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No.318 7"YI.ENE(Mixed Isomers) RISS <br /> E <br /> SEC' TC}N 6 `HALTH.:HAZARD INFC3RNIATION <br /> Xylcoc is not listed as a carcinogen by the IARC 3 .or OSHA. coaldcl may cause <br /> Summary of Risks:Liquid xylene is a skin irritant and causes eq'thema,dry ne.s,ani defacing prolonged > <br /> P y and in cstin it can result to gasttnmtcstioal disturC a- -and <br /> blistering.Inhaling xylcnc can depress the ccaual nervous s stem(Chs), S 6orid <br /> possibly hematcmesis(vomiting bl�osurefect6lchms w�h ey s�skinVicenlungs, <br /> tra!new ushsystem,kidneys, liver may ibe worsestcidiby s <br /> Aggravated by Long Term Exp a ctrointcstinaltract,blood,livcr,kidneys,skin. Primary Entry: Inhalation, <br /> exposureto xyltne. Target Organs: CNS,eyes.$ fig g-fi <br /> skin and throatccamca]vacuolization anorexia;nauusc3;vomiting, bdominal pain;ss;excitement-, and dermatitis. Effects'.Reversi Ie eye ose, <br /> damage,headache,loss of appetite,nervousness,pale skin,and skin rash. With lent of running water for at <br /> FIRST AID: Eyes. immediately flush eyes,including under the eyelids, gently but thoroughly P y' fi <br /> Icast 15 minutes. Skin Immediately his herb vvasl�the affected area athing as affected Have ith sO2P andperwater'administerInhaloxloen.n. RcIngestion.trpNcvergive anything <br /> air;restore andtor suppoR truism Vomitingma occur spoatancously,but do 3aa inducethe!un s�5evere nate <br /> by mouth to someone who is uncoaseious os con g y (breathing the li uid xy 5)• <br /> occur,keep exposed perwn's head below his or her hips onary injury aspirationacur from aspirins very small quantities of xylene. <br /> hemorrhagic paeumomus with grave,possibly fatal,pulmonary injury <br /> GET MEDICAL HELP(IN PLANT,PAIWIEDIC,COM,tIUNITY)FOR ALL EXPOSURES. Seek prompt <br /> medical assistance for further treatment,observation,and support after first aid.If exposure uredema Is Is <br /> with careful moni <br /> hospltilizatloa for at(east 72 hours toring for delayed onset of p 3' <br /> recommended <br /> �ECTI`ON 7 SPILL I Er Ii €�:p'DIS O$�`Y'`p D EDOREEcsiatl CIcaou personnel need <br /> Spill/Leak: Notify safety personnel,provide ventilation,and eliminate�Comaipsourcesl or <br /> ignition sills a ollcct waste or absorb it with an inert <br /> protection against:naiad with and inhalation of xylene vapor(see sect.S). �g P <br /> material such as sand,earth,or vermiculite.Usc nonsparking tools to place waste liquid or absorbent into closable containers for disposal. <br /> Keep waste out of sewers,watersheds,and waterways. <br /> Waste Disposal: Contact yoursupplier or a licensed contractor for detailed recommendations. Fallow Federal,state,and local <br /> regulations. <br /> OSHA Designations <br /> Air Contaminant(29 CFR 1910.1000 Subpart Z) <br /> EPA Designations(40 CFR 302.4) <br /> RCRA Hazardous Waste,No.U239 per ule Clean Warcr Act(CWA) section 311(b)(9) <br /> CERCLA Hazardous Substance,Reportable Quantity 111pC1 lbs(45�kg), <br /> $ECTI©! $:SPECItiL I'ROTECTIONKI TI O.FIVf TION shield <br /> a. <br /> goggles. 1: Respirator: Use a NIOSH <br /> Gos pOS51 <br /> sgles: Always wear protective eyeglasses or eh cmxrtd faccp rotection regulatiohere ns(29CFR 1910.13)wear a eslpl face shield c a <br /> supplementary protective measure.Follow OSHA P <br /> approved respirator per the NIOS11 Poc1Er Guide to Cher icai Hazards for the maximum-use conccnvatieas ame(leak the exposure limits <br /> cited in section 2.Follow OSHA a SCSto with a full facep ec op^.rated is she pressure-demand or poor sitive presstktrc modor cleaning�zrnl r Air- <br /> Vessels and storage tanks), en-deficient atmospheres. Other:Wear impervious gloves,boots,aprons,gauntlets, <br /> purifying respirators will nor protect workers in Oxyg P <br /> etc.,as required by the specifics of the u• latiO <br /> orl operation to pretreat prolaagcd or owcrful enough to mtaintain airborne level of xyiceestall <br /> and operate general and local maximum,explosion-proof ventilation systems p g hone iota <br /> be}ow the OSHA PEL standard cited in section 2.Local exhaust ventilation is preferred because ence 1 prevents dispersion 3 for drt4cd ar ice <br /> gennium refer <br /> eral work areas by eliminating it at its source.Consul[the latest edition dd cashin faeilil s a6ailablc in areas of use and handling. <br /> Safety Stations: Make cycA ash stations,safetylquick drench showers, g <br /> Contaminated Equipment: Contact]cases pose a special hazard;soft leases may absorb irritants ng d ain;cle z xylene from hoes <br /> not wear contact leases in any work arca.Remove contaminated clothing and launder it befom this material.Kcc it off of your <br /> and equipment. Comments: Practice good personal hygiene-always wash thoroughly after using P <br /> clothing and equip COL. Avoid transferring it from your hands to your mouth while eating,drinking,or smoking. Do not eat drink or <br /> smokc in any work area.Do not inhale xylene vapor. <br /> :'-SECTION''9i SPECIAL'PRECAa TIONS 1 ud�aaway COMFromE�NT of ignition and swag oxiducrs.Protect` <br /> Storage/Segregation: Store xylene in a cool, ry, <br /> containers from physical damage. <br /> Special HandlinalStorage: Make sure all engineering eyeless(production,transportation)arc -proof design. <br /> of maximum -proof <br /> and bond all containers,pipelines,etc.,used in shippi.':g,L-msfcrrjng,reacting,producing,and sampling operations. <br /> Transportation Data(49 CFR 172.101-1) DOT Label'Flammable Liouid 11,10 Label.Flammable Liquid <br /> DOT Shipping Name:Xylene <br /> ---DOT ID NoUI\1367--- -- -- DOT Hazard Class:Flammable Liquid 1150 Class 3.2 or <br /> 3.3 <br /> References: 1,2,12,73,S4-9=„1W,103. <br /> JssCgnens as to she sa:a5:ti:.• h11=for p-scta5^_=s p_:�oxrs a^ j prepared by PJ Igoe,BS <br /> F�.cssanly r,:r:hasers resro=sib:ln}.The fora,a::.`souF't rrasana5ie care has 1 <br /> LA-ir,tn--P;oPsc_ofs_hictonviio7,GeniumNbti*uzgca•,, Industrial Hygiene Review: DI 1, i on,ClH <br /> e.atends eo- tics,makes no rep:esen=os and as%=: no resxasibitity <br /> _ ss to t�sc a::cr+cy or s'��� �o:su=T.ir.:o-�zior.for EFPlica:ion to }I ardies,MD _ <br /> ia'scdrd -mo5 s e:to.,cora=u;,aces o:t3 <br /> Medical Review: AU <br /> --�—�rR^IIINnIVns�nmrrll�IP�IIIRl�l1 <br />