel#2). A ceramic-dome fine bubble diffuser(see Appendix B) will be placed <br /> in Vessel #1 and ozone delivered through the diffuser at a rate of 0.1 ppm of ozone at 2 scfm for <br /> four hours. Gaseous ozone in the vicinity will be continuously monitored and ORP in the vessel <br /> will be monitored hourly. Immediately after the four hour sparging is complete, Vessel #1 will be <br /> tested for dissolved ozone and Vessel #2 will then be f lled with half of the ozone-rich <br /> groundwater from Vessel #1. After one hour at room temperature, a laboratory sample will be <br /> collected from Vessel #1 and analyzed for EPA 8260 compounds. After the ozoned groundwater <br /> from Vessel#1 has been in contact with groundwater in Vessel #2 for at least 2 hours it will be <br /> tested for dissolved ozone and a laboratory sample will be collected and analyzed for EPA 8260 <br /> 1 compounds. <br /> The intent of this testing program is to investigate the effectiveness of gas phase ozone and <br /> dissolved ozone in reducing DCA in groundwater characteristic of the target area. The testing in <br /> Vessel#1 will indicate the effectiveness of gaseous-phase ozone oxidation on DCA. The testing <br /> in Vessel 92 will indicate the effectiveness of dissolve ozone oxidation on DCA and indicate the <br /> { effectiveness of DCA remediation in the absence of direct air bubble contact. The information <br /> 12280/2002R476 Page 21 of 26 <br /> Copyright 2002 Kleinfelder,Inc. May 17,2002 <br />