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PWI � ' 22 November 2006 AGE-NC Project No. 95-0167 Page 6 of 15 5 . 1 . 1 , PRINCIPLES For most SVE systems, a vacuum blower is used to enhance volatilization of hydrocarbons in the r 1 vadose (unsaturated) zone and draw the vapor into extraction wells screened within the contaminant Jplume. The hydrocarbon vapor is drawn from the wells and "treated" in one of several possible treatment units (carbon canisters, internal combustion engines, thermal oxidizers and/or catalytic oxidizers). Air injection wells may be installed outside the contaminant plume to increase air flow _ to the extraction unit. j r` j An internal-combustion (IC) system draws the vapor stream into a carburetor system of the internal- ! combustion engine and mixes the vapor with air before undergoing combustion. Exhaust gasses (oxides of carbon and hydrogen) are further broken down in a catalytic converter before being j emitted to the atmosphere. These systems require supplemental fuel, such as propane or natural gas, which can become expensive as vapor concentrations decrease below levels normally required for combustion. Typically, internal combustion engines work effectively where in-situ hydrocarbon concentrations approach the 40,000 parts per million - volume (ppmv) required for peak performance of the engine. As concentrations decrease below 20,000 ppmv, supplemental fuel requirements become burdensome. Another disadvantage of these systems is the noise generated by the engine; however, this can be mitigated by placing the unit inside an enclosure, such as a building. I In a carbon-canister system, hydrocarbon vapor is routed through activated carbon filters where it adsorption of hydrocarbons onto carbon takes place, removing the hydrocarbons from the vapor stream. This type of system works best for low concentrations of hydrocarbons, but becomes expensive when high concentrations ofhydrocarbon vapors necessitate frequent canister replacement and disposal of spent carbon. Thermal oxidation systems destroy hydrocarbons by open-flame combustion. Natural gas is _ commonly used as supplemental fuel, heating the extracted vapor stream to a combustion temperature of approximately 1400°F. Relative to internal combustion systems, these systems may _ be slightly more expensive to purchase and install. However, they can operate at higher air flow rates, and therefore remediate sites at a faster rate. For this system to be effective, hydrocarbon concentrations should range from 5 ,000 ppmv to 30,000 ppmv. Thermal oxidation systems operate j at much lower noise levels than internal combustion systems. ' I Catalytic oxidation units provide another option for treating vadose-zone contamination, particularly 1 after other extraction systems have reached their effective limits due to lowered hydrocarbon concentrations. These systems operate at temperatures of approximately 700°F, requiring less supplemental fuel than either thermal oxidizers or internal combustion engines. Other requirements and limitations are similar to those for internal-combustion and thermal oxidizer systems. ' _. Advanced CeoEnvironmental, Inc.