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T <br /> MIA <br /> NO. itta <br /> MATERIAL SAFETY DATA SHEET 4 � HYDRf1CFlI.ORIC ACID <br /> GENIUM PUBLISHING CORPORATION P.evi^ s <br /> 1145 C:ATALYN STREET <br /> 5CHENECTADY,NY 12303.1B35 USA OtNIUMrulk sHINGCORP. DATE June 198» <br /> (518)377.8855 <br /> SECTION 1, MATERIAL IDENTIFICATION <br /> MATERIAL NAMElHtDROCHLORIC ACIDOE 1•Saterial DiA3, <br /> water solution of hydrogen chloride bas. <br /> ESCRIPTION: This material is a id, Concentrated Hydrochloric Acid, <br /> VIER DESIGNATIONS- Muriatic Ac <br /> CASP 007 647 010, Aqueous Hydrochloric Acid <br /> UFACTURER: Available from navy suppliers. <br /> �c HAZARD DATA <br /> SECTION Ii, INGREDIENTS AND HAZARDS <38 7hr m� <br /> Trace g <br /> ydragen Chloride (HCI) Balance <br /> Impurities (depends nn acid grade) uman, Inhalation <br /> ater CLo 1300ppn130 H <br /> bbit, Oral <br /> D50 900 mglkg <br /> *Current OSHA PEL and ACGIH (1983) TLV Ceiling Level. at, Oral (20oBe') <br /> D50 700 mglkg <br /> abbit, Skin (20°Be' <br /> D59 >5g/kg, 24 H-C <br /> 20 Be22 Be' 23 Be' <br /> SECT)ON IH. pHYSICAL DATA 18,8e' 35. 37.1 <br /> -- 5 31.5 123 <br /> t±ezght b FiCI ---- 144 _101 <br /> _. Boiling pt, 1 atm, deg F- - 208 163 -86 1.1 <br /> oir.[, deg F (Approx) -»3 1.179 1.189 <br /> Freezing P 1.142 1.162 <br /> Specific gravity, 60(60 `r - ti25/33 ti67/9? ti186l190 <br /> t'ap. Press., 25C, <br /> HC11Tota1, rca Hg 1-7/17 <br /> rellov, fuming* liquid with a pungent, irrita- <br /> All rxterials are cor.,p'_etely water seluw_z _.4th '-100;: volatiles and pH 1• <br /> s gpn Hci detectc� b1. me1lJ 5-10 pm is disagreeable. <br /> Appzaran�e b Odor: Clear, colorless to It. p <br /> xr1cnp; cone. ten to a [unin� iaJ1 s a: rue's Cgt:oerature. Lower ; Upper <br /> SECTION N. FIRE AND EXPL05lON DATA I F{emmah d,r I'm•1"n A.+ I I <br /> A„1a.0 nil.on..n• I — <br /> NIA j ;IA <br /> Excinguishir,g media: Select that suitable for surrounding fire. Use a water sera} co cool <br /> fire exposed containers to prevent rupture. to produce flanable <br /> 'onflar ble, but acid can react with many metals, such as 1equipment.) Neutralize <br /> hydro[en gas. (Flammable cont. may accur..ulate inside metal <br /> and with limestone, staked lima or soda ash to minimize formation of potentially <br /> explosive hydrogen gas. g apparatus <br /> irefighters should u$e fullirrs[ina t rest ine and self-contained breathing <br /> wnen th_s naterial is invo_'e in a etre s.tuation. <br /> SECTION V. REACTIVITY DATA mineral acid <br /> i is natxrial is stable whet. Properly conta.ned and handled. It is a strong hydroxides, <br /> and is, <br /> ial i highly reactive with materials such as metals, metal oxides, h-' <br /> an cath°nares and ether alkaline materials. It is highly corrosive [o man)' <br /> materials; it must have Proper containmc:''.fo� or�pressuredlingdattroonetemperature wY;en <br /> t liberates significant levels Of HCl gas p P <br /> ed and large <br /> a-ounts of NCI when heated. <br /> en[ra[ o en as. <br /> cont i .•ill produce fla-=.-=1e h}dr g g <br /> eaction with nost net-is - sulfites aad formaldehyde (may <br /> ncompacible with materials such as cyan:-z_�. sulfites, <br /> H S, 50�, >�sc'tilorocethyl I?:Mev, respectively) - LISHI - -- - ------- <br /> 2 - <br /> GENI UM-------- <br /> UB �'�' <br /> ftba,aw Ca1p1u"^ <br /> An>�a„o1,si,J u,..nAo,a pa„biL ',f{*�IfL p,sm,unn a p• <br />