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High TECh ENTERPRISES . <br /> larly since I found no evidence at any location in the structure that volatile chemicals of any type had <br /> been flushed into the septic system. <br /> To place the laboratory mass concentration results in a more familiar context,please consider the fol- <br /> lowing set of calculations. The calculation relationship as well as all the Assumptions,Physical Pa- <br /> rameters, <br /> arameters,and Conversion Factors that were used to develop these solvent volumes have been listed on <br /> below. <br /> ASSUBMdo <br /> 1. Each of these two septic tanks on this property has a capacity of 1,200 gallons. <br /> 2. Each of these two septic tanks was fillet to 50%of its capacity at the time of their sampling(i.e., <br /> each tank contained 600 gallons of septic fluid). <br /> 3. A single drop of water has an approximate volume of 0.0156 cubic centimeters(using as a ref- <br /> erence: <br /> eference:Elements of Msical Chemistry,by Samuel Glasstone,published by D. Van Nosrand <br /> Company,Inc.,which states that approximately 64 drops of water are required to produce a vol- <br /> ume of 1 cubic centimeter). <br /> Tabulation of the ftakd Fame=and dMe COUMim Factors invOlv <br /> 1. The densities of the seven chemicals found to have been present in these two septic tanks are as <br /> follows: toluene [0.865 gms/cm3],ethyl benzene [0:867 gms/cm3],m-xylene [0.884 gms/cm3], <br /> p-xylene [0.866 jins/cm3], o-xylene [0.870 gms/cm], 1,4-dichlorobenzene [1.241 <br /> gms/cm3], and trichlorotrifluoroethane [1.570 gms/cm3]. <br /> 2. 1 gallon= 3.785 liters;therefore, 600 gallons=2,271 liters. <br /> The goal of the following calculations is to provide an estimate of the volume of each of these chemi- <br /> cals that would be required to produce the laboratory determined concentrations found in these two <br /> tanks. The formula is as follows: <br /> (tank concentration, µgms/liter)(2,271 liters/tank) <br /> Solvent Volume, in drops = 3 <br /> (solvent density, gms/cm )(106 µgms/gm)(0.0156 cm3/drop) <br /> On the basis of. (1)the relationship listed immediately above, (2)the lab concentration results, (3)the <br /> three assumptions,(4)the physical density parameters of the seven chemicals, and(5)the conversion <br /> factor for gallons to liters,the following tabulations list the volume of each of these seven chemicals— <br /> again in drops(as from an eye dropper)—that would have to have been added to each septic tank in <br /> order to have produced the concentrations that were determined by GeoAnalytical Labs. <br /> TaWe 2A—Swdq T4nLA <br /> No. Anal Volume,in dro s <br /> 1. toluene 1.40 drops <br /> tdchlorotdfluoroethane 0.19 drops <br /> 2. s <br /> Table 2A—Septic Tank B " <br /> No. Analyte. Volume,in drops <br /> 1. toluene 1.57 drops <br /> 2. ethyl benzene 0.34 drops <br /> 3. m-&p-xylene(total) 1.55 drops <br /> 4. o-xylene 0.23 drops <br /> 5. 1,4-dichlorobenzene 1.17 drops <br /> From the perspective of the equivalent volumes of solvents that were measured to have been present in <br /> these two half full septic tanks,it is extremely impressive how remarkably sensitive the EPA 8260B <br /> procedure is! In my judgment,these concentrations are insignificant and require no additional reme- <br /> diation or monitoring whatsoever. <br />